ZnCl2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 60630 ± 90 gas Wang, Niu, et al., 1990

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 60170 ± 80 gas Wang, Niu, et al., 1990

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 58060 ± 80 gas Wang, Niu, et al., 1990

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 17940 ± 80 gas Wang, Niu, et al., 1990
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 290 ± 8 gas PE Wang, Niu, et al., 1990

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 10180 ± 160 gas Wang, Niu, et al., 1990

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 4480 ± 120 gas Wang, Niu, et al., 1990
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 360 T gas PE Wang, Niu, et al., 1990
Πg 2 Bend 280 T gas PE Wang, Niu, et al., 1990

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Πg 2 Bend 240 ± 20 gas PE Wang, Niu, et al., 1990

Additional references: Jacox, 1994, page 72

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Niu, et al., 1990
Wang, L.-S.; Niu, B.; Lee, Y.T.; Shirley, D.A., Electronic structure and chemical bonding of the first row transition metal dichlorides, MnCl2, NiCl2, and ZnCl2: A high resolution photoelectron spectroscopic study, J. Chem. Phys., 1990, 93, 957. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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