Benzene-D6

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil345.430KN/AIngold, Raisin, et al., 1935Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Tfus280.0KN/AIngold, Raisin, et al., 1935Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Ttriple279.9KN/AZiegler and Andrews, 1942Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Δvap34.2kJ/molN/ADavis and Schiessler, 1953Based on data from 283. to 352. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
283. to 355.4.013791196.51-53.932Davis and Schiessler, 1953Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
9.791279.85Ziegler and Andrews, 1942, 2DH
9.79279.9Ziegler and Andrews, 1942, 2AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
34.99279.85Ziegler and Andrews, 1942, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C6D6+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference
9.25 ± 0.01PIDibeler and Reese, 1964
9.251SEl-Sayed, Kaaba, et al., 1961
9.251 ± 0.002SWilkinson, 1956
9.246 ± 0.005SPrice and Wood, 1935

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ingold, Raisin, et al., 1935
Ingold; Raisin, C.G.; Wilson, J. Chem. Soc., 1935, 1935, 915. [all data]

Ziegler and Andrews, 1942
Ziegler, W.T.; Andrews, D.H., The heat capacity of benzene-d6, J. Am. Chem. Soc., 1942, 64, 2482. [all data]

Davis and Schiessler, 1953
Davis, Raymond T.; Schiessler, Robert W., Vapor Pressures of Perdeuterobenzene and of Perdeuterocyclohex ane, J. Phys. Chem., 1953, 57, 9, 966-968, https://doi.org/10.1021/j150510a027 . [all data]

Ziegler and Andrews, 1942, 2
Ziegler, W.T.; Andrews, D.H., The heat capacity of benzene-d6, J. Am. Chem. Soc., 1942, 64, 2482-2485. [all data]

Dibeler and Reese, 1964
Dibeler, V.H.; Reese, R.M., Mass spectrometric study of photoionization. I. Apparatus and initial observations on acetylene, acetylene-d2, benzene, and benzene-d6, J. Res. NBS, 1964, 68A, 409. [all data]

El-Sayed, Kaaba, et al., 1961
El-Sayed, M.F.A.; Kaaba, M.; Tanaka, Y., Ionization potentials of benzene, hexadeuterobenzene, and pyridine from their observed Rydberg series in the region 600-2000 A, J. Chem. Phys., 1961, 34, 334. [all data]

Wilkinson, 1956
Wilkinson, P.G., Absorption spectra and ionization potentials of benzene and benzene-d6, J. Chem. Phys., 1956, 24, 917. [all data]

Price and Wood, 1935
Price, W.C.; Wood, R.W., The far ultraviolet absorption spectra and ionization potentials of C6H6 and C6D6, J. Chem. Phys., 1935, 3, 439. [all data]


Notes

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