Boron trichloride anion
- Formula: BCl3-
- Molecular weight: 117.171
- CAS Registry Number: 102210-07-1
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -104.3 ± 4.6 | kcal/mol | R-EA | Rothe, Mathur, et al., 1980 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| e | 3 | BCl3 stretch | 685.8 | Ne | IR | Jacox, Irikura, et al., 1996 | |
Additional references: Jacox, 1998, page 261
References
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rothe, Mathur, et al., 1980
Rothe, E.W.; Mathur, B.P.; Reck, G.P.,
Measurement of boron trihalide electron affinites: Correlation with boron-nitrogen adduct strengths,
Inorg. Chem., 1980, 19, 829. [all data]
Jacox, Irikura, et al., 1996
Jacox, M.E.; Irikura, K.K.; Thompson, W.E.,
Matrix isolation study of the interaction of excited neon atoms with BCl3: Infrared spectra of BCl+3, BCl+2, and BCl-3,
J. Chem. Phys., 1996, 104, 22, 8871, https://doi.org/10.1063/1.471622
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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