Benzene, bromo-

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Condensed phase thermochemistry data

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid58.6kJ/molCmHolm, 1973Grignard Rx; ALS
Δfliquid60.9 ± 4.1kJ/molCmChernick, Skinner, et al., 1956Reanalyzed by Cox and Pilcher, 1970, Original value = 59.0 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Δcliquid-3111.9 ± 0.67kJ/molCcbSmith and Bjellerup, 1947ALS
Quantity Value Units Method Reference Comment
liquid21922.J/mol*KN/AMasi and Scott, 1975DH
liquid207.9J/mol*KN/AStull, 1937Extrapolation below 91 K, 55.86 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
155.9303.15Reddy, 1986T = 303.15, 313.15 K.; DH
154.29298.15Masi and Scott, 1975T = 11 to 300 K.; DH
155.39298.1Stull, 1937T = 90 to 320 K.; DH
145.6302.6de Kolossowsky and Udowenko, 1934DH
145.6302.6Kolosovskii and Udovenko, 1934DH
127.6231.7Andrews and Haworth, 1928T = 101 to 232 K. Value is unsmoothed experimental datum.; DH
151.5293.2Williams and Daniels, 1925T = 20 to 80°C.; DH
151.0298.von Reis, 1881T = 291 to 444 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil429.1 ± 0.6KAVGN/AAverage of 27 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus242.4 ± 0.3KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple242.42KN/AMarsh, 1987Uncertainty assigned by TRC = 0.02 K; recommended as fixed point for thermometry; TRC
Ttriple242.400KN/AMasi and Scott, 1975, 2Uncertainty assigned by TRC = 0.01 K; TRC
Ttriple242.4KN/AStull, 1937, 2Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δvap44.54kJ/molN/AMajer and Svoboda, 1985 
Δvap44.8kJ/molN/ABoublik, Fried, et al., 1984Based on data from 330. to 430. K. See also Basarová and Svoboda, 1991.; AC
Δvap44.5 ± 0.1kJ/molCWadsö, Luoma, et al., 1968AC
Δvap44.54 ± 0.04kJ/molCWadso, 1968ALS
Δvap37.9 ± 0.03kJ/molVMathews, 1926ALS

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
300.90.007Buckingham and Donaghy, 1982BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
42.3348.AStephenson and Malanowski, 1987Based on data from 333. to 463. K. See also Dykyj, 1972.; AC
44.0293.CMasi and Scott, 1975, 3AC
42.4344.N/ADreyer, Martin, et al., 1955Based on data from 329. to 427. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
329.22 to 427.394.072021495.044-61.508Dreyer, Martin, et al., 1955Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
10.702242.40Masi and Scott, 1975DH
10.7242.4Domalski and Hearing, 1996AC
10.627242.43Stull, 1937DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
44.15242.40Masi and Scott, 1975DH
43.84242.43Stull, 1937DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Δr1620. ± 10.kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Δr1607. ± 8.8kJ/molG+TSLinnert and Riveros, 1994gas phase; Acidity between quinoline and benzonitrile; B
Quantity Value Units Method Reference Comment
Δr1586. ± 11.kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Δr1572. ± 8.4kJ/molIMRBLinnert and Riveros, 1994gas phase; Acidity between quinoline and benzonitrile; B

C6H7N+ + Benzene, bromo- = (C6H7N+ • Benzene, bromo-)

By formula: C6H7N+ + C6H5Br = (C6H7N+ • C6H5Br)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KN/AMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.325.PHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Δr1605. ± 8.8kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Quantity Value Units Method Reference Comment
Δr1570. ± 9.2kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Δr1643. ± 8.4kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Quantity Value Units Method Reference Comment
Δr1611. ± 8.8kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B

Ethylbenzene + Benzene, bromo- = C8H9Br + Benzene

By formula: C8H10 + C6H5Br = C8H9Br + C6H6

Quantity Value Units Method Reference Comment
Δr-0.59 ± 0.021kJ/molCmMerdzhanov, Alenin, et al., 1982gas phase; Heat of isomerization at 349 K; ALS

2Benzene, bromo- + Mercury(II) bromide = Mercury, diphenyl- + 2Bromine

By formula: 2C6H5Br + Br2Hg = C12H10Hg + 2Br2

Quantity Value Units Method Reference Comment
Δr328.6 ± 3.3kJ/molCmChernick, Skinner, et al., 1956liquid phase; ALS

Chlorine anion + Benzene, bromo- = (Chlorine anion • Benzene, bromo-)

By formula: Cl- + C6H5Br = (Cl- • C6H5Br)

Quantity Value Units Method Reference Comment
Δr28.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B,M

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C6H5Br+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)9.00 ± 0.03eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)754.1kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity725.8kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
9.00PEFujisawa, Ohno, et al., 1986LBLHLM
8.998PEVon Niessen, Asbrink, et al., 1982LBLHLM
9.02PEKimura, Katsumata, et al., 1981LLK
9.05 ± 0.02PEMohraz, Maier, et al., 1980LLK
8.98 ± 0.02EQLias and Ausloos, 1978LLK
8.98PEBehan, Johnstone, et al., 1976LLK
9.45EIBaldwin, Loudon, et al., 1976LLK
8.97 ± 0.02PIPECOBaer, Tsai, et al., 1976LLK
8.99PESergeev, Akopyan, et al., 1970RDSH
9.03 ± 0.01PISergeev, Akopyan, et al., 1970RDSH
8.98 ± 0.03EIJohnstone, Mellon, et al., 1970RDSH
8.950PIMomigny, Goffart, et al., 1968RDSH
8.98 ± 0.02PIWatanabe, 1957RDSH
8.99PEKlasinc, Kovac, et al., 1983Vertical value; LBLHLM
9.041PEPotts, Lyus, et al., 1980Vertical value; LLK
9.05PESell and Kupperman, 1978Vertical value; LLK
8.99 ± 0.03PECvitas and Klasinc, 1977Vertical value; LLK
9.00PEStreets and Ceasar, 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C4H4+16.8 ± 0.1?EIMomigny, 1959RDSH
C6H4+14.2 ± 0.2HBrEIMomigny, 1959RDSH
C6H5+11.74 ± 0.07BrPIMalinovich, Arakawa, et al., 1985LBLHLM
C6H5+11.79 ± 0.09BrPIDunbar and Honovich, 1984LBLHLM
C6H5+12.04 ± 0.05BrEIBurgers and Holmes, 1984LBLHLM
C6H5+12.2 ± 0.1BrEIBurgers and Holmes, 1982LBLHLM
C6H5+11.7 ± 0.4BrPIPECORosenstock, Stockbauer, et al., 1980LLK
C6H5+12.10BrPIPECOBaer, Tsai, et al., 1976LLK
C6H5+11.82BrEIJohnstone and Mellon, 1972LLK
C6H5+11.75 ± 0.05BrPISergeev, Akopyan, et al., 1970RDSH
C6H5+12.02BrEIHowe and Williams, 1969RDSH

De-protonation reactions

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Δr1620. ± 10.kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Δr1607. ± 8.8kJ/molG+TSLinnert and Riveros, 1994gas phase; Acidity between quinoline and benzonitrile; B
Quantity Value Units Method Reference Comment
Δr1586. ± 11.kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Δr1572. ± 8.4kJ/molIMRBLinnert and Riveros, 1994gas phase; Acidity between quinoline and benzonitrile; B

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Δr1605. ± 8.8kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Quantity Value Units Method Reference Comment
Δr1570. ± 9.2kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Δr1643. ± 8.4kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B
Quantity Value Units Method Reference Comment
Δr1611. ± 8.8kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes; B

IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 291408

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source McClure, Blake, et al., 1954
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 824
Instrument n.i.g.
Melting point -30.6
Boiling point 156.0

Gas Chromatography

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedC78, Branched paraffin130.960.0Dallos, Sisak, et al., 2000He; Column length: 3.3 m
CapillaryDB-5110.952.20Gerbino, Garbarino, et al., 199630. m/0.53 mm/1.5 μm, N2
CapillaryDB-570.931.71Gerbino, Garbarino, et al., 199630. m/0.53 mm/1.5 μm, N2
CapillaryDB-590.941.36Gerbino, Garbarino, et al., 199630. m/0.53 mm/1.5 μm, N2
PackedOV-101100.924.Righezza, Hassani, et al., 1996N2, Chromosorb G HP; Column length: 5. m
PackedOV-101110.932.Righezza, Hassani, et al., 1996N2, Chromosorb G HP; Column length: 5. m
PackedOV-10180.914.7Righezza, Hassani, et al., 1996N2, Chromosorb G HP; Column length: 5. m
PackedOV-10190.923.7Righezza, Hassani, et al., 1996N2, Chromosorb G HP; Column length: 5. m
PackedOV-101120.934.8Hassani and Meklati, 1992N2, Chromosorb G HP; Column length: 5. m
PackedC78, Branched paraffin130.959.6Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
PackedApolane130.961.Dutoit, 1991Column length: 3.7 m
PackedApolane150.974.Evans and Haken, 1987He, Chromosorb G AW DCMS; Column length: 3.7 m
PackedApolane150.974.Haken and Vernon, 1986Chromosorb G AW DCMS; Column length: 3.7 m
PackedSE-30180.964.Oszczapowicz, Osek, et al., 1985N2, Chromosorb A AW; Column length: 3. m
PackedSE-30180.964.Oszczapowicz, Osek, et al., 1984N2, Chromosorb W AW; Column length: 3. m
PackedSE-30150.945.Tiess, 1984Ar, Gas Chrom Q (80-100 mesh); Column length: 3. m
PackedApolane70.925.8Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApiezon L100.965.Brown, Chapman, et al., 1968N2, DCMS-treated Chromosorb W; Column length: 2.3 m
PackedApiezon L130.982.Wehrli and Kováts, 1959Celite; Column length: 2.25 m

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
PackedApiezon M979.6Jalali-Heravi and Garkani-Nejad, 1993Chromosorb W; Column length: 2. m; Program: not specified

Kovats' RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedCarbowax 20M150.1351.Haken and Vernon, 1986Chromosorb G AW DCMS; Column length: 3.7 m; Column diameter: 6.4 mm
PackedCarbowax 20M75.1338.Goebel, 1982N2, Kieselgur (60-100 mesh); Column length: 2. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillarySPB-5941.Engel and Ratel, 200760. m/0.32 mm/1. μm, 40. C @ 2. min, 3. K/min, 230. C @ 10. min
CapillaryDB-1903.9Sun and Stremple, 200330. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 40. C; Tend: 325. C
CapillaryCP Sil 8 CB926.Chevance and Farmer, 199960. C @ 5. min, 4. K/min, 220. C @ 30. min; Column length: 50. m; Column diameter: 0.32 mm
CapillaryOV-1909.5Gautzsch and Zinn, 19968. K/min; Tstart: 35. C; Tend: 300. C
CapillaryDB-5919.67Gerbino, Garbarino, et al., 199630. m/0.53 mm/1.5 μm, N2, 2. K/min; Tstart: 50. C
CapillaryDB-5921.35Gerbino, Garbarino, et al., 199630. m/0.53 mm/1.5 μm, N2, 2. K/min; Tstart: 50. C
CapillaryDB-5926.64Gerbino, Garbarino, et al., 199630. m/0.53 mm/1.5 μm, N2, 2. K/min; Tstart: 50. C
CapillaryDB-1927.Gerbino and Castello, 199530. m/0.235 mm/0.25 μm, N2, 100. C @ 0. min, 10. K/min
CapillaryDB-1927.Gerbino and Castello, 199530. m/0.235 mm/0.25 μm, N2, 100. C @ 0. min, 5. K/min
CapillaryDB-1918.Gerbino and Castello, 199530. m/0.235 mm/0.25 μm, N2, 50. C @ 0. min, 10. K/min
CapillaryDB-1915.Gerbino and Castello, 199530. m/0.235 mm/0.25 μm, N2, 50. C @ 0. min, 5. K/min
PackedSE-30930.Buchman, Cao, et al., 1984He, Chromosorb AW, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m

Van Den Dool and Kratz RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryCP-Wax 52CB1330.Chevance and Farmer, 199960. C @ 5. min, 4. K/min, 220. C @ 30. min; Column length: 50. m; Column diameter: 0.32 mm
CapillaryDB-Wax1381.03Gerbino and Castello, 199530. m/0.235 mm/0.5 μm, N2, 10. K/min; Tstart: 100. C
CapillaryDB-Wax1373.68Gerbino and Castello, 199530. m/0.235 mm/0.5 μm, N2, 5. K/min; Tstart: 100. C
CapillaryDB-Wax1358.59Gerbino and Castello, 199530. m/0.235 mm/0.5 μm, N2, 10. K/min; Tstart: 50. C
CapillaryDB-Wax1348.92Gerbino and Castello, 199530. m/0.235 mm/0.5 μm, N2, 5. K/min; Tstart: 50. C
PackedCarbowax 20M1391.Buchman, Cao, et al., 1984He, Supelcoport, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryBP-1921.Health Safety Executive, 200050. m/0.22 mm/0.75 μm, He, 5. K/min; Tstart: 50. C; Tend: 200. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-101935.Ebrahimi and Hadjmohammadi, 2006Program: not specified
CapillaryMethyl Silicone982.N/AProgram: not specified
CapillarySPB-1936.Flanagan, Streete, et al., 199760. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryCP Sil 2895.Fuhrer, Deissler, et al., 199755. m/0.25 mm/0.25 μm, N2; Program: 40C(3min) => 20C/min => 80C => 2C/min => 240C(45min)
CapillaryDB-5983.Sorimachi, Tanabe, et al., 1995He; Column length: 30. m; Program: not specified
CapillarySPB-1910.Vezzani, Moretti, et al., 1994Column length: 30. m; Column diameter: 0.32 mm; Program: not specified
CapillarySPB-1936.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySPB-1945.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: not specified
PackedSE-30930.Buchman, Cao, et al., 1984He, Chromosorb AW; Column length: 3.05 m; Program: not specified
CapillaryOV-1945.Ramsey and Flanagan, 1982Program: not specified

Normal alkane RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.1338.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryCarbowax 20M1365.Ramsey and Flanagan, 1982Program: not specified

Lee's RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP5-MS150.Vrana, Paschke, et al., 200530. m/0.25 mm/0.25 μm, Helium, 50. C @ 5. min, 5. K/min, 280. C @ 10. min

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holm, 1973
Holm, T., Thermochemistry of Grignard reagents. Enthalpies of formation of alkylmagnesium bromides and of alkyl bromides, J. Organomet. Chem., 1973, 56, 87-93. [all data]

Chernick, Skinner, et al., 1956
Chernick, C.L.; Skinner, H.A.; Wadso, I., Thermochemistry of metallic alkyls. Part 7.-The heat of formation of mercury diphenyl, and of mercury phenyl chloride, Trans. Faraday Soc., 1956, 52, 1088-1093. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Smith and Bjellerup, 1947
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Masi and Scott, 1975
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Notes

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