terbium (III) chloride hexahydrate

• Formula: Cl₃Tb
• Molecular weight: 265.284
• CAS Registry Number: 10042-88-3
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

By formula: TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

 + Cl₃Tb = Cl₄Tb^-

By formula: Cl^- + Cl₃Tb = Cl₄Tb^-

TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

By formula: TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

By formula: TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

Appearance energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + Cl₃Tb = Cl₄Tb^-

By formula: Cl^- + Cl₃Tb = Cl₄Tb^-

TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

By formula: TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

By formula: TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

By formula: TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Khasanshin, Kudin, et al., 1999
Khasanshin, I.V.; Kudin, L.S.; Pogrebnoi, A.M., A mass spectrometric study of saturated vapor over terbium trichloride and the TbCl3-DyCl3 system, Russ. J. Phys. Chem., 1999, 73, 849-855. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides, Russ. J. Phys. Chem., 1984, 58, 1792. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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