1-Pentene

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-22. ± 9.kJ/molAVGN/AAverage of 6 values; Individual data points

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
82.35200.Thermodynamics Research Center, 1997p=1 bar. Recommended values were calculated from data for lower alkenes by a method of increments. These values are in good agreement with experimental data. The results of the similar estimation [ Kilpatrick J.E., 1946] are in poor agreement with experiment.; GT
101.2273.15
108.2298.15
108.7300.
137.6400.
164.0500.
186.3600.
205.1700.
221.0800.
234.6900.
246.21000.
256.41100.
265.11200.
272.81300.
279.21400.
285.41500.

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
112.34 ± 0.33311.09Scott D.W., 1949GT
126.15 ± 0.38357.51
139.08 ± 0.42402.32
148.41 ± 0.45436.01
157.69 ± 0.47471.08

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-49. ± 5.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcliquid-3349.72 ± 0.58kJ/molCcbGood and Smith, 1979Corresponding Δfliquid = -46.98 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid262.60J/mol*KN/AMesserly, Todd, et al., 1990DH
liquid262.6J/mol*KN/AChao, Hall, et al., 1983DH
liquid262.55J/mol*KN/ATodd, Oliver, et al., 1947DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
154.87298.15Messerly, Todd, et al., 1990T = 10 to 320 K.; DH
154.298.15Chao, Hall, et al., 1983T = 12 to 353 K.; DH
154.3294.Schlinger and Sage, 1949T = 294 to 378 K. Cp given as 0.526 Btu/lb*R at 70°F.; DH
155.31298.15Todd, Oliver, et al., 1947T = 12 to 300 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil304. ± 8.KAVGN/AAverage of 30 out of 31 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus107.75KN/AStreiff, Murphy, et al., 1946Uncertainty assigned by TRC = 0.2 K; TRC
Tfus107.78KN/AStreiff, Murphy, et al., 1946Uncertainty assigned by TRC = 0.2 K; TRC
Tfus107.88KN/AStreiff, Murphy, et al., 1946Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Ttriple108.010KN/AMesserly, Todd, et al., 1990, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.003 K; TRC
Ttriple107.790KN/AMesserly, Todd, et al., 1990, 2Metastable crystal phase; Uncertainty assigned by TRC = 0.003 K; TRC
Ttriple5.800KN/AChao, Hall, et al., 1983, 2Uncertainty assigned by TRC = 0.01 K; TRC
Ttriple107.9KN/ATodd, Oliver, et al., 1947, 2Uncertainty assigned by TRC = 0.5 K; this value not measured but taken from 1956-strmur 0; TRC
Quantity Value Units Method Reference Comment
Tc464.8 ± 0.5KN/ATsonopoulos and Ambrose, 1996 
Tc464.7KN/AMajer and Svoboda, 1985 
Tc465.1KN/AWolfe, Kay, et al., 1983Uncertainty assigned by TRC = 0.3 K; $ %Y/SI 0.01 @Y/SI 0.3; TRC
Tc463.77KN/AMousa, Kay, et al., 1972Uncertainty assigned by TRC = 0.2 K; TRC
Tc464.74KN/AAmbrose, Cox, et al., 1960Uncertainty assigned by TRC = 0.03 K; Visual, PRT, IPTS-48; TRC
Quantity Value Units Method Reference Comment
Pc35.6 ± 0.5barN/ATsonopoulos and Ambrose, 1996 
Pc35.50barN/AWolfe, Kay, et al., 1983Uncertainty assigned by TRC = 0.20 bar; $ %Y/SI 1.5 @Y/SI 20.; TRC
Pc35.510barN/AMousa, Kay, et al., 1972Uncertainty assigned by TRC = 0.0344 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.2984l/molN/ATsonopoulos and Ambrose, 1996 
Quantity Value Units Method Reference Comment
ρc3.35 ± 0.05mol/lN/ATsonopoulos and Ambrose, 1996 
ρc3.32mol/lN/AWolfe, Kay, et al., 1983Uncertainty assigned by TRC = 0.03 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap29.82kJ/molN/AMajer and Svoboda, 1985 
Δvap25.5kJ/molN/AReid, 1972AC
Δvap25.5 ± 0.1kJ/molCScott, Waddington, et al., 1949AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
25.2303.1N/AMajer and Svoboda, 1985 
29.1233.AStephenson and Malanowski, 1987Based on data from 218. to 311. K.; AC
26.7295.MMForziati, Camin, et al., 1950Based on data from 286. to 304. K.; AC
26.9288.N/AScott, Waddington, et al., 1949Based on data from 273. to 334. K.; AC
26.2 ± 0.1284.CScott, Waddington, et al., 1949AC
25.2 ± 0.1303.CScott, Waddington, et al., 1949AC
26.3290.N/ADay, Nicholson, et al., 1948Based on data from 273. to 308. K.; AC
25.7341.N/ADay, Nicholson, et al., 1948Based on data from 313. to 368. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) β Tc (K) Reference Comment
284. to 303.39.710.2663464.7Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference
285.98 to 303.873.910581014.294-43.367Forziati, Camin, et al., 1950, 2

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
5.93739108.016Messerly, Todd, et al., 1990DH
5.88168107.797Messerly, Todd, et al., 1990c(metastable)/liq; DH
5.807107.90Chao, Hall, et al., 1983DH
5.807107.9Todd, Oliver, et al., 1947DH
5.81107.9Acree, 1991See also Messerly, Todd, et al., 1990.; AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
54.97108.016Messerly, Todd, et al., 1990DH
54.56107.797Messerly, Todd, et al., 1990c(metastable)/liq; DH
53.82107.90Chao, Hall, et al., 1983DH
53.82107.9Todd, Oliver, et al., 1947DH

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
71.7crystalineglassTakeda, Oguni, et al., 1990DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Pentene + Hydrogen = Pentane

By formula: C5H10 + H2 = C5H12

Quantity Value Units Method Reference Comment
Δr-126.6 ± 2.4kJ/molChydMolnar, Rachford, et al., 1984liquid phase; solvent: Dioxane
Δr-125.0 ± 1.8kJ/molChydMolnar, Rachford, et al., 1984liquid phase; solvent: Hexane
Δr-122.6 ± 2.4kJ/molChydRogers and Skanupong, 1974liquid phase; solvent: Hexane
Δr-119. ± 1.kJ/molChydRogers and McLafferty, 1971liquid phase; solvent: Hydrocarbon

2-Pentene, (E)- = 1-Pentene

By formula: C5H10 = C5H10

Quantity Value Units Method Reference Comment
Δr-10.9 ± 0.8kJ/molEqkEgger and Benson, 1966gas phase; Heat of Isomerization

Pentane, 2-chloro- = 1-Pentene + Hydrogen chloride

By formula: C5H11Cl = C5H10 + HCl

Quantity Value Units Method Reference Comment
Δr73.6kJ/molEqkKaraseva and Andreevskii, 1969gas phase

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
0.0025 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
0.0025 LN/A 
0.0025 VN/A 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C5H10+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)9.49 ± 0.03eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.50PITraeger, 1986LBLHLM
9.52 ± 0.05EIHolmes and Lossing, 1983LBLHLM
9.42 ± 0.02PEAshmore and Burgess, 1978LLK
9.52 ± 0.02PEBieri, Burger, et al., 1977LLK
9.524 ± 0.003PEMasclet, Grosjean, et al., 1973LLK
9.48EILossing, 1972LLK
9.82 ± 0.06EIGross and Wilkins, 1971LLK
9.50 ± 0.02PIWatanabe, Nakayama, et al., 1962RDSH
9.50 ± 0.02PISteiner, Giese, et al., 1961RDSH
9.68 ± 0.01PEKrause, Taylor, et al., 1978Vertical value; LLK
9.54 ± 0.02PEBunzli, Burak, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H6+10.68 ± 0.02C2H4PIBrand and Baer, 1984LBLHLM
C3H6+11.61 ± 0.08C2H4EIGross and Wilkins, 1971LLK
C4H7+10.50CH3PITraeger, 1986LBLHLM
C4H7+10.64CH3EIBrand and Baer, 1984LBLHLM
C4H7+10.63 ± 0.02CH3PIBrand and Baer, 1984LBLHLM
C4H7+10.64CH3EILossing, 1972LLK
C4H7+11.35 ± 0.07CH3EIGross and Wilkins, 1971LLK

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-2716
NIST MS number 230821

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryMethyl Silicone30.489.0Soják, Addová, et al., 2002He; Column length: 150. m; Column diameter: 0.250 mm
CapillarySqualane30.481.1Soják, Addová, et al., 2002He; Column length: 93. m; Column diameter: 0.250 mm
PackedC78, Branched paraffin130.485.0Dallos, Sisak, et al., 2000He; Column length: 3.3 m
CapillarySqualane100.483.Heinzen, Soares, et al., 1999 
CapillaryBPX-530.480.Aflalaye, Sternberg, et al., 199512. m/0.15 mm/0.25 μm, H2
CapillaryCP Sil 5 CB20.488.8Do and Raulin, 199225. m/0.15 mm/2. μm, H2
CapillaryPoraPLOT Q100.489.Do and Raulin, 198910. m/0.32 mm/10. μm, H2
CapillaryPoraPLOT Q160.491.Do and Raulin, 198910. m/0.32 mm/10. μm, H2
CapillaryOV-10140.488.Laub and Purnell, 1988 
CapillaryOV-10160.488.Laub and Purnell, 1988 
CapillaryOV-10180.489.Laub and Purnell, 1988 
CapillarySqualane50.481.3Papazova, Milina, et al., 1988Column length: 50. m; Column diameter: 0.25 mm
CapillaryOV-1100.488.8Anders, Anders, et al., 198555. m/0.21 mm/0.35 μm, N2
PackedSE-3042.496.Rudenko, Mal'tsev, et al., 1985Column length: 3. m
CapillaryDB-140.489.Lubeck and Sutton, 198460. m/0.264 mm/0.25 μm, H2
CapillaryHP-PONA40.489.Lubeck and Sutton, 198450. m/0.21 mm/0.5 μm, H2
CapillarySE-3080.492.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillaryOV-120.486.Nijs and Jacobs, 1981He; Column length: 150. m; Column diameter: 0.50 mm
CapillarySqualane50.481.6Bajus, Veselý, et al., 1979Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.482.Bajus, Veselý, et al., 1979Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane50.481.5Bajus, Veselý, et al., 1979, 2Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.481.6Bajus, Veselý, et al., 1979, 2Column length: 100. m; Column diameter: 0.25 mm
PackedSqualane80.482.Chrétien and Dubois, 1977 
CapillarySqualane50.482.Chretien and Dubois, 1976 
CapillarySqualane100.486.8Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
PackedApolane70.482.5Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
CapillarySqualane50.482.Rijks and Cramers, 1974N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.482.Rijks and Cramers, 1974N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane27.481.07Schomburg and Dielmann, 1973Column length: 100. m; Column diameter: 0.25 mm
PackedSE-3075.491.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m
CapillarySqualane40.482.Matukuma, 1969N2; Column length: 91.4 m; Column diameter: 0.25 mm
PackedSqualane27.481.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane49.481.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane67.483.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane86.483.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSE-3070.490.Widmer, 1967Diatoport S; Column length: 7.9 m
PackedSqualane26.483.Zulaïca and Guiochon, 1966Column length: 10. m
PackedApiezon L130.479.Wehrli and Kováts, 1959Celite; Column length: 2.25 m
PackedApiezon L70.485.Wehrli and Kováts, 1959Celite; Column length: 2.25 m

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryPetrocol DH-100491.Haagen-Smit Laboratory, 1997He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min)
CapillaryDB-1491.Hoekman, 199360. m/0.32 mm/1.0 μm, He; Program: -40 C for 12 min; -40 - 125 C at 3 deg.min; 125-185 C at 6 deg/min; 185 - 220 C at 20 deg/min; hold 220 C for 2 min

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedCarbowax 20M130.532.Widmer, 1967Diatoport P; Column length: 7.9 m
PackedCarbowax 20M70.523.Widmer, 1967Diatoport P; Column length: 7.9 m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryMethyl Silicone486.5Soják, Addová, et al., 2002He, 1. K/min; Column length: 150. m; Column diameter: 0.250 mm; Tstart: 30. C; Tend: 200. C
CapillaryUltra-1487.Olson, Sinkevitch, et al., 19924. K/min; Tstart: -40. C; Tend: 230. C
CapillaryPetrocol DH483.39White, Douglas, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH483.67White, Douglas, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH483.White, Hackett, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-5478.Zaikin and Borisov, 2002He; Column length: 30. m; Column diameter: 0.25 mm; Program: 30C => 5K/min=120C => 10C/min => 270C

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySqualane40.481.3Sojak, Addova, et al., 2000He; Column length: 93. m; Column diameter: 0.25 mm
CapillaryOV-10140.482.Li and Deng, 1998N2; Column length: 51. m; Column diameter: 0.25 mm
CapillarySE-5450.492.Xieyun, Maoqi, et al., 1996N2; Column length: 40. m; Column diameter: 0.25 mm
CapillaryMethyl Silicone50.482.N/AN2; Column length: 74.6 m; Column diameter: 0.28 mm
PackedMethyl Silicone50.500.Huguet, 1961Nitrogen, Celite C-22; Column length: 2.5 m

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane: CP-Sil 5 CB488.Bramston-Cook, 201360. m/0.25 mm/1.0 μm, Helium, 45. C @ 1.45 min, 3.6 K/min, 210. C @ 2.72 min
CapillaryPetrocol DH489.Supelco, 2012100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min
CapillaryUltra-ALLOY-5491.Tsuge, Ohtan, et al., 201130. m/0.25 mm/0.25 μm, 40. C @ 2. min, 20. K/min, 320. C @ 13. min
CapillaryUltra-ALLOY-5492.Tsuge, Ohtan, et al., 201130. m/0.25 mm/0.25 μm, 40. C @ 2. min, 20. K/min, 320. C @ 13. min
CapillaryUltra-ALLOY-5492.Tsuge, Ohtan, et al., 201130. m/0.25 mm/0.25 μm, 40. C @ 2. min, 20. K/min, 320. C @ 13. min
CapillaryUltra-ALLOY-5495.Tsuge, Ohtan, et al., 201130. m/0.25 mm/0.25 μm, 40. C @ 2. min, 20. K/min, 320. C @ 13. min
CapillarySPB-5488.Sivadier, Ratel, et al., 200960. m/0.32 mm/1.00 μm, 40. C @ 5. min, 3. K/min, 230. C @ 10. min
CapillaryPONA483.Zhang, Ding, et al., 200950. m/0.20 mm/0.50 μm, Nitrogen, 35. C @ 15. min, 2. K/min, 200. C @ 10. min
CapillaryDB-5MS483.Shoenmakers, Oomen, et al., 200030. m/0.25 mm/0.25 μm, He, 40. C @ 1. min, 3. K/min; Tend: 250. C
CapillaryOV-101487.Chupalov and Zenkevich, 1996N2, 3. K/min; Column length: 52. m; Column diameter: 0.26 mm; Tstart: 50. C; Tend: 220. C
CapillarySE-54483.Guan, Li, et al., 199560. C @ 2. min, 4. K/min; Column length: 50. m; Column diameter: 0.32 mm; Tend: 200. C
CapillaryDB-1486.Ramnas, Ostermark, et al., 199450. m/0.32 mm/1.0 μm, He, 2. K/min; Tstart: -20. C
CapillaryDB-1483.Ciccioli, Cecinato, et al., 199260. m/0.32 mm/1.2 μm, He, 30. C @ 10. min, 3. K/min; Tend: 240. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryMethyl Silicone483.Chen and Feng, 2007Program: not specified
CapillaryPolydimethyl siloxane483.Junkes, Castanho, et al., 2003Program: not specified
CapillaryPONA491.Perkin Elmer Instruments, 2002Column length: 100. m; Phase thickness: 0.50 μm; Program: not specified
CapillaryMethyl Silicone479.N/AProgram: not specified
CapillaryDB-1489.Zhu and Wang, 2001Program: not specified
CapillaryCP-Sil5 CB MS484.Tirillini, Verdelli, et al., 200050. m/0.32 mm/0.4 μm; Program: 0C (3min) => 3C/min => 50C => 5C/min => 220C (30min)
CapillaryMethyl Silicone488.Zenkevich, 2000Program: not specified
CapillaryMethyl Silicone488.Spieksma, 1999Program: not specified
CapillarySPB-1483.Flanagan, Streete, et al., 199760. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryPolydimethyl siloxanes488.Zenkevich, 1997Program: not specified
CapillaryMethyl Silicone488.Zenkevich, 1996Program: not specified
CapillarySPB-1483.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySE-52485.van Langenhove and Schamp, 1986Column length: 100. m; Column diameter: 0.50 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.492.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
PackedSE-30492.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m; Program: 50C910min) => 20C/min => 90(6min) => 10C/min => 150C(hold)
PackedSE-30492.Robinson and Odell, 1971, 2Chrom W; Column length: 6.1 m; Program: 50C(10min) => 20C/min(2min) => 90C(6min) => 10C/min(6min) => (hold at 150C)
PackedSqualane479.Robinson and Odell, 1971, 2Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min(5min) => 4C/min(15min) => (hold at 95C)

Normal alkane RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillarySupelcowax-10534.Girard and Durance, 200060. m/0.25 mm/0.25 μm, He, 35. C @ 10. min, 4. K/min; Tend: 200. C

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

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