dysprosium trichloride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub67.6 ± 1.2kcal/molTEBrunetti, Vassallo, et al., 1999Based on data from 924. to 1214. K.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

TbCl4- + Cl3Dy = Cl7DyTb-

By formula: TbCl4- + Cl3Dy = Cl7DyTb-

Quantity Value Units Method Reference Comment
Δr87. ± 12.kcal/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
11.42 ± 0.06PELee, Potts, et al., 1982Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Dy+10.20 ± 0.063ClEISapegin, Baluev, et al., 1984 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brunetti, Vassallo, et al., 1999
Brunetti, Bruno; Vassallo, Papirio; Piacente, Vincenzo; Scardala, Paolo, Vaporization Studies of Dysprosium Trichloride, Tribromide, and Triiodide, J. Chem. Eng. Data, 1999, 44, 3, 509-515, https://doi.org/10.1021/je9801821 . [all data]

Khasanshin, Kudin, et al., 1999
Khasanshin, I.V.; Kudin, L.S.; Pogrebnoi, A.M., A mass spectrometric study of saturated vapor over terbium trichloride and the TbCl3-DyCl3 system, Russ. J. Phys. Chem., 1999, 73, 849-855. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides, Russ. J. Phys. Chem., 1984, 58, 1792. [all data]


Notes

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