Ethanol, 2-ethoxy-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil408.2 ± 0.3KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δvap11.53kcal/molN/AMajer and Svoboda, 1985 
Δvap11.8kcal/molEBAntosik, Fras, et al., 1999Based on data from 313. to 353. K.; AC
Δvap12.0kcal/molEBAntosik, Fras, et al., 1999Based on data from 313. to 363. K.; AC
Δvap11.5 ± 0.02kcal/molCKusano, Wadsö, et al., 1971AC
Δvap11.8kcal/molISunwoo and Eisen, 1971AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
9.374408.1N/AMajer and Svoboda, 1985 
11.0338.TGAAl-Najjar and Al-Sammerrai, 2007Based on data from 323. to 353. K.; AC
11.3325.EBChylinski, Fras, et al., 2001Based on data from 310. to 385. K.; AC
10.7351.AStephenson and Malanowski, 1987Based on data from 336. to 408. K. See also Pick, Fried, et al., 1956.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
336. to 407.4.863061756.857-46.92Pick, Fried, et al., 1956, 2Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Antosik, Fras, et al., 1999
Antosik, Maria; Fras, Zbigniew; Malanowski, Stanislaw K., Vapor-Liquid Equilibrium in 2-Ethoxyethanol + Methanol at 313.15 to 333.15 K, J. Chem. Eng. Data, 1999, 44, 3, 368-372, https://doi.org/10.1021/je9801011 . [all data]

Kusano, Wadsö, et al., 1971
Kusano, Kazuhito; Wadsö, Ingemar; Rømming, Chr.; Lindberg, Alf A.; Lagerlund, Inger; Ehrenberg, L., Enthalpies of Vaporization of Organic Compounds. VIII. Alkoxyethanols., Acta Chem. Scand., 1971, 25, 219-224, https://doi.org/10.3891/acta.chem.scand.25-0219 . [all data]

Sunwoo and Eisen, 1971
Sunwoo, Chimin; Eisen, Henry, Solubility parameter of selected sulfonamides, J. Pharm. Sci., 1971, 60, 2, 238-244, https://doi.org/10.1002/jps.2600600217 . [all data]

Al-Najjar and Al-Sammerrai, 2007
Al-Najjar, Hazim; Al-Sammerrai, Dhoaib, Thermogravimetric determination of the heat of vaporization of some highly polar solvents, J. Chem. Technol. Biotechnol., 2007, 37, 3, 145-152, https://doi.org/10.1002/jctb.280370302 . [all data]

Chylinski, Fras, et al., 2001
Chylinski, K.; Fras, Z.; Malanowski, S.K., Vapor-Liquid Equilibrium in Phenol + 2-Ethoxyethanol at 363.15 to 383.15 K, J. Chem. Eng. Data, 2001, 46, 1, 29-33, https://doi.org/10.1021/je0001072 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Pick, Fried, et al., 1956
Pick, J.; Fried, V.; Hala, E.; Vilim, O., Collect. Czech. Chem. Commun., 1956, 21, 260. [all data]

Pick, Fried, et al., 1956, 2
Pick, J.; Fried, V.; Hala, E.; Vilim, O., Der Dampfdruck des Athylenglykolmonomethylathers und des Athylenglykolmonoathylathers, Collect. Czech. Chem. Commun., 1956, 21, 1, 260-261, https://doi.org/10.1135/cccc19560260 . [all data]


Notes

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