Germane, tetraphenyl-
- Formula: C24H20Ge
- Molecular weight: 381.06
- IUPAC Standard InChIKey: ILEXMONMGUVLRM-UHFFFAOYSA-N
- CAS Registry Number: 1048-05-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraphenylgermane; Tetraphenylgermanium
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 438. ± 15. | kJ/mol | Review | Martinho Simões | Selected data |
ΔfH°gas | 1028.0 ± 7.0 | kJ/mol | Review | Martinho Simões | |
ΔfH°gas | 602. ± 10. | kJ/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 281. ± 14. | kJ/mol | Review | Martinho Simões | Selected data |
ΔfH°solid | 871.1 ± 5.6 | kJ/mol | Review | Martinho Simões | |
ΔfH°solid | 444.8 ± 9.2 | kJ/mol | Review | Martinho Simões | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -13286.3 ± 8.4 | kJ/mol | CC-SB | Shaulov, Fedorov, et al., 1970 | |
ΔcH°solid | -13139. ± 14. | kJ/mol | CC-RB | Adams, Carson, et al., 1969 | Please also see Pedley and Rylance, 1977. |
ΔcH°solid | -13712.6 ± 4.2 | kJ/mol | CC-SB | Birr, 1962 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.1 | PE | Novak and Potts, 1984 | LBLHLM |
8.95 | PE | Novak and Potts, 1984 | Vertical value; LBLHLM |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Shaulov, Fedorov, et al., 1970
Shaulov, Yu.Kh.; Fedorov, A.K.; Genchel, V.G.,
Russ. J. Phys. Chem., 1970, 44, 146. [all data]
Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G.,
Heats of combustion of organo-metallic compounds using a vacuum-jacketed, rotating, aneroid calorimeter. Heat of formation of germanium tetraphenyl,
Trans. Faraday Soc., 1969, 65, 113, https://doi.org/10.1039/tf9696500113
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Birr, 1962
Birr, K.-H.,
Z. Anorg. Allg. Chem., 1962, 315, 175. [all data]
Novak and Potts, 1984
Novak, I.; Potts, A.W.,
The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives,
J. Organomet. Chem., 1984, 262, 17. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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