Methane, chloromethoxy-

• Formula: C₂H₅ClO
• Molecular weight: 80.513
• IUPAC Standard InChI: InChI=1S/C2H5ClO/c1-4-2-3/h2H2,1H3 Copy

  
• IUPAC Standard InChIKey: XJUZRXYOEPSWMB-UHFFFAOYSA-N Copy
• CAS Registry Number: 107-30-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Ether, chloromethyl methyl; Chlorodimethyl ether; Chloromethoxymethane; Chloromethyl methyl ether; Methoxychloromethane; Methoxymethyl chloride; Methyl chloromethyl ether; Monochlorodimethyl ether; Monochloromethyl methyl ether; CH3OCH2Cl; Chlormethyl methyl ether; Chlordimethylether; CMME; Ether methylique monochlore; Ether, dimethyl chloro; Methyl chloromethyl ether, anhydrous; Rcra waste number U046; UN 1239; NSC 21208
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Phase change data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₂H₄ClO^- +  =

By formula: C₂H₄ClO^- + H⁺ = C₂H₅ClO

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

De-protonation reactions

C₂H₄ClO^- +  =

By formula: C₂H₄ClO^- + H⁺ = C₂H₅ClO

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Paulino and Squires, 1991
Paulino, J.A.; Squires, R.R., Carbene Anion Complexes - Unusual Structural and Thermochemical Features of alpha-Halocarbanions in the Gas Phase, J. Am. Chem. Soc., 1991, 113, 5, 1845, https://doi.org/10.1021/ja00005a067 . [all data]

Vereschagin, Salikova, et al., 1980
Vereschagin, A.N.; Salikova, A.M.; Zverev, V.V.; Saitkulova, F.G.; Villem, Y.Y., Physical properties, conformations, and intramolecular interactions of α, α-dichlorodimethyl ether, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1980, 997. [all data]

Haney and Franklin, 1969
Haney, M.A.; Franklin, J.L., Excess energies in mass spectra of some oxygen-containing organic compounds, J. Chem. Soc. Faraday Trans., 1969, 65, 1794. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔrG°	Free energy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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