Dimethyl (dichloroboryl)amine
- Formula: C2H6BCl2N
- Molecular weight: 125.793
- CAS Registry Number: 1113-31-1
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 8.89 ± 0.31 | kcal/mol | N/A | Burg and Randolph, 1951 | See also Cox and Pilcher, 1970. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.56 | PE | Bock and Fuss, 1971 | LLK |
9.57 | EI | Lappert, Litzow, et al., 1970 | RDSH |
9.68 | PE | King, Krishnamurthy, et al., 1972 | Vertical value; LLK |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Burg and Randolph, 1951
Burg, Anton B.; Randolph, Carl L.,
Disproportionation Reactions of the Dimethylaminoboron Hydrides,
J. Am. Chem. Soc., 1951, 73, 3, 953-957, https://doi.org/10.1021/ja01147a019
. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]
Bock and Fuss, 1971
Bock, H.; Fuss, W.,
Ionisierungsenergien und geometrie von aminoboranen,
Chem. Ber., 1971, 104, 1687. [all data]
Lappert, Litzow, et al., 1970
Lappert, M.F.; Litzow, M.R.; Pedley, J.B.; Riley, P.N.K.; Spalding, T.R.; Tweedale, A.,
Bonding studies of compounds of boron and the group IV elements. Part III.First ionisation potentials of some simple boron compounds by electron impact and by a new empirical molecular orbital method,
J. Chem. Soc. A, 1970, 2320. [all data]
King, Krishnamurthy, et al., 1972
King, G.H.; Krishnamurthy, S.S.; Lappert, M.F.; Pedley, J.B.,
Bonding studies of compounds of boron and the Group 4 elements. Part 9. Photoelectron spectra and bonding studies of halogeno-, dimethylamino-, and methyl-boranes, BX3 and BX2Y,
Faraday Discuss. Chem. Soc., 1972, 54, 70. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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