bromotrimethylstannane


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-138.2 ± 5.6kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -49.7 ± 2.0 kJ/mol for the enthalpy of formation of Sn(Me)4(l).
Δfgas-145.6kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr).

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-185.5 ± 3.7kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -49.7 ± 2.0 kJ/mol for the enthalpy of formation of Sn(Me)4(l).
Quantity Value Units Method Reference Comment
Δfsolid-204.2 ± 4.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr).

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap47.3 ± 4.2kJ/molRSCDavies, Pope, et al., 1963 
Quantity Value Units Method Reference Comment
Δsub58.6kJ/molRSCBaldwin, Lappert, et al., 1972 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.4PEFlamini, Semprini, et al., 1976LLK
9.60PEFlamini, Semprini, et al., 1976Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S., J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]

Flamini, Semprini, et al., 1976
Flamini, A.; Semprini, E.; Stefani, F.; Sorriso, S.; Cardaci, G., He(I) photoelectron spectra and semiempirical molecular-orbital calculations on methylmetal halides of group 4A elements, J. Chem. Soc. Dalton Trans., 1976, 731. [all data]


Notes

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