Stannane, tetraethenyl-
- Formula: C8H12Sn
- Molecular weight: 226.891
- IUPAC Standard InChIKey: MZIYQMVHASXABC-UHFFFAOYSA-N
- CAS Registry Number: 1112-56-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Stannane, tetravinyl-; Tetravinylstannane; Tetravinyltin; Sn(CH=CH2)4
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 72.6 ± 1.8 | kcal/mol | Review | Martinho Simões | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -1373.0 ± 1.8 | kcal/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
3 (l) + (l) = 4C6H9ClSn (l)
By formula: 3C8H12Sn (l) + Cl4Sn (l) = 4C6H9ClSn (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -26.4 ± 3.0 | kcal/mol | RSC | Nash, Skinner, et al., 1965 |
(l) + 3 (l) = 4C2H3Cl3Sn (l)
By formula: C8H12Sn (l) + 3Cl4Sn (l) = 4C2H3Cl3Sn (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -24.5 ± 3.0 | kcal/mol | RSC | Nash, Skinner, et al., 1965 |
(l) + (l) = 2C4H6Cl2Sn (l)
By formula: C8H12Sn (l) + Cl4Sn (l) = 2C4H6Cl2Sn (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -22.0 ± 3.0 | kcal/mol | RSC | Nash, Skinner, et al., 1965 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.4 | PE | Novak, Cvitas, et al., 1981 | LLK |
9.56 | PE | Novak, Cvitas, et al., 1981 | Vertical value; LLK |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY |
NIST MS number | 60687 |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Apiezon L | 190. | 911. | Putnam and Pu, 1965 | Celite; Column length: 1. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Packed | Apiezon L | 914. | Putnam and Pu, 1965, 2 | Celite, 10. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 914. | Putnam and Pu, 1965, 2 | Celite, 15. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 914. | Putnam and Pu, 1965, 2 | Celite, 6. K/min; Column length: 3. m; Tstart: 60. C |
References
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F.,
Trans. Faraday Soc., 1965, 61, 640. [all data]
Novak, Cvitas, et al., 1981
Novak, I.; Cvitas, T.; Klasinc, L.,
Photoelectron spectrum of tetravinylstannane, Sn(CH=CH2)4,
J. Organomet. Chem., 1981, 220, 145. [all data]
Putnam and Pu, 1965
Putnam, R.C.; Pu, H.,
Retention indices of organotins,
J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160
. [all data]
Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H.,
Retention indices of organotins (II),
J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289
. [all data]
Notes
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- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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