samarium (III) chloride hexahydrate

• Formula: Cl₃Sm
• Molecular weight: 256.72
• CAS Registry Number: 10361-82-7
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Ion clustering data
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 + Cl₃Sm = Cl₄Sm^-

By formula: Cl^- + Cl₃Sm = Cl₄Sm^-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

Appearance energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Khasanshin, Pogrebnoi, et al., 1998
Khasanshin, I.V.; Pogrebnoi, A.M.; Kudin, L.S.; Kuznetsov, A.Y.; Butman, M.F., The Neutral and Ionic Components of Saturated Vapor of Samarium Dichloride: The Thermochemical Characteristics of Gaseous Molecules and Ions, High Temp., 1998, 36, 687-694. [all data]

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides, Russ. J. Phys. Chem., 1984, 58, 1792. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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