Dimanganese decacarbonyl


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-1585.3 ± 4.3kJ/molReviewMartinho SimõesSelected data.
Δfgas-1582.2 ± 9.4kJ/molReviewMartinho Simões 
Δfgas-1582.8 ± 9.2kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-1677.6 ± 3.7kJ/molReviewMartinho SimõesSelected data.
Δfsolid-1674.5 ± 9.2kJ/molReviewMartinho Simões 
Δfsolid-1675.1 ± 9.0kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcsolid-3251.0 ± 3.3kJ/molCC-RBGood, Fairbrother, et al., 1958Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub80.3 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Good, Fairbrother, et al., 1958, 2.; AC
Δsub92.3 ± 2.1kJ/molCC-RBConnor, Zafarani-Moattar, et al., 1982Other values for the enthalpy of sublimation have been reported: 80.3 ± 4.2 kJ/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975 (see also Behrens, 1976) and 62.8 ± 4.2 kJ/mol Cotton and Monchamp, 1960; MS
Δsub92.3 ± 2.1kJ/molCConnor, Zafarani-Moattar, et al., 1982, 2AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
60.7 ± 1.3446.Baev, Dem'yanchuk, et al., 1971Based on data from 428. to 463. K.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
80.3 ± 2.1390.MMBaev, Dem'yanchuk, et al., 1971Based on data from 351. to 428. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.32 ± 0.01EIMichels and Svec, 1981LLK
7.7PEHigginson, Lloyd, et al., 1975LLK
7.69 ± 0.01PEConnor, Zafarani-Moattar, et al., 1972LLK
8.46 ± 0.03EIJunk and Svec, 1970RDSH
8.4 ± 0.1EIBidinosti and McIntyre, 1970RDSH
8.55 ± 0.10EIWinters and Kiser, 1965RDSH
8.02PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.02PEEvans, Green, et al., 1969Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
MnCO+18.21?EISvec and Junk, 1967RDSH
MnCO+17.5 ± 0.2?EIWinters and Kiser, 1965RDSH
MnC2O2+14.80?EISvec and Junk, 1967RDSH
Mn2C2O2+16.438COEISvec and Junk, 1967RDSH
Mn2C3O3+15.347COEISvec and Junk, 1967RDSH
Mn2C4O4+13.986COEISvec and Junk, 1967RDSH
Mn2C4O4+14.0 ± 0.26COEIWinters and Kiser, 1965RDSH
MnC5O5+9.40?EISvec and Junk, 1967RDSH
MnC5O5+9.3 ± 0.1?EIBidinosti and McIntyre, 1966RDSH
Mn2C5O5+11.915COEISvec and Junk, 1967RDSH
Mn2C5O5+12.6 ± 0.25COEIWinters and Kiser, 1965RDSH
Mn+22.13?EISvec and Junk, 1967RDSH
Mn+20.8 ± 0.4?EIWinters and Kiser, 1965RDSH
Mn2+18.7310COEISvec and Junk, 1967RDSH
Mn2+18.8 ± 0.310COEIWinters and Kiser, 1965RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Good, Fairbrother, et al., 1958
Good, W.D.; Fairbrother, D.M.; Waddington, G., J. Phys. Chem., 1958, 62, 853. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Good, Fairbrother, et al., 1958, 2
Good, W.D.; Fairbrother, D.M.; Waddington, Guy, Manganese Carbonyl: Heat of Formation by Rotating-Bomb Calorimetry, J. Phys. Chem., 1958, 62, 7, 853-856, https://doi.org/10.1021/j150565a021 . [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M., J. Chem. Thermodyn., 1975, 7, 913. [all data]

Behrens, 1976
Behrens, R.G., J. Organometal. Chem., 1976, 121, C63. [all data]

Cotton and Monchamp, 1960
Cotton, F.A.; Monchamp, R.R., J. Chem. Soc., 1960, 533.. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)10 and TcRe(CO)10, Inorg. Chem., 1981, 20, 3445. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Connor, Zafarani-Moattar, et al., 1972
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; ElSaied, N.I.; Suradi, S.; Carson, R.; AlTakhin, G.; Skinner, H.A., [Title unavailable], Organometallics, 1972, 1, 1166. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Bidinosti and McIntyre, 1970
Bidinosti, D.R.; McIntyre, N.S., Mass spectrometric study of the thermal decomposition of dimanganese decacarbonyl and dicobalt octacarbonyl, Can. J. Chem., 1970, 48, 593. [all data]

Winters and Kiser, 1965
Winters, R.E.; Kiser, R.W., Ions produced by electron impact with the dimetallic carbonyls of cobalt and manganese, J. Phys. Chem., 1965, 69, 1618. [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W., Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10, J. Am. Chem. Soc., 1967, 89, 2836. [all data]

Bidinosti and McIntyre, 1966
Bidinosti, D.R.; McIntyre, N.S., The metal-metal bond dissociation energy in manganese carbonyl, Chem. Commun., 1966, 555. [all data]


Notes

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