terbium (III) chloride hexahydrate

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

TbCl4- + Cl3Tb = Cl7Tb2-

By formula: TbCl4- + Cl3Tb = Cl7Tb2-

Quantity Value Units Method Reference Comment
Δr242. ± 38.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr374. ± 10.kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

Chlorine anion + Cl3Tb = Cl4Tb-

By formula: Cl- + Cl3Tb = Cl4Tb-

Quantity Value Units Method Reference Comment
Δr353. ± 18.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr304. ± 6.7kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + 2Cl3Tb = Cl10Tb3-

By formula: TbCl4- + 2Cl3Tb = Cl10Tb3-

Quantity Value Units Method Reference Comment
Δr390. ± 9.6kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + 3Cl3Tb = Cl13Tb4-

By formula: TbCl4- + 3Cl3Tb = Cl13Tb4-

Quantity Value Units Method Reference Comment
Δr320. ± 84.kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
11.43 ± 0.05PELee, Potts, et al., 1982Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Tb+20.83 ± 0.043ClEISapegin, Baluev, et al., 1984 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Cl3Tb = Cl4Tb-

By formula: Cl- + Cl3Tb = Cl4Tb-

Quantity Value Units Method Reference Comment
Δr353. ± 18.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr304. ± 6.7kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + Cl3Tb = Cl7Tb2-

By formula: TbCl4- + Cl3Tb = Cl7Tb2-

Quantity Value Units Method Reference Comment
Δr242. ± 38.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr374. ± 10.kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + 2Cl3Tb = Cl10Tb3-

By formula: TbCl4- + 2Cl3Tb = Cl10Tb3-

Quantity Value Units Method Reference Comment
Δr390. ± 9.6kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + 3Cl3Tb = Cl13Tb4-

By formula: TbCl4- + 3Cl3Tb = Cl13Tb4-

Quantity Value Units Method Reference Comment
Δr320. ± 84.kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Khasanshin, Kudin, et al., 1999
Khasanshin, I.V.; Kudin, L.S.; Pogrebnoi, A.M., A mass spectrometric study of saturated vapor over terbium trichloride and the TbCl3-DyCl3 system, Russ. J. Phys. Chem., 1999, 73, 849-855. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides, Russ. J. Phys. Chem., 1984, 58, 1792. [all data]


Notes

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