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1-Decanol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil505. ± 3.KAVGN/AAverage of 16 out of 17 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus279.6KN/ADavies and Kybett, 1965Uncertainty assigned by TRC = 0.5 K; TRC
Tfus280.05KN/ACostello and Bowden, 1958Uncertainty assigned by TRC = 0.4 K; TRC
Tfus277.KN/ABadin, 1943Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Ttriple279.65KN/ASpizzichino, 1956Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Ptriple0.000001barN/ASpizzichino, 1956Uncertainty assigned by TRC = 1.3×10-7 bar; TRC
Quantity Value Units Method Reference Comment
Tc690. ± 10.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Pc23.2 ± 0.5barN/AGude and Teja, 1995 
Pc23.10barN/AQuadri, Khilar, et al., 1991Uncertainty assigned by TRC = 0.60 bar; TRC
Pc23.20barN/ARosenthal and Teja, 1990Uncertainty assigned by TRC = 0.20 bar; TRC
Pc23.20barN/ARosenthal and Teja, 1989Uncertainty assigned by TRC = 0.20 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.649l/molN/AGude and Teja, 1995 
Quantity Value Units Method Reference Comment
rhoc1.54 ± 0.05mol/lN/AGude and Teja, 1995 
rhoc1.67mol/lN/ATeja, Lee, et al., 1989TRC
rhoc1.54mol/lN/AAnselme and Teja, 1988Uncertainty assigned by TRC = 0.04 mol/l; TRC
rhoc1.67mol/lN/AEfremov, 1966Uncertainty assigned by TRC = 0.02 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap82. ± 6.kJ/molAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Deltasub112.5 ± 6.3kJ/molN/AKarnes, Kybett, et al., 1965AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
380.70.009Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
78.180323.15N/ASvensson, 1979No pressure measurement.; DH
79.5309.GSKulikov, Verevkin, et al., 2001Based on data from 281. - 327. K.; AC
81.1293.N/AN'Guimbi, Berro, et al., 1999Based on data from 278. - 378. K.; AC
75.4336.N/AN'Guimbi, Kasehgari, et al., 1992Based on data from 283. - 388. K.; AC
71.6364.AStephenson and Malanowski, 1987Based on data from 349. - 410. K.; AC
62.6420.AStephenson and Malanowski, 1987Based on data from 405. - 528. K.; AC
53.9489.AStephenson and Malanowski, 1987Based on data from 474. - 529. K.; AC
78.2 ± 0.8323.CSvensson, 1979AC
77.6313.N/AWilhoit and Zwolinski, 1973Based on data from 298. - 325. K.; AC
69.5393.DTAKemme and Kreps, 1969Based on data from 378. - 504. K.; AC
77.6311.MEDavies and Kybett, 1965Based on data from 298. - 325. K.; AC
69.6379.N/ARose, Papahronis, et al., 1958Based on data from 364. - 461. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) beta Tc (K) Reference Comment
298. - 323.122.270.4044687.Majer and Svoboda, 1985 

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
241.93323.15Svensson, 1979No; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
349.37 - 406.184.533211742.392-115.236Ambrose, Ellender, et al., 1974Coefficents calculated by NIST from author's data.
400.41 - 528.323.857521373.019-147.727Ambrose and Sprake, 1970Coefficents calculated by NIST from author's data.
378. - 504.3.518691180.306-168.829Kemme and Kreps, 1969 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
115.5 ± 6.3268.MEKarnes, Kybett, et al., 1965Based on data from 264. - 273. K. See also Stephenson and Malanowski, 1987.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
33.67280.van Miltenburg, Gabrielová, et al., 2003AC
37.66280.1Domanska and Gonzalez, 1997AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Davies and Kybett, 1965
Davies, M.; Kybett, B., Sublimation and vaporization heats of long-chain alcohols, Trans. Faraday Soc., 1965, 61, 1608. [all data]

Costello and Bowden, 1958
Costello, J.M.; Bowden, S.T., The Temperature Variation of Orthobaric Density Difference in Liquid-Vapor Systems III. Alcohols, Recl. Trav. Chim. Pays-Bas, 1958, 77, 36-46. [all data]

Badin, 1943
Badin, E.J., J. Am. Chem. Soc., 1943, 65, 1809. [all data]

Spizzichino, 1956
Spizzichino, C., Contribution a l'etude des tensions de vapeur et des chaleurs de vaporisation des acides gras, esters methyliques et alcools gras a des pressions inferieures a 1 mm de mercure, J. des Recherches du C.N.R.S., 1956, 34, 1-24. [all data]

Gude and Teja, 1995
Gude, M.; Teja, A.S., Vapor-Liquid Critical Properties of Elements and Compounds. 4. Aliphatic Alkanols, J. Chem. Eng. Data, 1995, 40, 1025-1036. [all data]

Quadri, Khilar, et al., 1991
Quadri, S.K.; Khilar, K.C.; Kudchadker, A.P.; Patni, M.J., Measurement of the critical temperatures and critical pressures of some thermally stable or mildly unstable alkanols, J. Chem. Thermodyn., 1991, 23, 67-76. [all data]

Rosenthal and Teja, 1990
Rosenthal, D.J.; Teja, A.S., The Critical Pressures and temperatures of Isomeric Alkanols, Ind. Eng. Chem. to be published 1990 1990, 1990. [all data]

Rosenthal and Teja, 1989
Rosenthal, D.J.; Teja, A.S., Critical pressures and temperatures of isomeric alkanols, Ind. Eng. Chem. Res., 1989, 28, 1693. [all data]

Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J., Correlation of the Critical Properties of Alkanes and Alkanols in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]

Anselme and Teja, 1988
Anselme, M.J.; Teja, A.S., Critical Temperatures and Densities of Isomeric Alkanols with Six to Ten Carbon Atoms, Fluid Phase Equilib., 1988, 40, 127-34. [all data]

Efremov, 1966
Efremov, Yu.V., Density, Surface Tension, Saturated Vapor Pressurs and Critical Parameters of Alcohols, Zh. Fiz. Khim., 1966, 40, 1240. [all data]

Karnes, Kybett, et al., 1965
Karnes, H.A.; Kybett, B.D.; Wilson, M.H.; Margrave, J.L.; Newman, M.S., Strain energies in hydrocarbons from heats of combustion. III. 3,4,5,6- and 2,4,5,7-tetramethylphenanthrenes, J. Am. Chem. Soc., 1965, 87, 5554-5558. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Svensson, 1979
Svensson, Ch., Enthalpies of vaporization of 1-decanol and 1-dodecanol and their influence on the CH2-increment for the enthalpies of formation, J. Chem. Thermodynam., 1979, 11, 593-596. [all data]

Kulikov, Verevkin, et al., 2001
Kulikov, Dmitry; Verevkin, Sergey P.; Heintz, Andreas, Enthalpies of vaporization of a series of aliphatic alcohols, Fluid Phase Equilibria, 2001, 192, 1-2, 187-207, https://doi.org/10.1016/S0378-3812(01)00633-1 . [all data]

N'Guimbi, Berro, et al., 1999
N'Guimbi, J.; Berro, C.; Mokbel, I.; Rauzy, E.; Jose, J., Experimental vapour pressures of 13 secondary and tertiary alcohols---correlation and prediction by a group contribution method, Fluid Phase Equilibria, 1999, 162, 1-2, 143-158, https://doi.org/10.1016/S0378-3812(99)00168-5 . [all data]

N'Guimbi, Kasehgari, et al., 1992
N'Guimbi, J.; Kasehgari, H.; Mokbel, I.; Jose, J., Tensions de vapeur d'alcools primaires dans le domaine 0,3 Pa à 1,5 kPa, Thermochimica Acta, 1992, 196, 2, 367-377, https://doi.org/10.1016/0040-6031(92)80100-B . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Wilhoit and Zwolinski, 1973
Wilhoit, R.C.; Zwolinski, B.J., Physical and thermodynamic properties of aliphatic alcohols, J. Phys. Chem. Ref. Data Suppl., 1973, 1, 2, 1. [all data]

Kemme and Kreps, 1969
Kemme, Herbert R.; Kreps, Saul I., Vapor pressure of primary n-alkyl chlorides and alcohols, J. Chem. Eng. Data, 1969, 14, 1, 98-102, https://doi.org/10.1021/je60040a011 . [all data]

Rose, Papahronis, et al., 1958
Rose, Arthur; Papahronis, B.; Williams, E., Experimental Measurement of Vapor-Liquid Equilibria for Octanol-Decanol and Decanol-Dodecanol Binaries., Ind. Eng. Chem. Chem. Eng. Data Series, 1958, 3, 2, 216-219, https://doi.org/10.1021/i460004a008 . [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Ambrose, Ellender, et al., 1974
Ambrose, D.; Ellender, J.H.; Sprake, C.H.S., Thermodynamic properties of organic oxygen compounds XXXV. Vapour pressures of aliphatic alcohols, The Journal of Chemical Thermodynamics, 1974, 6, 9, 909-914, https://doi.org/10.1016/0021-9614(74)90235-3 . [all data]

Ambrose and Sprake, 1970
Ambrose, D.; Sprake, C.H.S., Thermodynamic properties of organic oxygen compounds XXV. Vapour pressures and normal boiling temperatures of aliphatic alcohols, The Journal of Chemical Thermodynamics, 1970, 2, 5, 631-645, https://doi.org/10.1016/0021-9614(70)90038-8 . [all data]

van Miltenburg, Gabrielová, et al., 2003
van Miltenburg, J. Cees; Gabrielová, Hana; Ruzicka, Kvetoslav, Heat Capacities and Derived Thermodynamic Functions of 1-Hexanol, 1-Heptanol, 1-Octanol, and 1-Decanol between 5 K and 390 K, J. Chem. Eng. Data, 2003, 48, 5, 1323-1331, https://doi.org/10.1021/je0340856 . [all data]

Domanska and Gonzalez, 1997
Domanska, U.; Gonzalez, J.A., Solid-liquid equilibria for systems containing long-chain 1-alkanols III. Experimental data for 1-tetradecanol, 1-hexadecanol, 1-octadecanol or 1-icosanol + 1-butanol, 1-hexanol, 1-octanol or 1-decanol mixtures. Characterization in terms of DISQUAC, Fluid Phase Equilibria, 1997, 129, 1-2, 139-163, https://doi.org/10.1016/S0378-3812(96)03150-0 . [all data]


Notes

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