bromotrimethylgermane
- Formula: C3H9BrGe
- Molecular weight: 197.65
- CAS Registry Number: 1066-37-1
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -222.0 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -569. ± 17. kJ/mol for the estimated enthalpy of formation of [Ge(Me)3]2O(l) Baldwin, Lappert, et al., 1972. |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -259.7 ± 8.4 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -569. ± 17. kJ/mol for the estimated enthalpy of formation of [Ge(Me)3]2O(l) Baldwin, Lappert, et al., 1972. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 37.7 | kJ/mol | RSC | Baldwin, Lappert, et al., 1972 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.45 | PE | Drake and Gorzelska, 1981 | |
| 9.78 | PE | Drake and Gorzelska, 1981 | Vertical value |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S.,
J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]
Drake and Gorzelska, 1981
Drake, J.E.; Gorzelska, K.,
The photoelectron spectra of methyl(bromo)germanes,
J. Electron Spectrosc. Relat. Phenom., 1981, 21, 365. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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