1,2-Ethanediol

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-94.26 ± 0.67kcal/molCcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; ALS
Δfgas-92.7 ± 0.4kcal/molCcbGardner and Hussain, 1972ALS
Δfgas-93.28kcal/molN/AMcClaine, 1947Value computed using ΔfHliquid° value of -455.9 kj/mol from McClaine, 1947 and ΔvapH° value of 65.6 kj/mol from Knauth and Sabbah, 1990.; DRB
Δfgas-93.04kcal/molN/AParks, West, et al., 1946Value computed using ΔfHliquid° value of -454.9±0.3 kj/mol from Parks, West, et al., 1946 and ΔvapH° value of 65.6 kj/mol from Knauth and Sabbah, 1990.; DRB
Δfgas-92.61kcal/molN/AMoureu and Dode, 1937Value computed using ΔfHliquid° value of -453.1±1.2 kj/mol from Moureu and Dode, 1937 and ΔvapH° value of 65.6 kj/mol from Knauth and Sabbah, 1990.; DRB
Quantity Value Units Method Reference Comment
gas74.532cal/mol*KN/AChao J., 1986Other third-law entropy values at 298.15 K known from literature are 284.5 [ Buckley P., 1967], 312.5 [ Stull D.R., 1969], and 315.47(5.36) J/mol*K [ Yeh T.-S., 1994].; GT

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
14.29200.Yeh T.-S., 1994Other statistically calculated values of entropy at 298.15 K (274.76 [ Buckley P., 1967], 293.76 [ Frei H., 1977], 303.8 [ Chao J., 1986], and 323.55 J/mol*K [ Dyatkina M.E., 1954]) are in worse agreement with third-law entropy value.; GT
18.64298.15
18.74300.
23.42400.
27.161500.
30.031600.
32.321700.
34.240800.
35.911900.
37.3801000.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-109.9 ± 0.67kcal/molCcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; ALS
Δfliquid-108.9 ± 0.2kcal/molCcbGardner and Hussain, 1972ALS
Δfliquid-108.95kcal/molCcbMcClaine, 1947ALS
Δfliquid-108.73 ± 0.07kcal/molCcbParks, West, et al., 1946ALS
Δfliquid-108.30 ± 0.29kcal/molCcbMoureu and Dode, 1937Reanalyzed by Cox and Pilcher, 1970, Original value = -108.1 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcliquid-285. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
liquid39.89cal/mol*KN/AParks, Kelley, et al., 1929Extrapolation below 90 K, 8.2 cal/mol*K. Revision of previous data.; DH
liquid42.90cal/mol*KN/AParks and Kelley, 1925Extrapolation below 90 K, 11.46 cal/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
35.80298.Zaripov, 1982T = 298, 323, 363 K.; DH
35.68298.Stephens and Tamplin, 1979T = 273 to 493 K.; DH
35.76298.15Murthy and Subrahmanyam, 1977DH
34.70303.Kawaizumi, Otake, et al., 1972DH
35.99301.2Paz Andrade, Paz, et al., 1970T = 28, 40°C.; DH
35.930298.15Nikolaev and Rabinovich, 1967T = 80 to 300 K.; DH
35.21298.Tungusov and Mishchenko, 1965DH
35.581298.Rabinovich and Nikolaev, 1962T = 10 to 55°C.; DH
34.80293.4Neiman and Kurlyankin, 1932T = 20.2 to 78.4°C. Value is unsmoothed experimental datum.; DH
35.71293.0Parks and Kelley, 1925T = 88 to 293 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil470.5 ± 0.5KAVGN/AAverage of 27 out of 31 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus261. ± 2.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple256.6KN/AKnauth and Sabbah, 1990, 2Uncertainty assigned by TRC = 0.2 K; TRC
Ttriple260.6KN/AWilhoit, Chao, et al., 1985Uncertainty assigned by TRC = 0.2 K; TRC
Ttriple260.6KN/ANikolaev and Rabinovich, 1967, 2Uncertainty assigned by TRC = 0.2 K; TRC
Ttriple260.8KN/AParks and Kelley, 1925, 2Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tc720.KN/ANikitin, Pavlov, et al., 1993Uncertainty assigned by TRC = 4. K; TRC
Tc720.KN/ATeja and Rosenthal, 1991Uncertainty assigned by TRC = 1. K; TRC
Tc718.KN/ATeja and Anselme, 1990Uncertainty assigned by TRC = 1. K; TRC
Tc645.KN/AStephens and Tamplin, 1979, 2Uncertainty assigned by TRC = 30. K; TC data from Union Carbide Corp.; TRC
Tc790.KN/AArtemchenko, 1972Uncertainty assigned by TRC = 30. K; TRC
Quantity Value Units Method Reference Comment
Pc80.93atmN/ANikitin, Pavlov, et al., 1993Uncertainty assigned by TRC = 1.97 atm; TRC
Pc88.82atmN/ATeja and Rosenthal, 1991Uncertainty assigned by TRC = 0.987 atm; TRC
Pc129.29atmN/ALyons, 1985Uncertainty assigned by TRC = 9.869 atm; TRC
Quantity Value Units Method Reference Comment
Δvap15.6 ± 0.7kcal/molAVGN/AAverage of 13 values; Individual data points

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
14.9 ± 0.96345.N/APetitjean, Reyes-Perez, et al., 2010Based on data from 307. to 384. K.; AC
13.7385.TGAAl-Najjar and Al-Sammerrai, 2007Based on data from 363. to 408. K.; AC
15.6338.AStephenson and Malanowski, 1987Based on data from 323. to 473. K.; AC
14.9378.AStephenson and Malanowski, 1987Based on data from 363. to 418. K.; AC
16.2 ± 0.4409.VGardner and Hussain, 1972ALS
15.3338.N/AJones and Tamplin, 1952Based on data from 323. to 473. K. See also Gardner and Hussain, 1972.; AC
14.8 ± 1.5273.VGallaugher and Hibbert, 1937Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 13.64 kcal/mol; ALS
14.6383.N/ASchierholtz and Staples, 1935Based on data from 363. to 403. K.; AC
13.7436.N/ASchierholtz and Staples, 1935Based on data from 403. to 470. K.; AC
14.6410.N/Ade Forcrand, 1901Based on data from 395. to 459. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
323. to 473.4.964411914.951-84.996Jones and Tamplin, 1952, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.380260.6Nikolaev and Rabinovich, 1967DH
2.7780260.8Parks and Kelley, 1925DH

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
9.132260.6Nikolaev and Rabinovich, 1967DH
10.65260.8Parks and Kelley, 1925DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Chlorine anion • 1,2-Ethanediol) + 1,2-Ethanediol = (Chlorine anion • 21,2-Ethanediol)

By formula: (Cl- • C2H6O2) + C2H6O2 = (Cl- • 2C2H6O2)

Quantity Value Units Method Reference Comment
Δr15.9 ± 1.2kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr9.3 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + 1,2-Ethanediol = (Chlorine anion • 1,2-Ethanediol)

By formula: Cl- + C2H6O2 = (Cl- • C2H6O2)

Quantity Value Units Method Reference Comment
Δr25.3 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr16.6 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

C2H5O2- + Hydrogen cation = 1,2-Ethanediol

By formula: C2H5O2- + H+ = C2H6O2

Quantity Value Units Method Reference Comment
Δr365.1 ± 2.5kcal/molG+TSCrowder and Bartmess, 1993gas phase; B
Quantity Value Units Method Reference Comment
Δr360.9 ± 2.0kcal/molIMRECrowder and Bartmess, 1993gas phase; B

1,2-Ethanediol + Acetone = 1,3-Dioxolane, 2,2-dimethyl- + Water

By formula: C2H6O2 + C3H6O = C5H10O2 + H2O

Quantity Value Units Method Reference Comment
Δr-2.4kcal/molEqkAnteunis and Rommelaere, 1970liquid phase; ALS

1,2-Ethanediol + Nitric acid = 2-hydroxyethyl nitrate + Water

By formula: C2H6O2 + HNO3 = C2H5NO4 + H2O

Quantity Value Units Method Reference Comment
Δr-1.9kcal/molCmTsvetkov, Sopin, et al., 1986liquid phase; ALS

Nitric oxide anion + 1,2-Ethanediol = C2H6NO3-

By formula: NO- + C2H6O2 = C2H6NO3-

Quantity Value Units Method Reference Comment
Δr27.00kcal/molN/AHendricks, de Clercq, et al., 2002gas phase; B

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
4.0×10+6 MN/AValue at T = 293. K.
17000. MN/A missing citation say that this value is unreliable.

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C2H6O2+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)195.0kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity184.9kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
10.16EIHolmes and Lossing, 1982LBLHLM
10.55PEOhno, Imai, et al., 1985Vertical value; LBLHLM
10.55PEKimura, Katsumata, et al., 1981Vertical value; LLK
10.5PEVon Niessen, Bieri, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3O+11.12 ± 0.05CH2OHEIHolmes and Lossing, 1984LBLHLM
CH3O+12.5 ± 0.15CH2O+HEIHolmes, Lossing, et al., 1983LBLHLM
CH4O+[CH2OH2+]11.42 ± 0.05CH2OEIHolmes, Lossing, et al., 1982LBLHLM
CH5O+[CH3OH2+]10.7 ± 0.1CHOEIBurgers, Holmes, et al., 1987LBLHLM

De-protonation reactions

C2H5O2- + Hydrogen cation = 1,2-Ethanediol

By formula: C2H5O2- + H+ = C2H6O2

Quantity Value Units Method Reference Comment
Δr365.1 ± 2.5kcal/molG+TSCrowder and Bartmess, 1993gas phase; B
Quantity Value Units Method Reference Comment
Δr360.9 ± 2.0kcal/molIMRECrowder and Bartmess, 1993gas phase; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + 1,2-Ethanediol = (Chlorine anion • 1,2-Ethanediol)

By formula: Cl- + C2H6O2 = (Cl- • C2H6O2)

Quantity Value Units Method Reference Comment
Δr25.3 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Δr16.6 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase

(Chlorine anion • 1,2-Ethanediol) + 1,2-Ethanediol = (Chlorine anion • 21,2-Ethanediol)

By formula: (Cl- • C2H6O2) + C2H6O2 = (Cl- • 2C2H6O2)

Quantity Value Units Method Reference Comment
Δr15.9 ± 1.2kcal/molTDAsZhang, Beglinger, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Δr9.3 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase

Nitric oxide anion + 1,2-Ethanediol = C2H6NO3-

By formula: NO- + C2H6O2 = C2H6NO3-

Quantity Value Units Method Reference Comment
Δr27.00kcal/molN/AHendricks, de Clercq, et al., 2002gas phase

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
NIST MS number 341866

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Energetics of intra- and intermolecular bonds in ω-alkanediols (II) Thermochemical study of 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, and 1,5-pentanediol at 298.15K, Struct. Chem., 1990, 1, 43-46. [all data]

Knauth and Sabbah, 1989
Knauth, P.; Sabbah, R., Combustion calorimetry on milligram samples of liquid substances with a CRMT rocking bomb calorimeter. Application to the study of ω-alkanediol at 298.15 K, J. Chem. Thermodyn., 1989, 21, 203-210. [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]

McClaine, 1947
McClaine, L.A., Thermodynamic data for some compounds containing carbon, hydrogen and oxygen, Ph.D. Thesis for Stanford University, 1947, 1-57. [all data]

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

Moureu and Dode, 1937
Moureu, H.; Dode, M., Chaleurs de formation de l'oxyde d'ethylene, de l'ethanediol et de quelques homologues, Bull. Soc. Chim. France, 1937, 4, 637-647. [all data]

Chao J., 1986
Chao J., Thermodynamic properties of key organic oxygen compounds in the carbon range C1 to C4. Part 2. Ideal gas properties, J. Phys. Chem. Ref. Data, 1986, 15, 1369-1436. [all data]

Buckley P., 1967
Buckley P., Infrared studies on rotational isomerism. I. Ethylene glycol, Can. J. Chem., 1967, 45, 397-407. [all data]

Stull D.R., 1969
Stull D.R., Jr., The Chemical Thermodynamics of Organic Compounds. Wiley, New York, 1969. [all data]

Yeh T.-S., 1994
Yeh T.-S., Global conformational analysis of 1,2-ethanediol, J. Phys. Chem., 1994, 98, 8921-8929. [all data]

Frei H., 1977
Frei H., Ethylene glycol: infrared spectra, ab initio calculation, vibrational analysis and conformations of 5 matrix isolated isotopic modifications, Chem. Phys., 1977, 25, 271-298. [all data]

Dyatkina M.E., 1954
Dyatkina M.E., Thermodynamic functions of normal alcohols (propanol, butanol, ethylene glycol), Zh. Fiz. Khim., 1954, 28, 377. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Parks and Kelley, 1925
Parks, G.S.; Kelley, K.K., Thermal data on organic compounds. II. The heat capacities of five organic compounds. The entropies and free energies of some homologous series of aliphatic compounds, J. Am. Chem. Soc., 1925, 47, 2089-2097. [all data]

Zaripov, 1982
Zaripov, Z.I., Experimental study of the isobaric heat capacity of liquid organic compounds with molecular weights of up to 4000 a.e.m., 1982, Teplomassoobmen Teplofiz. [all data]

Stephens and Tamplin, 1979
Stephens, M.A.; Tamplin, W.S., Saturated liquid specific heats of ethylene glycol homologues, J. Chem. Eng. Data, 1979, 24, 81-82. [all data]

Murthy and Subrahmanyam, 1977
Murthy, N.M.; Subrahmanyam, S.V., Behaviour of excess heat capacity of aqueous non-electrolytes, Indian J. Pure Appl. Phys., 1977, 15, 485-489. [all data]

Kawaizumi, Otake, et al., 1972
Kawaizumi, F.; Otake, T.; Nomura, H.; Miyahara, Y., Heat capacities of aqueous solutions of ethylene glycol, propylene glycol and 1,3-butanediol, Nippon Kagaku. Kaishi, 1972, 1972, 1733-1776. [all data]

Paz Andrade, Paz, et al., 1970
Paz Andrade, M.I.; Paz, J.M.; Recacho, E., Contribucion a la microcalorimetria de los calores especificos de solidos y liquidos, An. Quim., 1970, 66, 961-967. [all data]

Nikolaev and Rabinovich, 1967
Nikolaev, P.N.; Rabinovich, I.B., Heat capacity of ethylene glycol and ethylene deuteroglycol in the temperature range 80-300K, Zhur. Fiz. Khim., 1967, 41, 2191-2194. [all data]

Tungusov and Mishchenko, 1965
Tungusov, V.P.; Mishchenko, K.P., Specific heat of pure ethylene glycol and solution of NaI and KI in ethylene glycol at 25°C, Zhur. Fiz. Khim., 1965, 39, 2968-2972. [all data]

Rabinovich and Nikolaev, 1962
Rabinovich, I.B.; Nikolaev, P.N., Isotopic effect in the specific heat of some deutero compounds, Dokl. Akad. Nauk, 1962, SSSR 142, 1335-1338. [all data]

Neiman and Kurlyankin, 1932
Neiman, M.B.; Kurlyankin, I.A., Thermodynamic studies of solutions. II. Study of the thermodynamics of aqueous solutions of ethylene glycol at different temperatures, Zhur. Obshch. Khim., 1932, 2, 318-321. [all data]

Knauth and Sabbah, 1990, 2
Knauth, P.; Sabbah, R., Can. J. Chem., 1990, 68, 731. [all data]

Wilhoit, Chao, et al., 1985
Wilhoit, R.C.; Chao, J.; Hall, K.R., Thermodynamic Properties of Key Organic Compounds in the Carbon Range C1 to C4. Part 1. Properties of Condensed Phases, J. Phys. Chem. Ref. Data, 1985, 14, 1. [all data]

Nikolaev and Rabinovich, 1967, 2
Nikolaev, P.N.; Rabinovich, I.B., Zh. Fiz. Khim., 1967, 41, 9, 2191. [all data]

Parks and Kelley, 1925, 2
Parks, G.S.; Kelley, K.K., Thermal Data on Organic Compounds II. The Heat Capacities of Five Organic Compounds. The Entropies and Free Energies of Some Homologous Series of Aliphatic Compounds, J. Am. Chem. Soc., 1925, 47, 2089-97. [all data]

Nikitin, Pavlov, et al., 1993
Nikitin, E.D.; Pavlov, P.A.; Skripov, P.V., Measurement of the critical properties of thermally unstable substances and mixtures by the pulse-heating method, J. Chem. Thermodyn., 1993, 25, 869-80. [all data]

Teja and Rosenthal, 1991
Teja, A.S.; Rosenthal, D.J., The critical pressures and temperatures of ten substances using a low residence time flow apparatus in Experimental Results for Phase Equilibria and Pure Component Properties, DIPPR DATA Series No. 1, 1991. [all data]

Teja and Anselme, 1990
Teja, A.S.; Anselme, M.J., The critical properties of thermally stable and unstable fluids. I. 1985 results, AIChE Symp. Ser., 1990, 86, 279, 115-21. [all data]

Stephens and Tamplin, 1979, 2
Stephens, M.A.; Tamplin, W.S., Saturated Liquid SPecific Heats of Ethylene GLycol Homologues, J. Chem. Eng. Data, 1979, 24, 81-2. [all data]

Artemchenko, 1972
Artemchenko, A.I., Fiz. Khim. Rastvorov, 1972, 1972, 128-34. [all data]

Lyons, 1985
Lyons, R.L., The determination of critical properties and vapor pressure of thermally stable and unstable compounds, M. S. Thesis, 1985. [all data]

Petitjean, Reyes-Perez, et al., 2010
Petitjean, M.; Reyes-Perez, E.; Perez, D.; Mirabel, Ph.; Le Calve, S., Vapor Pressure Measurements of Hydroxyacetaldehyde and Hydroxyacetone in the Temperature Range (273 to 356) K, J. Chem. Eng. Data, 2010, 55, 2, 852-855, https://doi.org/10.1021/je9004905 . [all data]

Al-Najjar and Al-Sammerrai, 2007
Al-Najjar, Hazim; Al-Sammerrai, Dhoaib, Thermogravimetric determination of the heat of vaporization of some highly polar solvents, J. Chem. Technol. Biotechnol., 2007, 37, 3, 145-152, https://doi.org/10.1002/jctb.280370302 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Jones and Tamplin, 1952
Jones, W.S.; Tamplin, W.S., Chapter 9. Physical Properties of Propylene Glycol in Glycols. American Chemical Society Monograph 114, G.O. Curme, Jr., ed(s)., Reinhold, New York, 1952, 210-240. [all data]

Gallaugher and Hibbert, 1937
Gallaugher, A.F.; Hibbert, H., Studies on reactions relating to carbohydrates and polysaccharides. LV. Vapor pressures of the polyethylene glycols and their derivatives, J. Am. Chem. Soc., 1937, 59, 2521-2525. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Schierholtz and Staples, 1935
Schierholtz, O.J.; Staples, M.L., Vapor Pressures of Certain Glycols, J. Am. Chem. Soc., 1935, 57, 12, 2709-2711, https://doi.org/10.1021/ja01315a106 . [all data]

de Forcrand, 1901
de Forcrand, M., Compt. Rend., 1901, 132, 688. [all data]

Jones and Tamplin, 1952, 2
Jones, W.S.; Tamplin, W.S., Chapter 3. Physical Properties of Ethylene Glycol in Glycols, George O. Curme, Jr., ed(s)., Reinhold Publishing Corporation, 330 West Forty-Second Street, New York, U.S.A., 1952, 27-62. [all data]

Zhang, Beglinger, et al., 1995
Zhang, W.; Beglinger, C.; Stone, J.A., High-pressure mass spectrometric study of the gas-phase association of Cl- with alpha,omega-diols, J. Phys. Chem., 1995, 99, 30, 11673, https://doi.org/10.1021/j100030a009 . [all data]

Crowder and Bartmess, 1993
Crowder, C.; Bartmess, J., The Gas Phase Acidities of Diols, J. Am. Soc. Mass Spectrom., 1993, 4, 9, 723, https://doi.org/10.1016/1044-0305(93)80051-Y . [all data]

Anteunis and Rommelaere, 1970
Anteunis, M.; Rommelaere, Y., NMR experiments on acetals. XXIX. The ease of acetonide formation of some glycols, Bull. Soc. Chim. Belg., 1970, 79, 523-530. [all data]

Tsvetkov, Sopin, et al., 1986
Tsvetkov, V.G.; Sopin, V.P.; Tsvetkova, L.Ya.; Marchenko, G.N., Enthalpy of reaction of nitric acid with some organic compounds, J. Gen. Chem. USSR, 1986, 56, 471-474. [all data]

Hendricks, de Clercq, et al., 2002
Hendricks, J.H.; de Clercq, H.L.; Freidhoff, C.B.; Arnold, S.T.; Eaton, J.G.; Fancher, C.; Lyapustina, S.A.; S., Anion solvation at the microscopic level: Photoelectron spectroscopy of the solvated anion clusters, NO-(Y)(n), where Y=Ar, Kr, Xe, N2O, H2S, NH3, H2O, and C2H4(OH)(2), J. Chem. Phys., 2002, 116, 18, 7926-7938, https://doi.org/10.1063/1.1457444 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Holmes and Lossing, 1982
Holmes, J.L.; Lossing, F.P., Towards a general scheme for estimating the heats of formation of organic ions in the gas phase. Part II. The effect of substitution at charge-bearing sites, Can. J. Chem., 1982, 60, 2365. [all data]

Ohno, Imai, et al., 1985
Ohno, K.; Imai, K.; Harada, Y., Variations in reactivity of lone-pair electrons due to intramolecular hydrogen bonding as observed by penning ionization electron spectroscopy, J. Am. Chem. Soc., 1985, 107, 8078. [all data]

Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S., Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]

Von Niessen, Bieri, et al., 1980
Von Niessen, W.; Bieri, G.; Asbrink, L., 30.4 nm He(II) photoelectron spectra of organic molecules. Part III. Oxo-compounds (C,H,O), J. Electron Spectrosc. Relat. Phenom., 1980, 21, 175. [all data]

Holmes and Lossing, 1984
Holmes, J.L.; Lossing, F.P., Heats of formation of organic radicals from appearance energies, Int. J. Mass Spectrom. Ion Processes, 1984, 58, 113. [all data]

Holmes, Lossing, et al., 1983
Holmes, J.L.; Lossing, F.P.; Terlouw, J.K.; Burgers, P.C., Novel gas-phase ions. The radical cations [CH2XH]+. (X = F, Cl, Br, I, OH, NH2, SH) and [CH2CH2NH3]+., Can. J. Chem., 1983, 61, 2305. [all data]

Holmes, Lossing, et al., 1982
Holmes, J.L.; Lossing, F.P.; Terlouw, J.K.; Burgers, P.C., The radical cation [CH2OH2]+ and related stable gas phase ion-dipole complexes, J. Am. Chem. Soc., 1982, 104, 2931. [all data]

Burgers, Holmes, et al., 1987
Burgers, P.C.; Holmes, J.L.; Hop, C.E.C.A.; Postma, R.; Ruttink, P.J.A.; Terlouw, J.K., The isomeric [C2H6O2]+ hydrogen-bridged radical cations [CH2-O(H)...H...O=CH2]+, [CH3-O...H...O=CH2]+, and [CH3-O(H)...H...O=CH]+: Theory and experiment, J. Am. Chem. Soc., 1987, 109, 7315. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References