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Ethane, 1,2-dimethoxy-

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH6N+ + Ethane, 1,2-dimethoxy- = (CH6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: CH6N+ + C4H10O2 = (CH6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar126.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

C3H10N+ + Ethane, 1,2-dimethoxy- = (C3H10N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C3H10N+ + C4H10O2 = (C3H10N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar112.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar146.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

C4H11O2+ + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet Ethane, 1,2-dimethoxy-)

By formula: C4H11O2+ + C4H10O2 = (C4H11O2+ bullet C4H10O2)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar115.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar129.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet 3Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet 2C4H10O2) + C4H10O2 = (C4H11O2+ bullet 3C4H10O2)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar42.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.208.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

(C4H11O2+ bullet Ethane, 1,2-dimethoxy- bullet 2Water) + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet 2Ethane, 1,2-dimethoxy- bullet 2Water)

By formula: (C4H11O2+ bullet C4H10O2 bullet 2H2O) + C4H10O2 = (C4H11O2+ bullet 2C4H10O2 bullet 2H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C5H6N+ + Ethane, 1,2-dimethoxy- = (C5H6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C5H6N+ + C4H10O2 = (C5H6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar106.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; glyme; M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; glyme; M

C6H14N+ + Ethane, 1,2-dimethoxy- = (C6H14N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C6H14N+ + C4H10O2 = (C6H14N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar123.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar149.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

Cesium ion (1+) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Cs+ + C4H10O2 = (Cs+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Cs+ bullet C4H10O2) + C4H10O2 = (Cs+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Copper ion (1+) + Ethane, 1,2-dimethoxy- = (Copper ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Cu+ + C4H10O2 = (Cu+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar264. ± 7.9kJ/molCIDTKoizumi, 2001RCD

(Copper ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Copper ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Cu+ bullet C4H10O2) + C4H10O2 = (Cu+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar180. ± 5.9kJ/molCIDTKoizumi, 2001RCD

NH4+ + Ethane, 1,2-dimethoxy- = (NH4+ bullet Ethane, 1,2-dimethoxy-)

By formula: H4N+ + C4H10O2 = (H4N+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar160. ± 10.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition; M
Quantity Value Units Method Reference Comment
Deltar150.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition; M

(NH4+ bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ bullet 2Ethane, 1,2-dimethoxy-)

By formula: (H4N+ bullet C4H10O2) + C4H10O2 = (H4N+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar97.1kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar140.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M

(NH4+ bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ bullet 3Ethane, 1,2-dimethoxy-)

By formula: (H4N+ bullet 2C4H10O2) + C4H10O2 = (H4N+ bullet 3C4H10O2)

Quantity Value Units Method Reference Comment
Deltar60. ± 10.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M

Potassium ion (1+) + Ethane, 1,2-dimethoxy- = (Potassium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: K+ + C4H10O2 = (K+ bullet C4H10O2)

Bond type: Polydentate bonding in non-hydrogen-bonded positive ions

Quantity Value Units Method Reference Comment
Deltar119. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar129.kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Potassium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Potassium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (K+ bullet C4H10O2) + C4H10O2 = (K+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar89. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar158. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ bullet C4H10O2) + C4H10O2 = (Li+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar139. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Na+ + C4H10O2 = (Na+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar158. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000glyme; RCD
Deltar241. ± 18.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar161. ± 4.2kJ/molCIDTMore, Ray, et al., 1997RCD
Deltar197.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar145.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
133.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Na+ bullet C4H10O2) + C4H10O2 = (Na+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar116. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar114. ± 8.4kJ/molCIDTMore, Ray, et al., 1997RCD
Deltar147.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar169.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet 3Ethane, 1,2-dimethoxy-)

By formula: (Na+ bullet 2C4H10O2) + C4H10O2 = (Na+ bullet 3C4H10O2)

Quantity Value Units Method Reference Comment
Deltar97.1kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar177.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Rubidium ion (1+) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Rb+ + C4H10O2 = (Rb+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar94.1 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Rb+ bullet C4H10O2) + C4H10O2 = (Rb+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar49. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Koizumi, 2001
Koizumi, H., Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethoxyethane Complexes, J. Am. Soc. Mass Spectrom., 2001, 12, 5, 480, https://doi.org/10.1016/S1044-0305(01)00242-2 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1996
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S., Complexing of the Ammonium Ion by Polyethers. Comparative Complexing Thermochemistry of Ammonium, Hydronium, and Alkali Cations, J. Phys. Chem., 1996, 100, 16, 6445, https://doi.org/10.1021/jp9514943 . [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Binding Energies and Stabilities of Potassium Ion Complexes with Ethylene Diamine and Dimethoxyethane (Glyme) from Measurements of the Complexing Equilibria in the Gas Phase, Can. J. Chem., 1976, 54, 16, 2594, https://doi.org/10.1139/v76-368 . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

More, Ray, et al., 1997
More, M.B.; Ray, D.; Armentrout, P.B., Cation-ether complexes in the gas phase: Bond dissociation energies of Na+(dimethyl ether)(x), x=1-4; Na+(1,2-dimethoxyethane)(x), x=1 and 2; and Na+(12-crown-4), J. Phys. Chem. AJOURNAL OF PHYSICAL CHEMISTRY A 101 (5): 831-839 JAN 30 1997, 1997, 101, 831. [all data]

Castleman, Peterson, et al., 1983
Castleman, A.W.; Peterson, K.I.; Upschulte, B.L.; Schelling, F.J., Energetics and Structure of Na+ Cluster Ions, Int. J. Mass Spectrom. Ion Phys., 1983, 47, 203, https://doi.org/10.1016/0020-7381(83)87171-X . [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]


Notes

Go To: Top, Ion clustering data, References