ClOClO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td 488 665 Jacobs, Kronberg, et al., 1994

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 ClO(t) stretch 994.5 vs Ar IR Jacobs, Kronberg, et al., 1994
Johnsson, Engdahl, et al., 1995
2 ClO stretch 695.9 w Ar IR Jacobs, Kronberg, et al., 1994
3 OCl stretch 440.3 w Ar IR Jacobs, Kronberg, et al., 1994
4 ClOCl deform 338.7 w Ar IR Jacobs, Kronberg, et al., 1994

Additional references: Jacox, 1998, page 264

Notes

wWeak
vsVery strong
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacobs, Kronberg, et al., 1994
Jacobs, J.; Kronberg, M.; Muller, H.S.P.; Willner, H., An Experimental Study on the Photochemistry and Vibrational Spectroscopy of Three Isomers of Cl2O2 Isolated in Cryogenic Matrixes, J. Am. Chem. Soc., 1994, 116, 3, 1106, https://doi.org/10.1021/ja00082a038 . [all data]

Johnsson, Engdahl, et al., 1995
Johnsson, K.; Engdahl, A.; Kolm, J.; Nieminen, J.; Nelander, B., The ClOClO, BrOClO, and IOClO Molecules and Their Photoisomerization. A Matrix Isolation Study, J. Phys. Chem., 1995, 99, 12, 3902, https://doi.org/10.1021/j100012a006 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

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