Cyclopentane, 1,2-dibromo,trans-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Cyclopentene + Bromine = Cyclopentane, 1,2-dibromo,trans-

By formula: C5H8 + Br2 = C5H8Br2

Quantity Value Units Method Reference Comment
Δr-119.7 ± 2.5kJ/molCmLister, 1941gas phase; Halogenation at 27 C

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.08 ± 0.02PEBotter, Menes, et al., 1973LLK
10.04PEGounelle, Menard, et al., 1975Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lister, 1941
Lister, M.W., Heats of organic reactions. X. Heats of bromination of cyclic olefins, J. Am. Chem. Soc., 1941, 63, 143-149. [all data]

Botter, Menes, et al., 1973
Botter, R.; Menes, F.; Gounelle, Y.; Pechine, J.M.; Solgadi, D., The ionization potentials of geometrical isomers: the cis and trans 2-subststituted cyclopentyl and cyclohexyl bromides, Int. J. Mass Spectrom. Ion Phys., 1973, 12, 188. [all data]

Gounelle, Menard, et al., 1975
Gounelle, Y.; Menard, C.; Pechine, J.M.; Solgadi, D.; Menes, F.; Botter, R., Conformational effects on ionization potentials; Photoelectron spectra of dibromo- and bromofluoro- alkyl compounds, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 247. [all data]


Notes

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