gadolinium trichloride
- Formula: Cl3Gd
- Molecular weight: 263.61
- CAS Registry Number: 10138-52-0
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.36 ± 0.04 | EI | Lee, Potts, et al., 1982 | Vertical value; LBLHLM |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
ClGd+ | 16.5 ± 1.0 | 2Cl? | EI | Ciach, Nicholson, et al., 1973 | LLK |
Cl2Gd+ | 11.9 ± 0.3 | Cl? | EI | Ciach, Nicholson, et al., 1973 | LLK |
Gd+ | 21.38 ± 0.05 | 3Cl | EI | Sapegin, Baluev, et al., 1984 | LBLHLM |
Gd+ | 20.9 ± 1.0 | 3Cl? | EI | Ciach, Nicholson, et al., 1973 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E.,
HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase,
Proc. R. Soc. London A, 1982, 381, 373. [all data]
Ciach, Nicholson, et al., 1973
Ciach, S.; Nicholson, A.J.C.; Swingler, D.L.; Thistlethwaite, P.J.,
Mass spectrometric study of the vapor phase over neodymium chloride gadolinium chloride,
Inorg. Chem., 1973, 12, 2072. [all data]
Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I.,
Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides,
Russ. J. Phys. Chem., 1984, 58, 1792. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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