Stannane, chlorotrimethyl-

• Formula: C₃H₉ClSn
• Molecular weight: 199.267
• IUPAC Standard InChI: InChI=1S/3CH3.ClH.Sn/h3*1H3;1H;/q;;;;+1/p-1 Copy

  
• IUPAC Standard InChIKey: KWTSZCJMWHGPOS-UHFFFAOYSA-M Copy
• CAS Registry Number: 1066-45-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Chlorotrimethylstannane; Chlorotrimethyltin; M&T Chemicals 1222-45; Trimethylchlorostannane; Trimethylchlorotin; Trimethylstannyl chloride; Trimethyltin chloride; (CH3)3SnCl; Stannylium, trimethyl-, chloride; Tin(+), trimethyl-, chloride; Trimethyltin monochloride; NSC 12088; NSC 92613
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

3 (l) +  (l) = 4 (l)

By formula: 3C₄H₁₂Sn (l) + Cl₄Sn (l) = 4C₃H₉ClSn (l)

 (cr) +  (l) = C₃H₁₀OSn (cr) + ( • 55) (solution)

By formula: C₃H₉ClSn (cr) + H₂O (l) = C₃H₁₀OSn (cr) + (HCl • 55H₂O) (solution)

 +  = C₃H₉Cl₂Sn^-

By formula: Cl^- + C₃H₉ClSn = C₃H₉Cl₂Sn^-

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S., J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]

Notes

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• Symbols used in this document:
  

  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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