cadmium chloride
- Formula: CdCl2
- Molecular weight: 183.317
- CAS Registry Number: 10108-64-2
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 132.6 | 950. | Bloom and Welch, 1958 | Based on data from 875. to 1026. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.2 ± 0.2 | EI | Bloom and Hastie, 1966 | RDSH |
| 11.42 | PE | Berkowitz, 1974 | Vertical value; LLK |
| 11.44 ± 0.05 | PE | Cocksey, Eland, et al., 1973 | Vertical value; LLK |
| 11.3 | PE | Boggess, Allen, et al., 1973 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| CdCl+ | 11.8 ± 0.2 | Cl | EI | Bloom and Hastie, 1966 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bloom and Welch, 1958
Bloom, H.; Welch, B.J.,
The Vapor Pressure of Cadmium and Zinc Chlorides,
J. Phys. Chem., 1958, 62, 12, 1594-1595, https://doi.org/10.1021/j150570a033
. [all data]
Bloom and Hastie, 1966
Bloom, H.; Hastie, J.W.,
Vapour phase composition above molten salt mixtures: a mass spectrometric study,
Australian J. Chem., 1966, 19, 1003. [all data]
Berkowitz, 1974
Berkowitz, J.,
PES of high-temperature vapors. VI. 304 A and 584 APES of Zn, Cd, and Hg halides and the electronegativity scale,
J. Chem. Phys., 1974, 61, 407. [all data]
Cocksey, Eland, et al., 1973
Cocksey, B.G.; Eland, J.H.D.; Danby, C.J.,
Photoelectron spectra of the zinc and cadmium halides,
J. Chem. Soc. Faraday Trans. 2, 1973, 69, 1558. [all data]
Boggess, Allen, et al., 1973
Boggess, G.W.; Allen, J.D., Jr.; Schweitzer, G.K.,
The photoelectron spectra of gaseous zinc(II) and cadmium(II) chlorides, bromides, and iodides,
J. Electron Spectrosc. Relat. Phenom., 1973, 2, 467. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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