nitrogen trichloride
- Formula: Cl3N
- Molecular weight: 120.366
- IUPAC Standard InChIKey: QEHKBHWEUPXBCW-UHFFFAOYSA-N
- CAS Registry Number: 10025-85-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Data at other public NIST sites:
- Options:
Phase change data
Go To: Top, Henry's Law data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
32.9 | 360. | Sladkov and Novikova, 1996 | Based on data from 280. to 440. K. |
Henry's Law data
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference |
---|---|---|---|
0.10 | 4100. | M | N/A |
Gas phase ion energetics data
Go To: Top, Phase change data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.1 ± 0.1 | PE | Colbourne, Frost, et al., 1978 | LLK |
10.7 | PE | Potts, Lempka, et al., 1970 | Vertical value; RDSH |
References
Go To: Top, Phase change data, Henry's Law data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sladkov and Novikova, 1996
Sladkov, I.B.; Novikova, N.Yu.,
Physicochemical properties of some nitrogen halides,
Zh. Prikl. Khim. (S.-Peterburg), 1996, 69, 11, 1840. [all data]
Colbourne, Frost, et al., 1978
Colbourne, D.; Frost, D.C.; McDowell, C.A.; Westwood, N.P.C.,
The photoelectron spectra of the chloramines NH2Cl, NHCl2, NCl3 and the methyl chloramines CH3NHCl, CH3NCl2, and (CH3)2NCl,
J. Chem. Phys., 1978, 69, 1078. [all data]
Potts, Lempka, et al., 1970
Potts, A.W.; Lempka, H.J.; Streets, D.G.; Price, W.C.,
Photoelectron spectra of the halides of elements in groups III, IV, V and VI,
Phil. Trans. Roy. Soc. (London), 1970, A268, 59. [all data]
Notes
Go To: Top, Phase change data, Henry's Law data, Gas phase ion energetics data, References
- Symbols used in this document:
d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.