strontium chloride

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-192.48kcal/molReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
liquid,1 bar32.462cal/mol*KReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
Δfsolid-198.10kcal/molReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
solid27.440cal/mol*KReviewChase, 1998Data last reviewed in December, 1972

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1147. to 3000.
A 25.00000
B 1.002360×10-8
C -4.381121×10-9
D 6.411941×10-10
E 1.664941×10-9
F -202.5660
G 57.28690
H -192.4840
ReferenceChase, 1998
Comment Data last reviewed in December, 1972

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1000.1000. to 1147.
A 13.0088029.40010
B 27.19111-0.000001
C -42.411507.364800×10-7
D 27.50540-1.328951×10-7
E -0.000785-1.920401×10-7
F -202.8700-211.4900
G 36.7132953.30330
H -198.1000-198.1000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1972 Data last reviewed in December, 1972

Gas phase ion energetics data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.8SEmons, Kiessling, et al., 1982LBLHLM
10.49 ± 0.04PELee and Potts, 1979LLK
9.70 ± 0.10EIHildenbrand, 1970RDSH
10.5 ± 1.0EIHildenbrand, 1970, 2RDSH
10.2PEHammer, Allen, et al., 1978Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClSr+10.2ClSEmons, Kiessling, et al., 1982LBLHLM
SrCl+10.48 ± 0.10ClEIHildenbrand, 1970RDSH
SrCl+10.7 ± 0.3ClEIHildenbrand, 1970, 2RDSH
Sr+14.6Cl2SEmons, Kiessling, et al., 1982LBLHLM

References

Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Emons, Kiessling, et al., 1982
Emons, H.-H.; Kiessling, D.; Horlbeck, W., Dampfdruckmessungen und massenspektrometrische untersuchungen der gasphase uber erdalkalimetallhalogeniden, Z. Anorg. Allg. Chem., 1982, 488, 219. [all data]

Lee and Potts, 1979
Lee, E.P.F.; Potts, A.W., An investigation of the valence shell electronic structure of alkaline earth halides by using Ab initio S. C. F. calculations and photoelectron spectroscopy, Proc. R. Soc. London A:, 1979, 365, 395. [all data]

Hildenbrand, 1970
Hildenbrand, D.L., Electron impact studies of the IIA metal chlorides, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 75. [all data]

Hildenbrand, 1970, 2
Hildenbrand, D.L., Dissociation energies and chemical bonding in the alkaline-earth chlorides from mass spectrometric studies, J. Chem. Phys., 1970, 52, 5751. [all data]

Hammer, Allen, et al., 1978
Hammer, C.A.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K., The high-temperature photoelectron spectra of alkaline-earth chlorides and iodides, J. Electron Spectrosc. Relat. Phenom., 1978, 13, 149. [all data]


Notes

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