Ethyne, 1-trimethylsilyl-

• Formula: C₂H₄Si
• Molecular weight: 56.1387
• IUPAC Standard InChI: InChI=1S/C5H10Si/c1-5-6(2,3)4/h1H,2-4H3 Copy

  
• IUPAC Standard InChIKey: CWMFRHBXRUITQE-UHFFFAOYSA-N Copy
• CAS Registry Number: 1066-27-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Species with the same structure:
  • (Trimethylsilyl)acetylene
• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Reaction thermochemistry data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

De-protonation reactions

C₂H₃Si^- +  =

By formula: C₂H₃Si^- + H⁺ = C₂H₄Si

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ensslin, Bock, et al., 1974
Ensslin, W.; Bock, H.; Becker, G., Photoelectron spectra and molecular properties. XXX. π interactions in H₃Si- H₃C-substituted acetylenes, J. Am. Chem. Soc., 1974, 96, 2757. [all data]

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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