Tetrafluorohydrazine

• Formula: F₄N₂
• Molecular weight: 104.0070
• IUPAC Standard InChI: InChI=1S/F4N2/c1-5(2)6(3)4 Copy

  
• IUPAC Standard InChIKey: GFADZIUESKAXAK-UHFFFAOYSA-N Copy
• CAS Registry Number: 10036-47-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Nitrogen fluoride (N2F4); Dinitrogen tetrafluoride; Hydrazine, tetrafluoro-; Perfluorohydrazine; N2F4; Nitrogen fluoride; 1,1,2,2-Tetrafluorohydrazine
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• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Phase change data
  • Henry's Law data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Greene, et al., 1984
Berkowitz, J.; Greene, J.P.; Foropoulos, J., Jr.; Neskovic, O.M., Bonding and ionization energies of N-F and P-F compounds, J. Chem. Phys., 1984, 81, 6166. [all data]

Foner and Hudson, 1973
Foner, S.N.; Hudson, R.L., Mass spectrometric studies of tetrafluorohydrazine and the difluoroamino radical, J. Chem. Phys., 1973, 58, 581. [all data]

Herron and Dibeler, 1960
Herron, J.T.; Dibeler, V.H., Mass spectrum and appearance potentials of tetrafluorohydrazine, J. Chem. Phys., 1960, 33, 1595. [all data]

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., Ionization potentials of the difluoroamino radical by photoelectron spectroscopy and INDO calculations, J. Chem. Phys., 1971, 54, 1872. [all data]

Cristy and Mamantov, 1970
Cristy, S.S.; Mamantov, G., Cryogenic mass spectrometry of reactive fluorine-containing species. II. Applications to synthesis via pyrolysis, photolysis and microwave discharge, Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 319. [all data]

Herron and Dibeler, 1961
Herron, J.T.; Dibeler, V.H., Mass spectrometric study of NF₂, NF₃, N₂F₂, and N₂F₄, J. Res. NBS, 1961, 65A, 405. [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy
  IE (evaluated)	Recommended ionization energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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