tris(η5-2,4-cyclopentadien-1-yl)praseodymium


Gas phase thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas97.3 ± 9.2kJ/molReviewMartinho Simões 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.2 ± 0.2EIGaivoronskii, Gavrishchuk, et al., 1978LLK
8.2 ± 0.2EIDevyatykh, Krasnova, et al., 1970RDSH
7.7 ± 0.1EIMuller, 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H5Pr+17.0 ± 0.42C5H5EIGaivoronskii, Gavrishchuk, et al., 1978LLK
C5H5Pr+17. ± 0.4?EIDevyatykh, Krasnova, et al., 1970RDSH
C5H5Pr+17.0 ± 0.4?EIMuller, 1969RDSH
C10H10Pr+10.0 ± 0.2C5H5EIGaivoronskii, Gavrishchuk, et al., 1978LLK
C10H10Pr+10. ± 0.2?EIDevyatykh, Krasnova, et al., 1970RDSH
C10H10Pr+8.5 ± 0.2?EIMuller, 1969RDSH
Pr+24.1 ± 0.4?EIDevyatykh, Krasnova, et al., 1970RDSH

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Gaivoronskii, Gavrishchuk, et al., 1978
Gaivoronskii, P.E.; Gavrishchuk, E.M.; Chernyaev, N.P.; Zverev, Y.B., Mass spectrometric study of tris(isopropylcyclopentadienyl) π- complexes of lanthanum, praseodymium, and neodymium, Russ. J. Inorg. Chem., 1978, 23, 1742. [all data]

Devyatykh, Krasnova, et al., 1970
Devyatykh, G.G.; Krasnova, S.G.; Borisov, G.K.; Larin, N.V.; Gaivoronskii, P.E., Preparation and investigation by mass spectrometry of cyclopentadienyl 7r-complexes of lanthanum, praseodymium, and neodymium, Dokl. Akad. Nauk SSSR, 1970, 193, 1069, In original 580. [all data]

Muller, 1969
Muller, J., Massenspektroskopische Untersuchungen an Tri- und Tetracyclopentadienyl-metall-Komplexen, Chem. Ber., 1969, 102, 152. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References