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Stannane, chlorotrimethyl-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess

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Individual Reactions

3Stannane, tetramethyl- (l) + Tin(IV) chloride (l) = 4Stannane, chlorotrimethyl- (l)

By formula: 3C4H12Sn (l) + Cl4Sn (l) = 4C3H9ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-184. ± 28.kJ/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Stannane, chlorotrimethyl- (cr) + Water (l) = C3H10OSn (cr) + (Hydrogen chloride bullet 55Water) (solution)

By formula: C3H9ClSn (cr) + H2O (l) = C3H10OSn (cr) + (HCl bullet 55H2O) (solution)

Quantity Value Units Method Reference Comment
Deltar-13.8 ± 0.4kJ/molRSCBaldwin, Lappert, et al., 1972MS

Chlorine anion + Stannane, chlorotrimethyl- = C3H9Cl2Sn-

By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-

Quantity Value Units Method Reference Comment
Deltar131. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S., J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]


Notes

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