Diisopropyl mercury
- Formula: C6H14Hg
- Molecular weight: 286.77
- CAS Registry Number: 1071-39-2
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 91.2 ± 4.6 | kJ/mol | Review | Martinho Simões | |
ΔfH°gas | 36.9 ± 6.2 | kJ/mol | Review | Martinho Simões | Selected data |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 37.6 ± 4.3 | kJ/mol | Review | Martinho Simões | |
ΔfH°liquid | -16.7 ± 6.0 | kJ/mol | Review | Martinho Simões | Selected data |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -4399.5 ± 4.2 | kJ/mol | CC-SB | Jones, Evans, et al., 1935 | Please also see Cox and Pilcher, 1970. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 53.6 ± 1.7 | kJ/mol | CC-SB | Tees, 1952 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.6 ± 0.1 | EI | Gowenlock, Haynes, et al., 1962 | RDSH |
8.03 | PE | Fehlner, Ulman, et al., 1976 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C3H7+ | 9.7 ± 0.1 | ? | EI | Gowenlock, Haynes, et al., 1962 | RDSH |
C3H7Hg+ | 9.1 ± 0.1 | C3H7 | EI | Gowenlock, Haynes, et al., 1962 | RDSH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C.,
J. Chem. Soc., 1935, 39.. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Tees, 1952
Tees, T.F.S.,
Trans. Faraday Soc., 1952, 48, 227. [all data]
Gowenlock, Haynes, et al., 1962
Gowenlock, B.G.; Haynes, R.M.; Majer, J.R.,
Electron impact measurement on some organomercury compounds,
J. Chem. Soc. Faraday Trans., 1962, 58, 1905. [all data]
Fehlner, Ulman, et al., 1976
Fehlner, T.P.; Ulman, J.; Nugent, W.A.; Kochi, J.K.,
Effect of alkyl substituents on the first ionization potential and on 5d10 ionization in dialkylmercury compounds,
Inorg. Chem., 1976, 15, 2544. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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