Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Tin(IV) chloride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

3Stannane, tetramethyl- (l) + Tin(IV) chloride (l) = 4Stannane, chlorotrimethyl- (l)

By formula: 3C4H12Sn (l) + Cl4Sn (l) = 4C3H9ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-184. ± 28.kJ/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Stannane, tetramethyl- (l) + 3Tin(IV) chloride (l) = 4Methyltin trichloride (l)

By formula: C4H12Sn (l) + 3Cl4Sn (l) = 4CH3Cl3Sn (l)

Quantity Value Units Method Reference Comment
Deltar-186. ± 28.kJ/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Stannane, tetramethyl- (l) + Tin(IV) chloride (l) = 2Tin, dichlorodimethyl- (l)

By formula: C4H12Sn (l) + Cl4Sn (l) = 2C2H6Cl2Sn (l)

Quantity Value Units Method Reference Comment
Deltar-97. ± 15.kJ/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Stannane, tetraethyl- (l) + Tin(IV) chloride (l) = C2H5Cl3Sn (l) + Stannane, chlorotriethyl- (l)

By formula: C8H20Sn (l) + Cl4Sn (l) = C2H5Cl3Sn (l) + C6H15ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-94.6 ± 4.6kJ/molRSC and ESTNash, Skinner, et al., 1965MS

Chlorine anion + Tin(IV) chloride = Cl5Sn-

By formula: Cl- + Cl4Sn = Cl5Sn-

Quantity Value Units Method Reference Comment
Deltar235. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

3Stannane, tetraethyl- (l) + Tin(IV) chloride (l) = 4Stannane, chlorotriethyl- (l)

By formula: 3C8H20Sn (l) + Cl4Sn (l) = 4C6H15ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-189.5 ± 9.2kJ/molRSC and ESTNash, Skinner, et al., 1965MS

3Stannane, tetraethenyl- (l) + Tin(IV) chloride (l) = 4C6H9ClSn (l)

By formula: 3C8H12Sn (l) + Cl4Sn (l) = 4C6H9ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-111. ± 13.kJ/molRSCNash, Skinner, et al., 1965MS

Stannane, tetraethenyl- (l) + 3Tin(IV) chloride (l) = 4C2H3Cl3Sn (l)

By formula: C8H12Sn (l) + 3Cl4Sn (l) = 4C2H3Cl3Sn (l)

Quantity Value Units Method Reference Comment
Deltar-103. ± 13.kJ/molRSCNash, Skinner, et al., 1965MS

Stannane, tetraethenyl- (l) + Tin(IV) chloride (l) = 2C4H6Cl2Sn (l)

By formula: C8H12Sn (l) + Cl4Sn (l) = 2C4H6Cl2Sn (l)

Quantity Value Units Method Reference Comment
Deltar-92. ± 13.kJ/molRSCNash, Skinner, et al., 1965MS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References