Stannane, chlorotrimethyl-
- Formula: C3H9ClSn
- Molecular weight: 199.267
- IUPAC Standard InChIKey: KWTSZCJMWHGPOS-UHFFFAOYSA-M
- CAS Registry Number: 1066-45-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Chlorotrimethylstannane; Chlorotrimethyltin; M&T Chemicals 1222-45; Trimethylchlorostannane; Trimethylchlorotin; Trimethylstannyl chloride; Trimethyltin chloride; (CH3)3SnCl; Stannylium, trimethyl-, chloride; Tin(+), trimethyl-, chloride; Trimethyltin monochloride; NSC 12088; NSC 92613
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -195.4 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr). |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -212.5 ± 7.1 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -49.7 ± 2.0 kJ/mol for the enthalpy of formation of Sn(Me)4(l). |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°solid | -245.6 ± 4.1 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr). |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 50.2 | kJ/mol | RSC | Baldwin, Lappert, et al., 1972 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: 3C4H12Sn (l) + Cl4Sn (l) = 4C3H9ClSn (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -184. ± 28. | kJ/mol | RSC | Nash, Skinner, et al., 1965 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS |
(cr) +
(l) = C3H10OSn (cr) + (
• 55
) (solution)
By formula: C3H9ClSn (cr) + H2O (l) = C3H10OSn (cr) + (HCl • 55H2O) (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -13.8 ± 0.4 | kJ/mol | RSC | Baldwin, Lappert, et al., 1972 | MS |
+
= C3H9Cl2Sn-
By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 131. ± 7.1 | kJ/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase; B |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.90 | PE | Fragala, Ciliberto, et al., 1980 | LLK |
10.16 | PE | Flamini, Semprini, et al., 1976 | Vertical value; LLK |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Gas Phase Spectrum
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Additional Data
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Owner | NIST Standard Reference Data Program Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Sadtler Research Labs Under US-EPA Contract |
State | gas |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-3022 |
NIST MS number | 231124 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S.,
J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]
Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F.,
Trans. Faraday Soc., 1965, 61, 640. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S.,
Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-),
J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x
. [all data]
Fragala, Ciliberto, et al., 1980
Fragala, I.; Ciliberto, E.; Egdell, R.G.; Granozzi, G.,
He(I) and He(II) photoelectron spectra of methyltin chlorides,
J. Chem. Soc. Dalton Trans., 1980, 145. [all data]
Flamini, Semprini, et al., 1976
Flamini, A.; Semprini, E.; Stefani, F.; Sorriso, S.; Cardaci, G.,
He(I) photoelectron spectra and semiempirical molecular-orbital calculations on methylmetal halides of group 4A elements,
J. Chem. Soc. Dalton Trans., 1976, 731. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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