neodymium trichloride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Cl4Nd- + 2Cl3Nd = Cl10Nd3-

By formula: Cl4Nd- + 2Cl3Nd = Cl10Nd3-

Quantity Value Units Method Reference Comment
Δr101. ± 11.kcal/molTDAsKudin, Pogrebnoi, et al., 1993gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
≤11.4EICiach, Nicholson, et al., 1973LLK
11.16PELee, Potts, et al., 1982Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClNd+17.3 ± 1.02Cl?EICiach, Nicholson, et al., 1973LLK
Cl2Nd+11.9 ± 0.3Cl?EICiach, Nicholson, et al., 1973LLK
Nd+20.07 ± 0.053ClEISapegin, Baluev, et al., 1984LBLHLM
Nd+20.9 ± 1.03Cl?EICiach, Nicholson, et al., 1973LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Pogrebnoi, et al., 1993
Kudin, L.S.; Pogrebnoi, A.M.; Burdukovskaya, G.G., Mass-Spectrometric Study of Saturated Vapor Composition over Neodymium Chlorides .2. Ion-Molecular Equilibrium and Enthalpies of Formation of Formation of Positive and Negative Ions., Zh. Fiz. Khim. SSSR, 1993, 67, 908. [all data]

Ciach, Nicholson, et al., 1973
Ciach, S.; Nicholson, A.J.C.; Swingler, D.L.; Thistlethwaite, P.J., Mass spectrometric study of the vapor phase over neodymium chloride gadolinium chloride, Inorg. Chem., 1973, 12, 2072. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]

Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides, Russ. J. Phys. Chem., 1984, 58, 1792. [all data]


Notes

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