Cyclohexane

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Enthalpy of combustion of liquid at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

ΔcH°liquid (kJ/mol) Method Reference Comment
-3918.6 ± 0.7CcbKaarsemaker and Coops, 1952Corresponding ΔfHºliquid = -157.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-3918.4 ± 1.0CcbSpitzer and Huffman, 1947Corresponding ΔfHºliquid = -157.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-3919.9 ± 0.71CcbProsen, Johnson, et al., 1946Corresponding ΔfHºliquid = -156.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-3919.6 ± 1.3CcbMoore, Renquist, et al., 1940Reanalyzed by Cox and Pilcher, 1970, Original value = -3917.9 ± 1.3 kJ/mol; Corresponding ΔfHºliquid = -156.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-3918.0 ± 0.75CcbMoore and Parks, 1939Corresponding ΔfHºliquid = -158.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-3935.3CcbRichards and Barry, 1915At 291 K; Corresponding ΔfHºliquid = -140.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-3947.CcbZubova, 1901Corresponding ΔfHºliquid = -129. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

References

Go To: Top, Enthalpy of combustion of liquid at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kaarsemaker and Coops, 1952
Kaarsemaker, S.; Coops, J., Thermal quantities of some cycloparaffins. Part III. Results of measurements, Rec. Trav. Chim. Pays/Bas, 1952, 71, 261. [all data]

Spitzer and Huffman, 1947
Spitzer, R.; Huffman, H.M., The heats of combustion of cyclopentane, cyclohexane, cycloheptane and cyclooctane, J. Am. Chem. Soc., 1947, 69, 211-213. [all data]

Prosen, Johnson, et al., 1946
Prosen, E.J.; Johnson, W.H.; Rossini, F.D., Heats of formation and combustion of the normal alkylcyclopentanes and cyclohexanes and the increment per CH2 group for several homologous series of hydrocarbons, J. Res. NBS, 1946, 37, 51-56. [all data]

Moore, Renquist, et al., 1940
Moore, G.E.; Renquist, M.L.; Parks, G.S., Thermal data on organic compounds. XX. Modern combustion data for two methylnonanes, methyl ethyl ketone, thiophene and six cycloparaffins, J. Am. Chem. Soc., 1940, 62, 1505-1507. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Moore and Parks, 1939
Moore, G.E.; Parks, G.S., New thermodynamic data for the cyclohexane-methylcyclopentane isomerization, J. Am. Chem. Soc., 1939, 61, 2561-2562. [all data]

Richards and Barry, 1915
Richards, T.W.; Barry, F., The heats of combustion of aromatic hydrocarbons and hexamethylene, J. Am. Chem. Soc., 1915, 37, 993-1020. [all data]

Zubova, 1901
Zubova, P., Data about heat of combustion of compound cycle structure, Zh. Fiz. Khim., 1901, 33, 708-722. [all data]

Notes

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