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Cyclohexane

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryHP-10.664.1Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-110.660.1Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-120.665.7Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-130.662.3Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-140.661.2Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-150.661.9Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-160.662.9Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
PackedPMS-100090.681.Arutyunov, Kudryashov, et al., 2004N2, Chromaton N-AW-DMCS; Column length: 2. m
PackedSE-30160.676.Kurbatova, Finkelstein, et al., 2004Chromaton N-AW; Column length: 1. m
CapillarySqualane70.667.14Soják, 2004H2
CapillarySqualane70.667.02Soják, 2004N2
CapillarySqualane70.667.46Soják, 2004N2
CapillaryOV-10140.656.8Chen, Liang, et al., 2001He; Column length: 50. m; Column diameter: 0.25 mm
CapillaryOV-10160.662.2Chen, Liang, et al., 2001He; Column length: 50. m; Column diameter: 0.25 mm
PackedC78, Branched paraffin130.693.6Dallos, Sisak, et al., 2000He; Column length: 3.3 m
CapillaryHP-10160.663.35Garay, 200050. m/0.2 mm/0.2 «mu»m, H2
CapillaryOV-101110.668.Zhuravleva, 200050. m/0.3 mm/0.4 «mu»m, He
CapillaryOV-1010.649.Skrbic, 1997 
CapillaryOV-1010.650.Skrbic, 1997 
CapillaryCP Sil 260.672.0Estel, Mohnke, et al., 1995100. m/0.25 mm/0.25 «mu»m
CapillaryOV-101150.688.3Cha and Lee, 1994Column length: 20. m; Column diameter: 0.5 mm
CapillaryOV-101180.697.9Cha and Lee, 1994Column length: 20. m; Column diameter: 0.5 mm
CapillarySqualane25.658.Hilal, Carreira, et al., 1994 
CapillaryCP Sil 5 CB20.655.7Do and Raulin, 199225. m/0.15 mm/2. «mu»m, H2
PackedC78, Branched paraffin130.692.8Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
CapillaryBP-10.649.Skrbic and Cvejanov, 199215. m/0.53 mm/1.0 «mu»m, N2
PackedApolane130.694.Dutoit, 1991Column length: 3.7 m
CapillaryOV-145.660.6Guan, Kiraly, et al., 198920. m/0.32 mm/1.2 «mu»m, He
CapillaryOV-165.665.6Guan, Kiraly, et al., 198920. m/0.32 mm/1.2 «mu»m, He
CapillaryOV-145.660.6Guan, Kiraly, et al., 198925. m/0.31 mm/0.52 «mu»m, He
CapillaryOV-165.665.6Guan, Kiraly, et al., 198925. m/0.31 mm/0.52 «mu»m, He
CapillarySqualane50.662.7Guan, Kiraly, et al., 198950. m/0.22 mm/0.21 «mu»m, He
CapillarySqualane70.667.1Guan, Kiraly, et al., 198950. m/0.22 mm/0.21 «mu»m, He
CapillaryHP-160.663.Bangjie, Yijian, et al., 1988N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryHP-160.664.Bangjie, Yijian, et al., 1988N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryOV-10140.658.Laub and Purnell, 1988 
CapillaryOV-10160.663.Laub and Purnell, 1988 
CapillaryOV-10180.668.Laub and Purnell, 1988 
PackedOV-101120.676.Litvinenko, Isakova, et al., 1988He, Chromaton W AW; Column length: 2.4 m
CapillarySqualane50.662.Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillarySqualane70.666.4Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillaryOV-1100.671.1Engewald, Billing, et al., 1987Column length: 50. m; Column diameter: 0.3 mm
CapillaryOV-101100.674.Engewald, Topalova, et al., 1987Column length: 50. m; Column diameter: 0.30 mm
PackedApolane150.680.Evans and Haken, 1987He, Chromosorb G AW DCMS; Column length: 3.7 m
PackedSqualane80.669.Fernández-Sánchez, García-Domínguez, et al., 1987H2
CapillaryOV-10140.658.7Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
CapillaryOV-10150.660.9Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
CapillaryOV-10160.663.2Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
CapillaryOV-10170.665.5Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
PackedApolane150.680.Haken and Vernon, 1986Chromosorb G AW DCMS; Column length: 3.7 m
CapillaryOV-1100.673.6Anders, Anders, et al., 198555. m/0.21 mm/0.35 «mu»m, N2
PackedSE-30180.658.Oszczapowicz, Osek, et al., 1985N2, Chromosorb A AW; Column length: 3. m
PackedSE-30150.685.Tiess, 1984Ar, Gas Chrom Q (80-100 mesh); Column length: 3. m
CapillaryOV-10130.656.Chien, Furio, et al., 1983 
CapillaryOV-10140.658.Chien, Furio, et al., 1983 
CapillaryOV-10150.660.Chien, Furio, et al., 1983 
CapillaryOV-10160.663.Chien, Furio, et al., 1983 
CapillaryOV-10170.665.Chien, Furio, et al., 1983 
CapillaryOV-10180.668.Chien, Furio, et al., 1983 
CapillaryOV-330.664.5Chien, Furio, et al., 1983, 2 
CapillaryOV-340.666.8Chien, Furio, et al., 1983, 2 
CapillaryOV-350.669.2Chien, Furio, et al., 1983, 2 
CapillaryOV-360.671.7Chien, Furio, et al., 1983, 2 
CapillaryOV-370.674.4Chien, Furio, et al., 1983, 2 
CapillaryOV-380.677.3Chien, Furio, et al., 1983, 2 
CapillaryDB-160.663.7Lubeck and Sutton, 1983Column length: 60. m; Column diameter: 0.264 mm
CapillaryDB-160.664.2Lubeck and Sutton, 198360. m/0.259 mm/1. «mu»m
PackedSE-30100.675.Winskowski, 1983Gaschrom Q; Column length: 2. m
CapillaryOV-150.661.Anders, Scheller, et al., 1982Column length: 55. m; Column diameter: 0.21 mm
CapillarySE-30130.683.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillarySE-3080.669.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
PackedPorapack Q200.639.Goebel, 1982N2
PackedApiezon L70.680.Jaworski, 1982Column length: 1.8 m
CapillaryOV-10150.661.Johansen and Ettre, 1982100. m/0.27 mm/0.20 «mu»m
CapillaryOV-10150.661.Johansen and Ettre, 198255. m/0.27 mm/0.9 «mu»m
CapillaryOV-150.662.Johansen and Ettre, 198217.5 m/0.2 mm/0.15 «mu»m
CapillarySE-3050.661.Johansen and Ettre, 198217.5 m/0.2 mm/0.15 «mu»m
CapillarySF-9650.661.Johansen and Ettre, 198291.4 m/0.31 mm/0.20 «mu»m
CapillaryOV-130.657.2Chien, Kopecni, et al., 1981H2
CapillaryOV-140.659.6Chien, Kopecni, et al., 1981H2
CapillaryOV-150.662.1Chien, Kopecni, et al., 1981H2
CapillaryOV-160.664.7Chien, Kopecni, et al., 1981H2
CapillaryOV-170.667.4Chien, Kopecni, et al., 1981H2
CapillaryOV-180.670.3Chien, Kopecni, et al., 1981H2
CapillarySE-3030.657.Chien, Kopecni, et al., 1981H2
CapillarySE-3040.659.1Chien, Kopecni, et al., 1981H2
CapillarySE-3050.661.3Chien, Kopecni, et al., 1981H2
CapillarySE-3060.663.6Chien, Kopecni, et al., 1981H2
CapillarySE-3070.666.1Chien, Kopecni, et al., 1981H2
CapillarySE-3080.668.8Chien, Kopecni, et al., 1981H2
CapillarySqualane50.662.Mitra, 1981N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane50.663.Mitra, 1981N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySE-3080.669.2Albaigés and Guardino, 1980He; Column length: 64. m; Column diameter: 0.25 mm
CapillarySqualane80.668.1Albaigés and Guardino, 1980He; Column length: 100. m; Column diameter: 0.25 mm
CapillaryApiezon L100.690.Morishita, Okano, et al., 1980Column length: 45. m; Column diameter: 0.25 mm
PackedSqualane100.675.Nabivach and Kirilenko, 1980He, Chromaton N-AW-HMDS; Column length: 1. m
CapillarySqualane50.662.7Bajus, Veselý, et al., 1979Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.663.9Bajus, Veselý, et al., 1979Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane50.662.78Pacáková and Koslík, 197850. m/0.2 mm/0.5 «mu»m, N2
CapillarySqualane100.674.Rang, Orav, et al., 1977Nitrogen or helium; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane100.664.Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
CapillarySqualane100.668.8Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
CapillarySqualane100.667.8Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
PackedApolane70.675.6Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedSqualane100.671.Vernon and Edwards, 1975N2, DCMS-treated Celite; Column length: 1. m
CapillarySqualane42.5660.Engewald, Epsch, et al., 1974N2; Column length: 100. m; Column diameter: 0.23 mm
CapillarySqualane70.668.Engewald, Epsch, et al., 1974N2; Column length: 100. m; Column diameter: 0.23 mm
PackedSE-30120.663.Pascal, Heintz, et al., 1974Column length: 2. m
PackedSE-30140.668.Pascal, Heintz, et al., 1974Column length: 2. m
PackedSE-30160.674.Pascal, Heintz, et al., 1974Column length: 2. m
CapillarySqualane50.663.Rijks and Cramers, 1974N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.667.Rijks and Cramers, 1974N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane100.674.Besson and Gäumann, 1973Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L100.689.Besson and Gäumann, 1973Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L50.669.Gäumann and Bonzo, 1973Column length: 100. m
CapillarySqualane50.662.Gäumann and Bonzo, 1973Column length: 100. m
CapillaryOV-10150.662.Pacáková, Hoch, et al., 197325. m/0.25 mm/1.39 «mu»m, N2
CapillaryOV-10160.664.Pacáková, Hoch, et al., 197325. m/0.25 mm/1.39 «mu»m, N2
CapillarySqualane100.675.7Schomburg and Dielmann, 1973Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane120.682.Agrawal, Tesarík, et al., 1972N2, Celite 545; Column length: 50. m; Column diameter: 0.3 mm
CapillarySqualane86.674.Agrawal, Tesarík, et al., 1972N2, Celite 545; Column length: 50. m; Column diameter: 0.3 mm
PackedApiezon L130.683.Paris and Alexandre, 1972Chromosorb W AW
CapillaryVacuum Grease Oil (VM-4)35.662.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)45.665.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)50.667.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)58.669.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)68.672.Sidorov, Petrova, et al., 1972 
CapillarySqualane70.663.8Dimov and Schopov, 1971Column length: 100. m; Column diameter: 0.25 mm
PackedSE-3075.667.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m
PackedSqualane100.674.Robinson and Odell, 1971N2, Embacel; Column length: 3.0 m
PackedVacuum Grease Oil (VM-4)35.662.Sidorov, Ivanova, et al., 1971 
PackedApiezon L100.700.Wagaman and Smith, 1971CH4; Column length: 3. m
CapillarySqualane70.667.Cramers, Rijks, et al., 1970Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.667.Cramers, Rijks, et al., 1970Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.667.Cramers, Rijks, et al., 1970Column length: 100. m; Column diameter: 0.25 mm
PackedSE-30130.676.Mitra and Saha, 1970N2
PackedSE-3080.667.Mitra and Saha, 1970N2
PackedApiezon L100.688.Brown, Chapman, et al., 1968N2, DCMS-treated Chromosorb W; Column length: 2.3 m
PackedSqualane27.658.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane49.664.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane67.668.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane86.672.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane22.656.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane30.658.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane40.660.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane55.664.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane70.667.Evans, 1966Untreated celite; Column length: 1.8 m
PackedDC-200100.675.Rohrschneider, 1966Column length: 4. m
PackedSqualane100.675.Rohrschneider, 1966Column length: 5. m
PackedApiezon L100.689.Rohrschneider, 1966Column length: 5. m
CapillarySqualane120.675.Schomburg, 1966 
CapillarySqualane70.668.Schomburg, 1966 
CapillarySqualane80.668.Schomburg, 1966 
PackedMethyl Silicone130.676.Antheaume and Guiochon, 1965 
PackedSqualane150.688.Schomburg, 1964 
PackedApiezon L70.676.Wehrli and Kováts, 1959Celite; Column length: 2.25 m

Kovats' RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-101650.Hayes and Pitzer, 1982110. m/0.25 mm/0.20 «mu»m, He, 1. K/min; Tstart: 35. C; Tend: 200. C
CapillaryApiezon L678.Louis, 1971N2, 1. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 60. C

Kovats' RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryPetrocol DH-100657.8Haagen-Smit Laboratory, 1997He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min)
CapillaryDB-1658.Hoekman, 199360. m/0.32 mm/1.0 «mu»m, He; Program: -40 C for 12 min; -40 - 125 C at 3 deg.min; 125-185 C at 6 deg/min; 185 - 220 C at 20 deg/min; hold 220 C for 2 min

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedCarbowax 20M160.740.Kurbatova, Finkelstein, et al., 2004Chromaton N-AW; Column length: 1. m
CapillaryPEG 4000100.766.Rang, Orav, et al., 1988 
CapillaryPEG 400060.748.Rang, Orav, et al., 1988 
CapillaryPEG 400070.752.Rang, Orav, et al., 1988 
CapillaryPEG 400080.757.Rang, Orav, et al., 1988 
PackedCarbowax 20M150.740.Haken and Vernon, 1986Chromosorb G AW DCMS; Column length: 3.7 m; Column diameter: 6.4 mm
PackedCarbowax 20M75.735.Goebel, 1982N2, Kieselgur (60-100 mesh); Column length: 2. m
CapillaryPEG-20M100.742.Morishita, Okano, et al., 1980Column length: 75. m; Column diameter: 0.25 mm
CapillaryPEG 4000100.766.Rang, Orav, et al., 1977Nitrogen or Helium; Column length: 45. m; Column diameter: 0.25 mm
PackedCarbowax 20M120.726.Pascal, Heintz, et al., 1974Column length: 2. m
PackedCarbowax 20M140.732.Pascal, Heintz, et al., 1974Column length: 2. m
PackedCarbowax 20M160.738.Pascal, Heintz, et al., 1974Column length: 2. m
PackedCarbowax 20M100.752.Rohrschneider, 1966Column length: 2. m

Kovats' RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryDB-Wax722.Umano and Shibamoto, 198840. C @ 10. min, 2. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 220. C
CapillaryDB-Wax722.Umano and Shibamoto, 198840. C @ 10. min, 2. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 220. C
CapillaryDB-Wax722.Umano and Shibamoto, 1987He, 40. C @ 10. min, 2. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 200. C

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySPB-5663.Engel and Ratel, 200760. m/0.32 mm/1. «mu»m, 40. C @ 2. min, 3. K/min, 230. C @ 10. min
CapillaryPetrocol DH655.8Censullo, Jones, et al., 200350. m/0.25 mm/0.5 «mu»m, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
CapillarySPB-1647.56LECO Corporation, 200330. m/0.25 mm/0.25 «mu»m, 40. C @ 2. min, 10. K/min, 250. C @ 2. min
CapillarySPB-1648.22LECO Corporation, 200330. m/0.25 mm/0.25 «mu»m, 40. C @ 2. min, 10. K/min, 250. C @ 2. min
CapillaryDB-5656.2Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5654.9Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 4. K/min; Tend: 310. C
CapillaryDB-5655.4Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 2. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5656.2Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5657.6Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 6. K/min; Tstart: 40. C; Tend: 310. C
CapillaryOV-101654.6Yin, Liu, et al., 2001N2, 1. K/min; Column length: 80. m; Column diameter: 0.22 mm; Tstart: 30. C; Tend: 130. C
CapillaryDB-5655.4Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 2. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5656.2Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5657.6Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 6. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5656.2Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5654.9Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 4. K/min; Tend: 310. C
CapillaryPetrocol DH651.20Subramaniam, Bochniak, et al., 1994100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH651.24Subramaniam, Bochniak, et al., 1994100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryUltra-1651.Olson, Sinkevitch, et al., 19924. K/min; Tstart: -40. C; Tend: 230. C
CapillaryPetrocol DH651.09White, Douglas, et al., 1992100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH651.14White, Douglas, et al., 1992100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH651.White, Hackett, et al., 1992100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH668.White, Hackett, et al., 1992100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryHP-1660.8Bangjie, Xijian, et al., 1987N2, 10. K/min; Column length: 25. m; Column diameter: 0.2 mm; Tstart: 30. C
CapillaryHP-1657.3Bangjie, Xijian, et al., 1987N2, 2. K/min; Column length: 25. m; Column diameter: 0.2 mm; Tstart: 30. C
CapillaryHP-1656.4Bangjie, Xijian, et al., 1987N2, 30. C @ 5. min, 5. K/min; Column length: 25. m; Column diameter: 0.2 mm
CapillaryUltra-1647.36Haynes and Pitzer, 198550. m/0.22 mm/0.33 «mu»m, He, 1. K/min; Tstart: -30. C; Tend: 240. C
CapillaryUltra-1650.41Haynes and Pitzer, 198550. m/0.22 mm/0.33 «mu»m, He, 2. K/min; Tstart: -30. C; Tend: 240. C
CapillaryUltra-1652.19Haynes and Pitzer, 198550. m/0.22 mm/0.33 «mu»m, He, 3. K/min; Tstart: -30. C; Tend: 240. C
CapillaryUltra-2653.15Haynes and Pitzer, 198550. m/0.22 mm/0.33 «mu»m, He, 1. K/min; Tstart: -30. C; Tend: 240. C
CapillaryUltra-2656.24Haynes and Pitzer, 198550. m/0.22 mm/0.33 «mu»m, He, 2. K/min; Tstart: -30. C; Tend: 240. C
CapillaryUltra-2658.10Haynes and Pitzer, 198550. m/0.22 mm/0.33 «mu»m, He, 3. K/min; Tstart: -30. C; Tend: 240. C
PackedSE-30662.Buchman, Cao, et al., 1984He, Chromosorb AW, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m
CapillaryOV-101650.Hayes and Pitzer, 1981108. m/0.25 mm/0.2 «mu»m, 1. K/min; Tstart: 35. C; Tend: 200. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-1665.Peng, 200015. m/0.53 mm/1. «mu»m, He; Program: 40C(3min) => 8C/min => 200(1min) => 5C/min => 300C(25min)
CapillaryMethyl Silicone648.90Hassoun, Pilling, et al., 199950. m/0.25 mm/1. «mu»m, He; Program: -50C(2min) => 49.9C/min => 35C(10min) => 3C/min => 200C(2min) => 40C/min => 240C(30min)
PackedSE-30662.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)
PackedSE-30662.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-Wax732.Malliaa, Fernandez-Garcia, et al., 200560. m/0.32 mm/1. «mu»m, He, 45. C @ 1. min, 5. K/min, 250. C @ 12. min
CapillaryPEG-20M734.0Wang and Sun, 19853. K/min; Column length: 62. m; Column diameter: 0.27 mm; Tstart: 70. C
CapillaryPEG-20M735.5Wang and Sun, 19854. K/min; Column length: 62. m; Column diameter: 0.27 mm; Tstart: 70. C
CapillaryPEG-20M737.0Wang and Sun, 19852. K/min; Column length: 62. m; Column diameter: 0.27 mm; Tstart: 80. C
CapillaryPEG-20M741.7Wang and Sun, 19852. K/min; Column length: 62. m; Column diameter: 0.27 mm; Tstart: 90. C
PackedCarbowax 20M723.Buchman, Cao, et al., 1984He, Supelcoport, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m

Normal alkane RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryMethyl Silicone100.673.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryMethyl Silicone120.680.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryMethyl Silicone140.685.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryMethyl Silicone80.668.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryOV-10140.660.Li and Deng, 1998N2; Column length: 51. m; Column diameter: 0.25 mm
CapillaryMethyl Silicone50.663.N/AN2; Column length: 74.6 m; Column diameter: 0.28 mm
CapillaryOV-10150.661.Wu and Lu, 1984 
CapillaryOV-10170.665.Wu and Lu, 1984 
PackedSynachrom150.619.Dufka, Malinsky, et al., 1971Helium, Synachrom (60-80 mesh); Column length: 1.5 m
PackedSynachrom150.625.Dufka, Malinsky, et al., 1971Helium, Synachrom (60-80 mesh); Column length: 1.5 m
CapillarySqualane86.661.Vigdergauz and Martynov, 1971He; Column length: 150. m; Column diameter: 0.35 mm
PackedApieson L120.688.Kurdina, Markovich, et al., 1969not specified, not specified
PackedSqualane125.676.Cremer and Nonn, 1964H2, Chromosorb W (80-100 mesh); Column length: 3. m

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane: CP-Sil 5 CB658.Bramston-Cook, 201360. m/0.25 mm/1.0 «mu»m, Helium, 45. C @ 1.45 min, 3.6 K/min, 210. C @ 2.72 min
CapillaryPetrocol DH651.Supelco, 2012100. m/0.25 mm/0.50 «mu»m, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min
CapillaryOV-101666.Zenkevich, Eliseenkov, et al., 200925. m/0.20 mm/0.25 «mu»m, Nitrogen, 6. K/min; Tstart: 60. C; Tend: 240. C
CapillaryBP-1662.Health Safety Executive, 200050. m/0.22 mm/0.75 «mu»m, He, 5. K/min; Tstart: 50. C; Tend: 200. C
CapillaryDB-5MS654.9Shoenmakers, Oomen, et al., 200030. m/0.25 mm/0.25 «mu»m, He, 40. C @ 1. min, 3. K/min; Tend: 250. C
CapillaryMethyl Silicone648.95Baraldi, Rapparini, et al., 199960. m/0.25 mm/0.25 «mu»m, 40. C @ 10. min, 5. K/min; Tend: 220. C
CapillaryOV-101658.Orav, Kailas, et al., 199950. m/0.20 mm/0.50 «mu»m, Helium, 30. C @ 6. min, 1. K/min; Tend: 100. C
CapillarySE-54670.Bellesia, Pinetti, et al., 199625. m/0.2 mm/0.5 «mu»m, He, 35. C @ 2. min, 5. K/min; Tend: 250. C
CapillaryDB-1658.Ciccioli, Cecinato, et al., 199260. m/0.32 mm/1.2 «mu»m, He, 30. C @ 10. min, 3. K/min; Tend: 240. C
CapillarySE-30651.Heydanek and McGorrin, 1981He, 40. C @ 3. min, 3. K/min; Column length: 50. m; Column diameter: 0.5 mm; Tend: 170. C
PackedApiezon L668.Dahlmann, Köser, et al., 1979Chromosorb G-AW-DMCS, 10. K/min; Column length: 2. m; Tstart: 25. C
CapillarySF-96659.Donetzhuber, Johansson, et al., 1976Nitrogen, 3. K/min, 130. C @ 40. min; Column length: 111. m; Column diameter: 0.76 mm; Initial hold: 8. min

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySqualane660.Chen, 2008Program: not specified
CapillarySqualane669.Chen, 2008Program: not specified
CapillaryDB-5 MS669.Cajka, Hajslova, et al., 200730. m/0.25 mm/0.25 «mu»m, Helium; Program: 45 0C (0.75 min) 10 0C/min -> 200 0C 30 0C/min -> 245 0C (1.25 min)
CapillaryMethyl Silicone663.Feng and Mu, 2007Program: not specified
CapillaryMethyl Silicone661.Blunden, Aneja, et al., 200560. m/0.32 mm/1.0 «mu»m, Helium; Program: -50 0C (2 min) 8 0C/min -> 200 0C (7.75 min) 25 0C -> 225 0C (8 min)
CapillarySE-30677.Vinogradov, 2004Program: not specified
CapillarySPB-5657.Begnaud, Pérès, et al., 200360. m/0.32 mm/1. «mu»m; Program: not specified
CapillaryApiezon L696.Finkelstein, Kurbatova, et al., 2002Program: not specified
CapillaryMethyl Silicone700.N/AProgram: not specified
CapillaryDB-1664.Zhu and Wang, 2001Program: not specified
CapillaryMethyl Silicone666.Zenkevich, 2000Program: not specified
CapillaryMethyl Silicone657.Spieksma, 1999Program: not specified
CapillaryMethyl Silicone666.Zenkevich, 1998Program: not specified
CapillarySPB-1666.Flanagan, Streete, et al., 199760. m/0.53 mm/5. «mu»m, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryMethyl Silicone654.Xu, Chu, et al., 1995Program: not specified
CapillaryDB-1649.Ciccioli, Cecinato, et al., 199460. m/0.32 mm/0.25 «mu»m; Program: not specified
CapillaryDB-1649.Ciccioli, Brancaleoni, et al., 199360. m/0.32 mm/0.25 «mu»m; Program: 3 min at 5 C; 5 - 50 C at 3 deg/min; 50 - 220 C at 5 deg/min
CapillarySE-30664.Lou, Liu, et al., 1993Column diameter: 0.25 mm; Program: not specified
CapillaryOV-101650.Skrbic and Cvejanov, 1993Program: not specified
CapillarySPB-1666.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 «mu»m, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySPB-1664.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 «mu»m, Helium; Program: not specified
CapillaryOV-101677.Shibamoto, 1987Program: not specified
CapillarySE-52666.van Langenhove and Schamp, 1986Column length: 100. m; Column diameter: 0.50 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.645.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.661.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.669.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.675.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1664.Ramsey and Flanagan, 1982Program: not specified
PackedSE-30675.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m; Program: 50C910min) => 20C/min => 90(6min) => 10C/min => 150C(hold)
PackedSqualane669.Robinson and Odell, 1971N2, Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min => 35 => 4C/min => 95C(hold)
PackedSE-30675.Robinson and Odell, 1971, 2Chrom W; Column length: 6.1 m; Program: 50C(10min) => 20C/min(2min) => 90C(6min) => 10C/min(6min) => (hold at 150C)
PackedSqualane669.Robinson and Odell, 1971, 2Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min(5min) => 4C/min(15min) => (hold at 95C)

Normal alkane RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-Wax729.Shimadzu, 201230. m/0.32 mm/0.50 «mu»m, Helium, 4. K/min; Tstart: 40. C; Tend: 260. C
CapillaryDB-Wax729.Shimadzu Corporation, 200330. m/0.32 mm/0.5 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 260. C
CapillarySupelcowax-10717.Girard and Durance, 200060. m/0.25 mm/0.25 «mu»m, He, 35. C @ 10. min, 4. K/min; Tend: 200. C
CapillaryDB-Wax712.Chung, Eiserich, et al., 199360. C @ 4. min, 3. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 220. C
CapillaryBP-20765.MacLeod and Snyder, 198570. C @ 5. min, 3. K/min; Column length: 25. m; Column diameter: 0.2 mm; Tend: 180. C

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySOLGel-Wax742.Johanningsmeier and McFeeters, 201130. m/0.25 mm/0.25 «mu»m, Helium; Program: 40 0C (2 min) 5 0C/min -> 140 0C 10 0C/min -> 250 0C (3 min)
CapillarySOLGel-Wax737.Johanningsmeier and McFeeters, 201130. m/0.25 mm/0.25 «mu»m, Helium; Program: not specified
CapillaryCarbowax 20M765.Vinogradov, 2004Program: not specified
CapillaryDB-Wax723.Peng, Yang, et al., 1991Program: not specified
CapillaryCarbowax 20M756.Shibamoto, 1987Program: not specified
CapillaryCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.723.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryCarbowax 20M726.Ramsey and Flanagan, 1982Program: not specified

References

Go To: Top, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Liu, et al., 2005
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Mitra, G.D., Conversion of linear retention indices into logarithmic retention indices, J. Chromatogr., 1981, 211, 2, 239-242, https://doi.org/10.1016/S0021-9673(00)88039-5 . [all data]

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Morishita, F.; Okano, T.; Kojima, T., Retention indices of monocyclic monoterpene hydrocarbons, Bunseki Kagaku, 1980, 29, 1, 48-53, https://doi.org/10.2116/bunsekikagaku.29.48 . [all data]

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Nabivach, V.M.; Kirilenko, A.V., Relationship between the gas chromatographic behaviour and the molecular structure of hydrocarbon samples and various stationary phases. Part II. Correlation between the retention index, physicochemical properties and molecular structure, Chromatographia, 1980, 13, 2, 93-100, https://doi.org/10.1007/BF02263060 . [all data]

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Bajus, M.; Veselý, V.; Leclercq, P.A.; Rijks, J.A., Steam cracking of hydrocarbons. 2. Pyrolysis of methylcyclohexane, Ind. Eng. Chem. Prod. Res. Dev., 1979, 18, 2, 135-142, https://doi.org/10.1021/i360070a012 . [all data]

Pacáková and Koslík, 1978
Pacáková, V.; Koslík, V., Capillary reaction gas chromatography. I. Catalytic decomposition of hydrocarbons, Chromatographia, 1978, 11, 5, 266-273, https://doi.org/10.1007/BF02282952 . [all data]

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Notes

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