lutetium trichloride

• Formula: Cl₃Lu
• Molecular weight: 281.326
• CAS Registry Number: 10099-66-8
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
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  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 + Cl₃Lu = ( • Cl₃Lu)

By formula: Cl^- + Cl₃Lu = (Cl^- • Cl₃Lu)

Cl₄Lu^- + Cl₃Lu = Cl₇Lu₂^-

By formula: Cl₄Lu^- + Cl₃Lu = Cl₇Lu₂^-

Cl₇Lu₂^- + 2Cl₃Lu = Cl₁₀Lu₃^-

By formula: Cl₇Lu₂^- + 2Cl₃Lu = Cl₁₀Lu₃^-

Cl₁₀Lu₃^- + 3Cl₃Lu = Cl₁₃Lu₄^-

By formula: Cl₁₀Lu₃^- + 3Cl₃Lu = Cl₁₃Lu₄^-

Cl₁₃Lu₄^- + 4Cl₃Lu = Cl₁₆Lu₅^-

By formula: Cl₁₃Lu₄^- + 4Cl₃Lu = Cl₁₆Lu₅^-

Cl₁₆Lu₅^- + 5Cl₃Lu = Cl₁₉Lu₆^-

By formula: Cl₁₆Lu₅^- + 5Cl₃Lu = Cl₁₉Lu₆^-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + Cl₃Lu = ( • Cl₃Lu)

By formula: Cl^- + Cl₃Lu = (Cl^- • Cl₃Lu)

Cl₄Lu^- + Cl₃Lu = Cl₇Lu₂^-

By formula: Cl₄Lu^- + Cl₃Lu = Cl₇Lu₂^-

Cl₇Lu₂^- + 2Cl₃Lu = Cl₁₀Lu₃^-

By formula: Cl₇Lu₂^- + 2Cl₃Lu = Cl₁₀Lu₃^-

Cl₁₀Lu₃^- + 3Cl₃Lu = Cl₁₃Lu₄^-

By formula: Cl₁₀Lu₃^- + 3Cl₃Lu = Cl₁₃Lu₄^-

Cl₁₃Lu₄^- + 4Cl₃Lu = Cl₁₆Lu₅^-

By formula: Cl₁₃Lu₄^- + 4Cl₃Lu = Cl₁₆Lu₅^-

Cl₁₆Lu₅^- + 5Cl₃Lu = Cl₁₉Lu₆^-

By formula: Cl₁₆Lu₅^- + 5Cl₃Lu = Cl₁₉Lu₆^-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pogrebnoi, Kudion, et al., 1997
Pogrebnoi, A.; Kudion, L.S.; Kuznetsov, A.Yu.; Butman, M.F., Molecular and Ionic Clusters in Saturated Vapor over Lutetium Trichloride, Rapid Commun. Mass Spectrom., 1997, 11, 14, 1536, https://doi.org/10.1002/(SICI)1097-0231(199709)11:14<1536::AID-RCM31>3.0.CO;2-D . [all data]

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Hastie, Ficalora, et al., 1968
Hastie, J.W.; Ficalora, P.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXV. Vapor composition over LaCl₃, EuCl₃ and LuCl₃ and stabilities of the trichloride dimers, J. Less-Common Metals, 1968, 14, 83. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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