strontium chloride
- Formula: Cl2Sr
- Molecular weight: 158.53
- CAS Registry Number: 10476-85-4
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Condensed phase thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -192.48 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1972 |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid,1 bar | 32.462 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1972 |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°solid | -198.10 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1972 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 27.440 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1972 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 1147. to 3000. |
---|---|
A | 25.00000 |
B | 1.002360×10-8 |
C | -4.381121×10-9 |
D | 6.411941×10-10 |
E | 1.664941×10-9 |
F | -202.5660 |
G | 57.28690 |
H | -192.4840 |
Reference | Chase, 1998 |
Comment | Data last reviewed in December, 1972 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 1000. | 1000. to 1147. |
---|---|---|
A | 13.00880 | 29.40010 |
B | 27.19111 | -0.000001 |
C | -42.41150 | 7.364800×10-7 |
D | 27.50540 | -1.328951×10-7 |
E | -0.000785 | -1.920401×10-7 |
F | -202.8700 | -211.4900 |
G | 36.71329 | 53.30330 |
H | -198.1000 | -198.1000 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in December, 1972 | Data last reviewed in December, 1972 |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.8 | S | Emons, Kiessling, et al., 1982 | LBLHLM |
10.49 ± 0.04 | PE | Lee and Potts, 1979 | LLK |
9.70 ± 0.10 | EI | Hildenbrand, 1970 | RDSH |
10.5 ± 1.0 | EI | Hildenbrand, 1970, 2 | RDSH |
10.2 | PE | Hammer, Allen, et al., 1978 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
ClSr+ | 10.2 | Cl | S | Emons, Kiessling, et al., 1982 | LBLHLM |
SrCl+ | 10.48 ± 0.10 | Cl | EI | Hildenbrand, 1970 | RDSH |
SrCl+ | 10.7 ± 0.3 | Cl | EI | Hildenbrand, 1970, 2 | RDSH |
Sr+ | 14.6 | Cl2 | S | Emons, Kiessling, et al., 1982 | LBLHLM |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Emons, Kiessling, et al., 1982
Emons, H.-H.; Kiessling, D.; Horlbeck, W.,
Dampfdruckmessungen und massenspektrometrische untersuchungen der gasphase uber erdalkalimetallhalogeniden,
Z. Anorg. Allg. Chem., 1982, 488, 219. [all data]
Lee and Potts, 1979
Lee, E.P.F.; Potts, A.W.,
An investigation of the valence shell electronic structure of alkaline earth halides by using Ab initio S. C. F. calculations and photoelectron spectroscopy,
Proc. R. Soc. London A:, 1979, 365, 395. [all data]
Hildenbrand, 1970
Hildenbrand, D.L.,
Electron impact studies of the IIA metal chlorides,
Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 75. [all data]
Hildenbrand, 1970, 2
Hildenbrand, D.L.,
Dissociation energies and chemical bonding in the alkaline-earth chlorides from mass spectrometric studies,
J. Chem. Phys., 1970, 52, 5751. [all data]
Hammer, Allen, et al., 1978
Hammer, C.A.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K.,
The high-temperature photoelectron spectra of alkaline-earth chlorides and iodides,
J. Electron Spectrosc. Relat. Phenom., 1978, 13, 149. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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