dysprosium trichloride
- Formula: Cl3Dy
- Molecular weight: 268.859
- CAS Registry Number: 10025-74-8
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Phase change data
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 67.6 ± 1.2 | kcal/mol | TE | Brunetti, Vassallo, et al., 1999 | Based on data from 924. to 1214. K. |
Reaction thermochemistry data
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: TbCl4- + Cl3Dy = Cl7DyTb-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87. ± 12. | kcal/mol | TDEq | Khasanshin, Kudin, et al., 1999 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.42 ± 0.06 | PE | Lee, Potts, et al., 1982 | Vertical value |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Dy+ | 10.20 ± 0.06 | 3Cl | EI | Sapegin, Baluev, et al., 1984 |
References
Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brunetti, Vassallo, et al., 1999
Brunetti, Bruno; Vassallo, Papirio; Piacente, Vincenzo; Scardala, Paolo,
Vaporization Studies of Dysprosium Trichloride, Tribromide, and Triiodide,
J. Chem. Eng. Data, 1999, 44, 3, 509-515, https://doi.org/10.1021/je9801821
. [all data]
Khasanshin, Kudin, et al., 1999
Khasanshin, I.V.; Kudin, L.S.; Pogrebnoi, A.M.,
A mass spectrometric study of saturated vapor over terbium trichloride and the TbCl3-DyCl3 system,
Russ. J. Phys. Chem., 1999, 73, 849-855. [all data]
Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E.,
HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase,
Proc. R. Soc. London A, 1982, 381, 373. [all data]
Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I.,
Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides,
Russ. J. Phys. Chem., 1984, 58, 1792. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔrH° Enthalpy of reaction at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.