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Phosphorus oxychloride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)11.5 ± 0.1eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
1.41 ± 0.20NBIEMathur, Rothe, et al., 1976B

Ionization energy determinations

IE (eV) Method Reference Comment
11.36 ± 0.02PEBunzli, Frost, et al., 1973LLK
11.58 ± 0.05PEBasset and Lloyd, 1972LLK
11.4 ± 0.3EIKiser, Dillard, et al., 1969RDSH
13.1 ± 0.2EIHalmann and Klein, 1964RDSH
11.89PEChattorpadhyay, Findley, et al., 1981Vertical value; LLK
11.89 ± 0.02PEGan, Peel, et al., 1977Vertical value; LLK
11.49PEVovna, Lopatin, et al., 1975Vertical value; LLK
11.89 ± 0.03PECox, Evans, et al., 1972Vertical value; LLK
12.0PEBetteridge, Thompson, et al., 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl+19. ± 1.?EIHalmann and Klein, 1964RDSH
POCl+15.6 ± 0.3?EIKiser, Dillard, et al., 1969RDSH
PCl+20.2 ± 0.4?EIKiser, Dillard, et al., 1969RDSH
PCl+17. ± 1.?EIHalmann and Klein, 1964RDSH
POCl2+12.8 ± 0.3ClEIKiser, Dillard, et al., 1969RDSH
POCl2+13.3 ± 0.2ClEIHalmann and Klein, 1964RDSH
PCl2+13.3 ± 0.5?EIHalmann and Klein, 1964RDSH
PCl3+12.3 ± 0.5OEIHalmann and Klein, 1964RDSH
O+13. ± 2.?EIHalmann and Klein, 1964RDSH
PO+16.6 ± 0.4?EIKiser, Dillard, et al., 1969RDSH
PO+14.5 ± 0.5?EIHalmann and Klein, 1964RDSH
P+28.1 ± 0.5?EIKiser, Dillard, et al., 1969RDSH
P+21.4?EIHalmann and Klein, 1964RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mathur, Rothe, et al., 1976
Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Reck, G., Negative ions from phosphorus halides due to cesium charge exchange, J. Chem. Phys., 1976, 64, 565. [all data]

Bunzli, Frost, et al., 1973
Bunzli, J.C.; Frost, D.C.; McDowell, C.A., Photoelectron spectra of phosphoryl and thioophosphoryl ch;prodes and bromides, J. Electron Spectrosc. Relat. Phenom., 1973, 1, 481. [all data]

Basset and Lloyd, 1972
Basset, P.J.; Lloyd, D.R., Photoelectron spectra of halides. Part III. Trifluorides and oxide trifluorides of nitrogen and phosphorus, and phosphorus oxide trichloride, J. Chem. Soc. Dalton Trans., 1972, 248. [all data]

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]

Halmann and Klein, 1964
Halmann, M.; Klein, Y., Electron-impact spectroscopy of phosphorus compounds. Part III. Positive- andnegative-ion formation from phosphorus trichloride and phosphoryl chloride, J. Chem. Soc., 1964, 4324. [all data]

Chattorpadhyay, Findley, et al., 1981
Chattorpadhyay, S.; Findley, G.L.; McGlynn, S.P., Photoelectron spectroscopy of phosphites and phosphates, J. Electron Spectrosc. Relat. Phenom., 1981, 24, 27. [all data]

Gan, Peel, et al., 1977
Gan, T.H.; Peel, J.B.; Willett, G.D., Comparison of He I and He II photoelectron spectra of phosphoryl chloride, Chem. Phys. Lett., 1977, 48, 483. [all data]

Vovna, Lopatin, et al., 1975
Vovna, V.I.; Lopatin, S.N.; Pettsol'd, R.; Vilesov, F.I., Photoelectron spectra and electronic structure of some phosphoryl compounds, Khim. Vys. Energ., 1975, 9, 9. [all data]

Cox, Evans, et al., 1972
Cox, P.A.; Evans, S.; Orchard, A.F.; Richardson, N.V.; Roberts, P.J., Simple quantitative molecular orbital methods used in connection with photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 26. [all data]

Betteridge, Thompson, et al., 1972
Betteridge, D.; Thompson, M.; Baker, A.D.; Kemp, N.R., Photoelectron spectra of phosphorus halides, alkyl phosphites and phosphates, organophosphorus pesticides, and related compounds, Anal. Chem., 1972, 44, 2005. [all data]


Notes

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