CH2NH2


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to CH4N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)199.0kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity191.6kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Δf(+) ion178.kcal/molN/AN/A 

Ionization energy determinations

IE (eV) Method Reference Comment
6.29 ± 0.03PEDyke, Lee, et al., 1989LL
6.1DERBurkey, Castelhano, et al., 1983LBLHLM
6.2DERGriller and Lossing, 1981LLK
6.97 ± 0.03PEDyke, Lee, et al., 1989Vertical value; LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Dyke, Lee, et al., 1989
Dyke, J.M.; Lee, E.P.F.; Niavaran, M.H.Z., A study of the aminomethyl radical CH2NH2 by vacuum UV photoelectron spectroscopy and AB initio molecular orbital calculations, Int. J. Mass Spectrom. Ion Phys., 1989, 94, 221. [all data]

Burkey, Castelhano, et al., 1983
Burkey, T.J.; Castelhano, A.L.; Griller, D.; Lossing, F.P., Heats of formation and ionization potentials of some α-aminoalkyl radicals, J. Am. Chem. Soc., 1983, 105, 4701. [all data]

Griller and Lossing, 1981
Griller, D.; Lossing, F.P., On the thermochemistry of α-aminoalkyl radicals, J. Am. Chem. Soc., 1981, 103, 1586. [all data]


Notes

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