terbium (III) chloride hexahydrate

• Formula: Cl₃Tb
• Molecular weight: 265.284
• CAS Registry Number: 10042-88-3
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

By formula: TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

 + Cl₃Tb = Cl₄Tb^-

By formula: Cl^- + Cl₃Tb = Cl₄Tb^-

TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

By formula: TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

By formula: TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

Appearance energy determinations

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + Cl₃Tb = Cl₄Tb^-

By formula: Cl^- + Cl₃Tb = Cl₄Tb^-

TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

By formula: TbCl₄^- + Cl₃Tb = Cl₇Tb₂^-

TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

By formula: TbCl₄^- + 2Cl₃Tb = Cl₁₀Tb₃^-

TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

By formula: TbCl₄^- + 3Cl₃Tb = Cl₁₃Tb₄^-

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Khasanshin, Kudin, et al., 1999
Khasanshin, I.V.; Kudin, L.S.; Pogrebnoi, A.M., A mass spectrometric study of saturated vapor over terbium trichloride and the TbCl3-DyCl3 system, Russ. J. Phys. Chem., 1999, 73, 849-855. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides, Russ. J. Phys. Chem., 1984, 58, 1792. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.