Pyridine, 3-methyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas24.76 ± 0.31kcal/molCcbGerasimov, Gubareva, et al., 1992%hf298_condensed[kJ/mol]=-61.1±1.3; ALS
Δfgas25.37 ± 0.17kcal/molCcbScott, Good, et al., 1963ALS
Δfgas27.14 ± 0.24kcal/molCmAndon, Cox, et al., 1957ALS
Δfgas27.16 ± 0.24kcal/molCcbCox, Challoner, et al., 1954ALS
Δfgas18.0kcal/molN/AConstam and White, 1903Value computed using ΔfHliquid° value of 33.0 kj/mol from Constam and White, 1903 and ΔvapH° value of 42.5 kj/mol from Gerasimov, Gubareva, et al., 1992.; DRB

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid14.6 ± 0.31kcal/molCcbGerasimov, Gubareva, et al., 1992%hf298_condensed[kJ/mol]=-61.1±1.3; ALS
Δfliquid14.75 ± 0.14kcal/molCcbScott, Good, et al., 1963ALS
Δfliquid16.32 ± 0.24kcal/molCcbCox, Challoner, et al., 1954ALS
Δfliquid7.8kcal/molCcbConstam and White, 1903ALS
Quantity Value Units Method Reference Comment
Δcliquid-788.81 ± 0.31kcal/molCcbGerasimov, Gubareva, et al., 1992%hf298_condensed[kJ/mol]=-61.1±1.3; ALS
Δcliquid-818.17 ± 0.12kcal/molCcbScott, Good, et al., 1963ALS
Δcliquid-819.74 ± 0.24kcal/molCcbCox, Challoner, et al., 1954ALS
Δcliquid-813.1kcal/molCcbConstam and White, 1903ALS
Quantity Value Units Method Reference Comment
liquid51.699cal/mol*KN/AScott, Good, et al., 1963DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
37.928298.15Scott, Good, et al., 1963T = 12 to 400 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil417.0 ± 0.7KAVGN/AAverage of 20 out of 22 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus255. ± 2.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple255.010KN/AScott, Good, et al., 1963, 2Uncertainty assigned by TRC = 0.06 K; by extrapolation of 1/f, from calorimeter, to zero; TRC
Quantity Value Units Method Reference Comment
Tc645.KN/AMajer and Svoboda, 1985 
Tc644.85KN/AAmbrose and Grant, 1957Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Δvap10.6 ± 0.4kcal/molAVGN/AAverage of 10 values; Individual data points

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
8.927417.3N/AMajer and Svoboda, 1985 
10.3 ± 0.02320.EBChirico, Knipmeyer, et al., 1999Based on data from 314. to 457. K.; AC
9.78 ± 0.02360.EBChirico, Knipmeyer, et al., 1999Based on data from 314. to 457. K.; AC
9.23 ± 0.02400.EBChirico, Knipmeyer, et al., 1999Based on data from 314. to 457. K.; AC
8.63 ± 0.05440.EBChirico, Knipmeyer, et al., 1999Based on data from 314. to 457. K.; AC
9.58389.AStephenson and Malanowski, 1987Based on data from 374. to 458. K.; AC
9.01465.AStephenson and Malanowski, 1987Based on data from 450. to 570. K.; AC
8.80576.AStephenson and Malanowski, 1987Based on data from 561. to 645. K.; AC
9.87362.EB,IPStephenson and Malanowski, 1987Based on data from 347. to 458. K. See also Osborn and Douslin, 1968.; AC
9.87362.EBStephenson and Malanowski, 1987Based on data from 347. to 458. K. See also Scott, Good, et al., 1963.; AC
10.4 ± 0.02313.CMajer, Svoboda, et al., 1984AC
10.2 ± 0.02328.CMajer, Svoboda, et al., 1984AC
10.0 ± 0.02343.CMajer, Svoboda, et al., 1984AC
9.66 ± 0.02368.CMajer, Svoboda, et al., 1984AC
9.61 ± 0.02372.CScott, Good, et al., 1963AC
9.30 ± 0.02393.CScott, Good, et al., 1963AC
8.94 ± 0.02417.CScott, Good, et al., 1963AC
9.80369.MGHerington and Martin, 1953Based on data from 354. to 418. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kcal/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kcal/mol) β Tc (K) Reference Comment
298. to 417.14.590.2913645.Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference
347.19 to 457.724.173081484.307-61.606Osborn and Douslin, 1968

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
14.9240.Stephenson and Malanowski, 1987Based on data from 225. to 255. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.3891255.01Scott, Good, et al., 1963DH
3.389255.Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
13.29255.01Scott, Good, et al., 1963DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H6N- + Hydrogen cation = Pyridine, 3-methyl-

By formula: C6H6N- + H+ = C6H7N

Quantity Value Units Method Reference Comment
Δr377.8 ± 3.1kcal/molG+TSDePuy, Kass, et al., 1988gas phase; Acid: 3-methylpyridine. Comparable to EtOH.; B
Quantity Value Units Method Reference Comment
Δr371.0 ± 3.0kcal/molIMRBDePuy, Kass, et al., 1988gas phase; Acid: 3-methylpyridine. Comparable to EtOH.; B

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) • Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
Δr47.0 ± 3.5kcal/molCIDTRodgers, 2001RCD

Sodium ion (1+) + Pyridine, 3-methyl- = (Sodium ion (1+) • Pyridine, 3-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.0kcal/molCIDTRodgers, 2001RCD

Potassium ion (1+) + Pyridine, 3-methyl- = (Potassium ion (1+) • Pyridine, 3-methyl-)

By formula: K+ + C6H7N = (K+ • C6H7N)

Quantity Value Units Method Reference Comment
Δr23.8 ± 0.8kcal/molCIDTRodgers, 2001RCD

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
54. QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
130.6400.MN/A 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C6H7N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)9.0eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)225.5kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity217.9kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.9PEModelli and Distefano, 1981LLK
9.43 ± 0.05EIZaretskii, Oren, et al., 1976LLK
9.4 ± 0.1EIStefanovic and Grutzmacher, 1974LLK
9.04 ± 0.03PIWatanabe, Nakayama, et al., 1962RDSH
9.3PEModelli and Distefano, 1981Vertical value; LLK
9.31PEKimura, Katsumata, et al., 1981Vertical value; LLK
9.29PEKlasinc, Novak, et al., 1978Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H6+12.94 ± 0.05HCNEIZaretskii, Oren, et al., 1976LLK
C6H6N+12.3 ± 0.1HEIPalmer and Lossing, 1963RDSH

De-protonation reactions

C6H6N- + Hydrogen cation = Pyridine, 3-methyl-

By formula: C6H6N- + H+ = C6H7N

Quantity Value Units Method Reference Comment
Δr377.8 ± 3.1kcal/molG+TSDePuy, Kass, et al., 1988gas phase; Acid: 3-methylpyridine. Comparable to EtOH.; B
Quantity Value Units Method Reference Comment
Δr371.0 ± 3.0kcal/molIMRBDePuy, Kass, et al., 1988gas phase; Acid: 3-methylpyridine. Comparable to EtOH.; B

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Potassium ion (1+) + Pyridine, 3-methyl- = (Potassium ion (1+) • Pyridine, 3-methyl-)

By formula: K+ + C6H7N = (K+ • C6H7N)

Quantity Value Units Method Reference Comment
Δr23.8 ± 0.8kcal/molCIDTRodgers, 2001 

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) • Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
Δr47.0 ± 3.5kcal/molCIDTRodgers, 2001 

Sodium ion (1+) + Pyridine, 3-methyl- = (Sodium ion (1+) • Pyridine, 3-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.0kcal/molCIDTRodgers, 2001 

IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-5548
NIST MS number 228545

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Coulson and Ditcham, 1952
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 12161
Instrument n.i.g.
Melting point - 18.1
Boiling point 144.1

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedC78, Branched paraffin130.844.9Dallos, Sisak, et al., 2000He; Column length: 3.3 m
CapillaryOV-101110.852.Zhuravleva, 200050. m/0.3 mm/0.4 μm, He
CapillaryOV-101150.877.Terenina, Zhuravieva, et al., 199750. m/0.3 mm/0.4 μm, He
PackedC78, Branched paraffin130.843.4Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
PackedApolane130.846.Dutoit, 1991Column length: 3.7 m
CapillaryOV-170.857.Nabivach, 1989 
CapillarySE-30110.852.Samusenko and Golovnya, 198825. m/0.32 mm/1. μm, He
CapillarySE-3080.845.Samusenko and Golovnya, 198825. m/0.32 mm/1. μm, He
CapillaryOV-101150.859.Morishita, Morimoto, et al., 1986N2; Column length: 20. m; Column diameter: 0.23 mm
PackedOV-101130.841.Osmialowski, Halkiewicz, et al., 1985Ar, Chromosorb W HP; Column length: 1. m
PackedApiezon L130.874.Shatts, Avots, et al., 1977He, Chromosorb W AW-DMCS; Column length: 2.4 m
PackedApolane70.826.8Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApiezon L100.856.Zhuravleva, Kapustin, et al., 1976N2 or He, Chromosorb G, AW; Column length: 2.7 m
PackedApiezon L110.863.Bark and Wheatstone, 1974N2, Chromosorb W AW-DCMS; Column length: 2. m
PackedApiezon L130.871.Bark and Wheatstone, 1974N2, Chromosorb W AW-DCMS; Column length: 2. m
PackedPMS-100130.850.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPMS-100150.849.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPMS-100180.849.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryPEG-40M150.1310.Terenina, Zhuravieva, et al., 199750. m/0.3 mm/0.4 μm, He
CapillaryPEG-40M110.1303.Golovnya, Samusenko, et al., 1987He; Column length: 50. m; Column diameter: 0.3 mm
CapillaryPEG-40M80.1284.Golovnya, Samusenko, et al., 1987He; Column length: 50. m; Column diameter: 0.3 mm
PackedCarbowax 20M100.1297.Bark and Wheatstone, 1974N2, Chromosorb W AW-DCMS; Column length: 2. m
PackedCarbowax 20M110.1302.Bark and Wheatstone, 1974N2, Chromosorb W AW-DCMS; Column length: 2. m
PackedCarbowax 20M90.1289.Bark and Wheatstone, 1974N2, Chromosorb W AW-DCMS; Column length: 2. m
PackedPEG-2000150.1347.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryCP-Sil 8CB-MS869.Hierro, de la Hoz, et al., 200460. m/0.25 mm/0.25 μm, 40. C @ 2. min, 4. K/min, 280. C @ 5. min
CapillaryDB-1838.Kim, 200160. m/0.32 mm/1. μm, He, 40. C @ 5. min, 2. K/min; Tend: 220. C
CapillarySE-54860.Li, Wang, et al., 1998H2, 35. C @ 3. min, 4. K/min; Column length: 25. m; Column diameter: 0.31 mm; Tend: 250. C
CapillaryOV-1831.0Gautzsch and Zinn, 19968. K/min; Tstart: 35. C; Tend: 300. C
CapillaryOV-101852.Golovnya, Samusenko, et al., 1988He, 2. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 100. C
CapillaryOV-101850.Golovnya, Samusenko, et al., 1988He, 8. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 70. C
CapillaryOV-101850.Golovnya, Samusenko, et al., 1988He, 4. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 80. C
CapillaryDB-5861.Premecz and Ford, 1987He, 60. C @ 10. min, 10. K/min, 280. C @ 3. min; Column length: 30. m; Column diameter: 0.32 mm
CapillaryDB-5857.Rostad and Pereira, 198630. m/0.26 mm/0.25 μm, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min

Van Den Dool and Kratz RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryCP-Sil 8CB-MS868.Elmore, Mottram, et al., 200060. m/0.25 mm/0.25 μm, He; Program: 0C(5min) => 40C/min => 40C (2min) => 4C/min => 280C
CapillarySE-54859.Li, Wang, et al., 1998H2; Column length: 25. m; Column diameter: 0.31 mm; Program: not specified

Van Den Dool and Kratz RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryFFAP1289.Calvo-Gómez, Morales-López, et al., 200430. m/0.25 mm/0.25 μm, He, 40. C @ 3. min, 5. K/min; Tend: 220. C
CapillarySupelcowax-101290.Chung, Yung, et al., 200260. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min
CapillarySupelcowax-101290.Chung, Yung, et al., 200160. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min
CapillaryDB-Wax1292.Kim, 200160. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 2. K/min, 200. C @ 30. min
CapillaryDB-Wax1319.Le Guen, Prost, et al., 200060. m/0.32 mm/0.5 μm, He, 40. C @ 2. min, 4. K/min, 250. C @ 10. min
CapillarySupelcowax-101291.Chung, 199960. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min
CapillarySupelcowax-101290.Chung, 1999, 260. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min
CapillaryPEG-40M1303.Golovnya, Samusenko, et al., 198825. m/0.32 mm/0.80 μm, He, 2. K/min; Tstart: 100. C
CapillaryPEG-40M1304.Golovnya, Samusenko, et al., 198825. m/0.32 mm/0.80 μm, He, 8. K/min; Tstart: 70. C
CapillaryPEG-40M1304.Golovnya, Samusenko, et al., 198825. m/0.32 mm/0.80 μm, He, 8. K/min; Tstart: 70. C
CapillaryPEG-40M1298.Golovnya, Samusenko, et al., 198825. m/0.32 mm/0.80 μm, He, 4. K/min; Tstart: 80. C
CapillaryCAM1284.Premecz and Ford, 1987He, 60. C @ 5. min, 5. K/min, 240. C @ 21. min; Column length: 15. m; Column diameter: 0.24 mm

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-101130.841.Qi, Yang, et al., 2000 

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-5 MS863.Radulovic, Blagojevic, et al., 201030. m/0.25 mm/0.25 μm, Helium, 5. K/min, 290. C @ 10. min; Tstart: 70. C
CapillarySLB-5MS874.Risticevic, Carasek, et al., 200810. m/0.18 mm/0.18 μm, Helium, 40. C @ 1.5 min, 10. K/min; Tend: 295. C
CapillaryHP-5866.4Leffingwell and Alford, 200560. m/0.32 mm/0.25 μm, He, 30. C @ 2. min, 2. K/min, 260. C @ 28. min
CapillaryHP-5864.Kubec, Drhová, et al., 199930. m/0.25 mm/0.25 μm, N2, 40. C @ 3. min, 4. K/min, 240. C @ 10. min
CapillaryHP-5864.Kubec, Drhová, et al., 199830. m/0.25 mm/0.25 μm, N2, 40. C @ 3. min, 4. K/min, 240. C @ 10. min
CapillaryDB-1845.Yu and Ho, 199560. m/0.25 mm/1. μm, He, 40. C @ 5. min, 2. K/min, 260. C @ 60. min
CapillarySE-30850.Bur'yan and Nabivach, 19921.7 K/min; Tstart: 82. C; Tend: 177. C
CapillaryDB-5868.Lee, Macku, et al., 199160. m/0.25 mm/0.25 μm, 40. C @ 5. min, 2. K/min; Tend: 250. C
CapillaryOV-101841.Misharina, Golovnya, et al., 199150. m/0.32 mm/0.5 μm, He, 4. K/min; Tstart: 50. C; Tend: 250. C
CapillaryMethyl Silicone832.Lorenz, Stern, et al., 19834. K/min, 200. C @ 15. min; Column length: 25. m; Column diameter: 0.2 mm; Tstart: 50. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySLB-5MS871.Risticevic, Carasek, et al., 200810. m/0.18 mm/0.18 μm, Helium; Program: not specified
CapillarySE-30872.Li, Gao, et al., 2000Program: not specified
CapillaryDB-1834.Kawai, Ishida, et al., 199160. m/0.25 mm/0.25 μm; Program: not specified
CapillaryDB-1835.Kawai, Ishida, et al., 199160. m/0.25 mm/0.25 μm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.832.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.832.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified

Normal alkane RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-Innowax1284.Puvipirom and Chaisei, 201215. m/0.32 mm/0.50 μm, Helium, 3. K/min; Tstart: 40. C; Tend: 250. C
CapillaryFFAP1306.Nebesny, Budryn, et al., 200730. m/0.32 mm/0.5 μm, N2, 35. C @ 5. min, 4. K/min, 320. C @ 45. min
CapillaryTC-Wax1305.Ishizaki, Tachihara, et al., 200560. m/0.25 mm/0.25 μm, N2, 3. K/min, 220. C @ 40. min; Tstart: 70. C
CapillaryRTX-Wax1338.Galindo-Cuspinera, Lubran, et al., 200260. m/0.25 mm/0.5 μm, He, 40. C @ 5. min, 5. K/min, 180. C @ 20. min
CapillaryHP-Wax1323.Sanz, Maeztu, et al., 200260. m/0.25 mm/0.5 μm, He, 40. C @ 6. min, 3. K/min; Tend: 190. C
CapillaryHP-Innowax1292.Kubec, Drhová, et al., 199930. m/0.25 mm/0.25 μm, He, 40. C @ 3. min, 4. K/min, 190. C @ 10. min
CapillaryDB-Wax1289.Horiuchi, Umano, et al., 199860. m/0.25 mm/1. μm, He, 3. K/min, 200. C @ 40. min; Tstart: 50. C
CapillaryHP-Innowax1292.Kubec, Drhová, et al., 199830. m/0.25 mm/0.25 μm, N2, 40. C @ 3. min, 4. K/min, 190. C @ 10. min
CapillaryPEG-20M1264.Kubota, Matsujage, et al., 199650. m/0.25 mm/0.25 μm, Nitrogen, 2. K/min; Tstart: 60. C; Tend: 180. C
CapillaryDB-Wax1291.Umano, Hagi, et al., 1995He, 40. C @ 2. min, 2. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 200. C
CapillaryCarbowax 20M1288.Liardon and Ledermann, 1980H2, 2. K/min; Column length: 39. m; Column diameter: 0.30 mm; Tstart: 60. C; Tend: 220. C

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-FFAP1301.Mebazaa, Mahmoudi, et al., 200930. m/0.25 mm/0.25 μm, Helium; Program: 50 0C 2 0C/min -> 100 0C (5 min) 5 0C/min -> 250 0C
CapillaryDB-FFAP1319.Mebazaa, Mahmoudi, et al., 200930. m/0.25 mm/0.25 μm, Helium; Program: not specified
CapillaryTC-Wax1305.Kraft and Switt, 2005Program: not specified
CapillaryTC-Wax1305.Tachihara, Ishizaki, et al., 2004Program: not specified
CapillarySupelcowax-101311.Jung, Kim, et al., 2001Program: not specified
CapillaryDB-Wax1283.Peng, Yang, et al., 1991Program: not specified
CapillaryCarbowax1285.Baltes and Bochmann, 1987Program: not specified
CapillaryCarbowax1286.Baltes and Bochmann, 1987Program: not specified
CapillaryCarbowax1287.Baltes and Bochmann, 1987Program: not specified
CapillaryCarbowax1287.Baltes and Bochmann, 1987Program: not specified
CapillaryCarbowax1287.Baltes and Bochmann, 1987Program: not specified
CapillaryCarbowax1288.Baltes and Bochmann, 1987Program: not specified
CapillaryCarbowax1288.Baltes and Bochmann, 1987Program: not specified

Lee's RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-5133.54Rostad and Pereira, 198630. m/0.26 mm/0.25 μm, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Bark, L.S.; Wheatstone, K.C., Studies in the relationship between molecular structure and chromatographic behaviour. Gas chromatographic study of monoalkylpyridines, J. Chromatogr., 1974, 92, 2, 281-289, https://doi.org/10.1016/S0021-9673(00)85738-6 . [all data]

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Le Guen, Prost, et al., 2000
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Chung, 1999, 2
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Kubec, Drhová, et al., 1999
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Kubec, Drhová, et al., 1998
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Lee, Macku, et al., 1991
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Misharina, Golovnya, et al., 1991
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Lorenz, Stern, et al., 1983
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Kawai, Ishida, et al., 1991
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Waggott and Davies, 1984
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Puvipirom and Chaisei, 2012
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Nebesny, Budryn, et al., 2007
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Ishizaki, S.; Tachihara, T.; Tamura, H.; Yanai, T.; Kitahara, T., Evaluation of odour-active compounds in roasted shrimp (Sergia lucens Hansen) by aroma extract dilution analysis, Flavour Fragr. J., 2005, 20, 6, 562-566, https://doi.org/10.1002/ffj.1484 . [all data]

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Notes

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