lanthanum chloride, anhydrous

• Formula: Cl₃La
• Molecular weight: 245.264
• CAS Registry Number: 10099-58-8
• Information on this page:
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + Cl₃La = ( • Cl₃La)

By formula: Cl^- + Cl₃La = (Cl^- • Cl₃La)

( • Cl₃La) + Cl₃La = ( • 2Cl₃La)

By formula: (Cl^- • Cl₃La) + Cl₃La = (Cl^- • 2Cl₃La)

Cl₄La^- + Cl₃La = Cl₇La₂^-

By formula: Cl₄La^- + Cl₃La = Cl₇La₂^-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ruscic, Goodman, et al., 1983
Ruscic, B.; Goodman, G.L.; Berkowitz, J., Photoelectron spectra of the lanthanide trihalides and their interpretation, J. Chem. Phys., 1983, 78, 5443. [all data]

Hastie, Ficalora, et al., 1968
Hastie, J.W.; Ficalora, P.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXV. Vapor composition over LaCl₃, EuCl₃ and LuCl₃ and stabilities of the trichloride dimers, J. Less-Common Metals, 1968, 14, 83. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V., Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl₄^- and La₂Cl₇^-, Russ. J. Phys. Chem., 1987, 61, 1518. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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