Mercury, chloroethyl-
- Formula: C2H5ClHg
- Molecular weight: 265.10
- IUPAC Standard InChIKey: QWUGXIXRFGEYBD-UHFFFAOYSA-M
- CAS Registry Number: 107-27-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ceresan; Chloroethylmercury; Cryptodine; Ethylmercuric chloride; Ethylmercury chloride; Granosan; Granozan; C2H5HgCl; EMC; Ganozan; Ethylmerkurichlorid; Emcon D; NSC 1203; Monoethylmercury chloride
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -16.2 ± 0.98 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on 7.22 ± 0.36 kcal/mol for the enthalpy of formation of Hg(Et)2(l). |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -34.37 ± 0.69 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on 7.22 ± 0.36 kcal/mol for the enthalpy of formation of Hg(Et)2(l). |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 18.2 ± 0.69 | kcal/mol | RSC | Charnley and Skinner, 1951 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.9 | PE | Baidin, Chizhov, et al., 1981 | LLK |
10.22 ± 0.05 | PE | Baidin, Timoshenko, et al., 1985 | Vertical value; LBLHLM |
10.22 | PE | Baidin, Chizhov, et al., 1981 | Vertical value; LLK |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Gas Phase Spectrum
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Additional Data
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Owner | NIST Standard Reference Data Program Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Sadtler Research Labs Under US-EPA Contract |
State | gas |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | MASS SPECTROMETRY CENTER, UNIV. OF UTAH EPA-PTSEL 3400 |
NIST MS number | 52395 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Charnley and Skinner, 1951
Charnley, T.; Skinner, H.A.,
J. Chem. Soc., 1951, 1921.. [all data]
Baidin, Chizhov, et al., 1981
Baidin, V.N.; Chizhov, Y.V.; Timoshenko, M.M.; Sokolikova, O.K.; Grishin, Y.K.; Ustynyuk, Y.A.,
The photoelectron spectra of alkylmercury chlorides,
J. Struct. Chem., 1981, 22, 616, In original 164. [all data]
Baidin, Timoshenko, et al., 1985
Baidin, V.N.; Timoshenko, M.M.; Chizhov, Y.V.; Ustynyuk, Y.A.; Kritskaya, I.I.,
Photoelectron spectra nad the structure of organomercury compounds,
J. Organomet. Chem., 1985, 292, 55. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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