1,4-Butanediol
- Formula: C4H10O2
- Molecular weight: 90.1210
- IUPAC Standard InChIKey: WERYXYBDKMZEQL-UHFFFAOYSA-N
- CAS Registry Number: 110-63-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Diol 14B; Sucol B; Tetramethylene glycol; 1,4-Butylene glycol; 1,4-Dihydroxybutane; 1,4-Tetramethylene glycol; Butane-1,4-diol; Butanediol; 1,4-BD; Tetramethylene 1,4-diol; BDO; Butylene glycol; Dabco BDO; Butane diol-1,4; NSC 406696
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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
ΔvapH° (kJ/mol) | Method | Reference | Comment |
---|---|---|---|
79.0 ± 0.9 | GS | Vasiltsova, Verevkin, et al., 2005 | Based on data from 330. to 363. K.; AC |
78.3 ± 0.3 | C | Ermelinda Eusébio, Lopes Jesus, et al., 2003 | AC |
79.3 | N/A | Knauth and Sabbah, 1990 | DRB |
79.3 ± 0.5 | C | Knauth and Sabbah, 1988 | See also Knauth and Sabbah, 1990.; AC |
79.3 ± 0.5 | C | Knauth and Sabbah, 1988, 2 | ALS |
76.1 ± 0.5 | EB | Palczewska-Tulinska, Cholinski, et al., 1984 | Based on data from 416. to 501. K. See also Vasiltsova, Verevkin, et al., 2005.; AC |
76.0 | N/A | Gardner and Hussain, 1972 | DRB |
76.6 ± 1.7 | N/A | Gardner and Hussain, 1972 | Based on data from 419. to 490. K. See also Ermelinda Eusébio, Lopes Jesus, et al., 2003.; AC |
References
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Vasiltsova, Verevkin, et al., 2005
Vasiltsova, Tatiana V.; Verevkin, Sergey P.; Bich, Eckard; Heintz, Andreas; Bogel-Lukasik, Rafal; Domanska, Urszula,
Thermodynamic Properties of Mixtures Containing Ionic Liquids. Activity Coefficients of Ethers and Alcohols in 1-Methyl-3-Ethyl-Imidazolium Bis(Trifluoromethyl-sulfonyl) Imide Using the Transpiration Method,
J. Chem. Eng. Data, 2005, 50, 1, 142-148, https://doi.org/10.1021/je0497799
. [all data]
Ermelinda Eusébio, Lopes Jesus, et al., 2003
Ermelinda Eusébio, M.; Lopes Jesus, A.J.; Cruz, Mafalda S.C.; Leitão, M. Luisa P.; Simões Redinha, J.,
Enthalpy of vaporisation of butanediol isomers,
The Journal of Chemical Thermodynamics, 2003, 35, 1, 123-129, https://doi.org/10.1016/S0021-9614(02)00306-3
. [all data]
Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R.,
Energetics of intra- and intermolecular bonds in ω-alkanediols (II) Thermochemical study of 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, and 1,5-pentanediol at 298.15K,
Struct. Chem., 1990, 1, 43-46. [all data]
Knauth and Sabbah, 1988
Knauth, P.; Sabbah, R.,
Energetics of intra- and intermolecular bonds in ω-alkanediols. I. Calorimetric investigation of the enthalpies of vaporization at 298.15 K,
Bull. Soc. Chim. Fr., 1988, 5, 834. [all data]
Knauth and Sabbah, 1988, 2
Knauth, P.; Sabbah, R.,
Energetique des liaisons intra- et intermoleculaires dans la serie des <omega>-alcanediols. I : etude calorimetrique des enthalpies de vaporisation a 298,15 K,
Bull. Soc. Chim. Fr., 1988, 834-836. [all data]
Palczewska-Tulinska, Cholinski, et al., 1984
Palczewska-Tulinska, Marcela; Cholinski, Jacek; Szafranski, Andrzej M.; Wyrzykowska-Stankiewicz, Danuta,
Experimental vapor pressures and maximum-likelihood Antoine-equation constants for 1,1,1-methoxydimethylpropane, thiacyclopentane and 1,4-butanediol,
Fluid Phase Equilibria, 1984, 15, 3, 295-307, https://doi.org/10.1016/0378-3812(84)87014-4
. [all data]
Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S.,
The standard enthalpies of formation of some aliphatic diols,
J. Chem. Thermodyn., 1972, 4, 819-827. [all data]
Notes
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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