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Ethane, 1,2-dimethoxy-

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH6N+ + Ethane, 1,2-dimethoxy- = (CH6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: CH6N+ + C4H10O2 = (CH6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar30.1kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.1cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

C3H10N+ + Ethane, 1,2-dimethoxy- = (C3H10N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C3H10N+ + C4H10O2 = (C3H10N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar26.7kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.8cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

C4H11O2+ + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet Ethane, 1,2-dimethoxy-)

By formula: C4H11O2+ + C4H10O2 = (C4H11O2+ bullet C4H10O2)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar27.4kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.9cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet 3Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet 2C4H10O2) + C4H10O2 = (C4H11O2+ bullet 3C4H10O2)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.0208.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

(C4H11O2+ bullet Ethane, 1,2-dimethoxy- bullet 2Water) + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet 2Ethane, 1,2-dimethoxy- bullet 2Water)

By formula: (C4H11O2+ bullet C4H10O2 bullet 2H2O) + C4H10O2 = (C4H11O2+ bullet 2C4H10O2 bullet 2H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar19.8kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.5cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C5H6N+ + Ethane, 1,2-dimethoxy- = (C5H6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C5H6N+ + C4H10O2 = (C5H6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar25.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; glyme; M
Quantity Value Units Method Reference Comment
Deltar31.4cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; glyme; M

C6H14N+ + Ethane, 1,2-dimethoxy- = (C6H14N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C6H14N+ + C4H10O2 = (C6H14N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar29.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar35.5cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

Cesium ion (1+) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Cs+ + C4H10O2 = (Cs+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Cs+ bullet C4H10O2) + C4H10O2 = (Cs+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar12.9 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD

Copper ion (1+) + Ethane, 1,2-dimethoxy- = (Copper ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Cu+ + C4H10O2 = (Cu+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar63.1 ± 1.9kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Copper ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Cu+ bullet C4H10O2) + C4H10O2 = (Cu+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar43.0 ± 1.4kcal/molCIDTKoizumi, 2001RCD

NH4+ + Ethane, 1,2-dimethoxy- = (NH4+ bullet Ethane, 1,2-dimethoxy-)

By formula: H4N+ + C4H10O2 = (H4N+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar38. ± 3.kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition; M
Quantity Value Units Method Reference Comment
Deltar36.cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition; M

(NH4+ bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ bullet 2Ethane, 1,2-dimethoxy-)

By formula: (H4N+ bullet C4H10O2) + C4H10O2 = (H4N+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar23.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar33.5cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M

(NH4+ bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ bullet 3Ethane, 1,2-dimethoxy-)

By formula: (H4N+ bullet 2C4H10O2) + C4H10O2 = (H4N+ bullet 3C4H10O2)

Quantity Value Units Method Reference Comment
Deltar14. ± 3.kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.3cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M

Potassium ion (1+) + Ethane, 1,2-dimethoxy- = (Potassium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: K+ + C4H10O2 = (K+ bullet C4H10O2)

Bond type: Polydentate bonding in non-hydrogen-bonded positive ions

Quantity Value Units Method Reference Comment
Deltar28.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar30.8kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.8cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Potassium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Potassium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (K+ bullet C4H10O2) + C4H10O2 = (K+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar21.3 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar37.8 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

(Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ bullet C4H10O2) + C4H10O2 = (Li+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar33.2 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Na+ + C4H10O2 = (Na+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar37.8 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000glyme; RCD
Deltar57.6 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar38.5 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD
Deltar47.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.6cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
31.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Na+ bullet C4H10O2) + C4H10O2 = (Na+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar27.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar27.2 ± 2.0kcal/molCIDTMore, Ray, et al., 1997RCD
Deltar35.1kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar40.5cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet 3Ethane, 1,2-dimethoxy-)

By formula: (Na+ bullet 2C4H10O2) + C4H10O2 = (Na+ bullet 3C4H10O2)

Quantity Value Units Method Reference Comment
Deltar23.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar42.2cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Rubidium ion (1+) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Rb+ + C4H10O2 = (Rb+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar22.5 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Rb+ bullet C4H10O2) + C4H10O2 = (Rb+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar11.7 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Koizumi, 2001
Koizumi, H., Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethoxyethane Complexes, J. Am. Soc. Mass Spectrom., 2001, 12, 5, 480, https://doi.org/10.1016/S1044-0305(01)00242-2 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1996
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S., Complexing of the Ammonium Ion by Polyethers. Comparative Complexing Thermochemistry of Ammonium, Hydronium, and Alkali Cations, J. Phys. Chem., 1996, 100, 16, 6445, https://doi.org/10.1021/jp9514943 . [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Binding Energies and Stabilities of Potassium Ion Complexes with Ethylene Diamine and Dimethoxyethane (Glyme) from Measurements of the Complexing Equilibria in the Gas Phase, Can. J. Chem., 1976, 54, 16, 2594, https://doi.org/10.1139/v76-368 . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

More, Ray, et al., 1997
More, M.B.; Ray, D.; Armentrout, P.B., Cation-ether complexes in the gas phase: Bond dissociation energies of Na+(dimethyl ether)(x), x=1-4; Na+(1,2-dimethoxyethane)(x), x=1 and 2; and Na+(12-crown-4), J. Phys. Chem. AJOURNAL OF PHYSICAL CHEMISTRY A 101 (5): 831-839 JAN 30 1997, 1997, 101, 831. [all data]

Castleman, Peterson, et al., 1983
Castleman, A.W.; Peterson, K.I.; Upschulte, B.L.; Schelling, F.J., Energetics and Structure of Na+ Cluster Ions, Int. J. Mass Spectrom. Ion Phys., 1983, 47, 203, https://doi.org/10.1016/0020-7381(83)87171-X . [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]


Notes

Go To: Top, Ion clustering data, References