Diisopropyl mercury


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas91.2 ± 4.6kJ/molReviewMartinho Simões 
Δfgas36.9 ± 6.2kJ/molReviewMartinho SimõesSelected data

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid37.6 ± 4.3kJ/molReviewMartinho Simões 
Δfliquid-16.7 ± 6.0kJ/molReviewMartinho SimõesSelected data
Quantity Value Units Method Reference Comment
Δcliquid-4399.5 ± 4.2kJ/molCC-SBJones, Evans, et al., 1935Please also see Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap53.6 ± 1.7kJ/molCC-SBTees, 1952 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.6 ± 0.1EIGowenlock, Haynes, et al., 1962RDSH
8.03PEFehlner, Ulman, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H7+9.7 ± 0.1?EIGowenlock, Haynes, et al., 1962RDSH
C3H7Hg+9.1 ± 0.1C3H7EIGowenlock, Haynes, et al., 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., J. Chem. Soc., 1935, 39.. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Tees, 1952
Tees, T.F.S., Trans. Faraday Soc., 1952, 48, 227. [all data]

Gowenlock, Haynes, et al., 1962
Gowenlock, B.G.; Haynes, R.M.; Majer, J.R., Electron impact measurement on some organomercury compounds, J. Chem. Soc. Faraday Trans., 1962, 58, 1905. [all data]

Fehlner, Ulman, et al., 1976
Fehlner, T.P.; Ulman, J.; Nugent, W.A.; Kochi, J.K., Effect of alkyl substituents on the first ionization potential and on 5d10 ionization in dialkylmercury compounds, Inorg. Chem., 1976, 15, 2544. [all data]


Notes

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