1,1-Dimethyl-1-silacyclopentane
- Formula: C6H14Si
- Molecular weight: 114.2609
- IUPAC Standard InChI: InChI=1S/C6H14Si/c1-7(2)5-3-4-6-7/h3-6H2,1-2H3
- IUPAC Standard InChIKey: KDQBKCRYCZJUAE-UHFFFAOYSA-N
- CAS Registry Number: 1072-54-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Silacyclopentane, 1,1-dimethyl-; Cyclotetramethylenedimethylsilane; 1,1-Dimethylsilacyclopentane
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C6H14Si+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.26 ± 0.03 | EI | Gusel'nikov, Volkova, et al., 1981 | LLK |
| 9.0 | PE | Cundy, Lappert, et al., 1973 | LLK |
| 9.75 | PE | Cundy, Lappert, et al., 1973 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C4H10Si+ | 9.76 ± 0.04 | C2H4 | EI | Gusel'nikov, Volkova, et al., 1981 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Gusel'nikov, Volkova, et al., 1981
Gusel'nikov, L.E.; Volkova, V.V.; Tarasenko, N.A.; Tishenkov, A.A.; Zaikin, V.G.; Eremina, E.I.; Nametkin, N.S.,
Deuterium labelling and thermochemical studies of dissociative ionization of methyl substituted monosilacyclobutanes. Ring expansion in the molecular ion of 1,1,3-trimethylΣ-1-silacyclobutane,
Org. Mass Spectrom., 1981, 16, 242. [all data]
Cundy, Lappert, et al., 1973
Cundy, C.S.; Lappert, M.F.; Pedley, J.B.; Schmidt, W.; Wilkins, B.T.,
Bonding studies of compounds of boron and the Group IV elements. XI. Photoelectron spectra of strained cyclic organosilicon compounds,
J. Organomet. Chem., 1973, 51, 99. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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