nickel difluoride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
1350. to 1556.5.428677272.953-433.953McDougall and Kilpatrick, 1965Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
332.2 ± 4.11054. to 1106.MEEhlert, Kent, et al., 1964AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
11.5 ± 0.3EIEhlert, Kent, et al., 1964, 2

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
NiF+13.0 ± 0.3FEIEhlert, Kent, et al., 1964, 2 
Ni+16.7 ± 0.3?EIEhlert, Kent, et al., 1964, 2 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + nickel difluoride = (Fluorine anion • nickel difluoride)

By formula: F- + F2Ni = (F- • F2Ni)

Quantity Value Units Method Reference Comment
Δr338. ± 15.kJ/molTDEqNikitin, Igolkina, et al., 1986gas phase; Reanalyzed literature data, 35.9 kcal < AlF3

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McDougall and Kilpatrick, 1965
McDougall, L.A.; Kilpatrick, J.E., Entropy and Related Thermodynamic Properties of Carbon Suboxide, J. Chem. Phys., 1965, 42, 7, 2311-2321, https://doi.org/10.1063/1.1696294 . [all data]

Ehlert, Kent, et al., 1964
Ehlert, T.C.; Kent, R.A.; Margrave, J.L., Mass Spectrometric Studies at High Temperatures. VI. The Sublimation Pressure of Nickel(II) Fluoride, J. Am. Chem. Soc., 1964, 86, 23, 5093-5095, https://doi.org/10.1021/ja01077a009 . [all data]

Ehlert, Kent, et al., 1964, 2
Ehlert, T.C.; Kent, R.A.; Margrave, J.L., Mass spectrometric studies at high temperatures. VI. The sublimation pressure of nickel(II) fluoride, J. Am. Chem. Soc., 1964, 86, 5093. [all data]

Nikitin, Igolkina, et al., 1986
Nikitin, M.I.; Igolkina, N.A.; Skokan, E.V.; Sorokin, I.D.; Sidirov, L.N., Enthalpies of formation of the AlF4- ion, J. Phys. Chem., 1986, 60, 22. [all data]


Notes

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