SrSH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 15003.15 gas C-X 642 690 Fernando, Ram, et al., 1991
Sheridan, Dick, et al., 2006
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 SrS stretch 269 gas LF Fernando, Ram, et al., 1991

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 14809.61 gas B-X 675 688 Fernando, Ram, et al., 1991
Sheridan, Dick, et al., 2006

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 14275.69 gas A-X 686 727 Fernando, Ram, et al., 1991
Sheridan, Dick, et al., 2006
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 SrS stretch 270 gas LF Fernando, Ram, et al., 1991

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 SrS stretch 270 gas LF Fernando, Ram, et al., 1991

Additional references: Jacox, 1994, page 29; Jacox, 2003, page 24; Halfen, Apponi, et al., 2001

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fernando, Ram, et al., 1991
Fernando, W.T.M.L.; Ram, R.S.; O'Brien, L.C.; Bernath, P.F., Gas-phase inorganic chemistry: laser spectroscopy of calcium and strontium monothiolates and monohydrosulfides, J. Phys. Chem., 1991, 95, 7, 2665, https://doi.org/10.1021/j100160a009 . [all data]

Sheridan, Dick, et al., 2006
Sheridan, P.M.; Dick, M.J.; Wang, J.-G.; Bernath, P.F., High-resolution investigation of the excited electronic states of CaSH and SrSH by laser excitation spectroscopy -- ARTICLE WITHDRAWN, Mol. Phys., 2006, 104, 20-21, 3245, https://doi.org/10.1080/00268970601075253 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Halfen, Apponi, et al., 2001
Halfen, D.T.; Apponi, A.J.; Thompsen, J.M.; Ziurys, L.M., The pure rotational spectra of SrSH (X [sup 2]A[sup ´]) and SrS (X [sup 1]Σ[sup +]): Further studies in alkaline-earth bonding, J. Chem. Phys., 2001, 115, 24, 11131, https://doi.org/10.1063/1.1419060 . [all data]

Notes

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