1,4-Benzenediamine, N,N,N',N'-tetramethyl-
- Formula: C10H16N2
- Molecular weight: 164.2474
- IUPAC Standard InChIKey: CJAOGUFAAWZWNI-UHFFFAOYSA-N
- CAS Registry Number: 100-22-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: p-Phenylenediamine, N,N,N',N'-tetramethyl-; p-Bis(dimethylamino)benzene; N,N,N',N'-Tetramethyl-p-phenylenediamine; N,N,N',N'-Tetramethyl-1,4-phenylenediamine; Tetramethyl-p-phenylenediamine; TMPD; N,N,N',N'-Tetramethyl-1,4-Benzenediamine; N,N,N',N,-Tetramethyl-p-phenylenediamine; Benzene, 1,4-bis(dimethylamino)-; 1,4-Bis(dimethylamino)benzene; N,N,N',N'-Tetramethyl-p-fenylendiamin; Tetramethyl-p-phenyldiamine; TL 85; Wurster's reagent; Wurster's blue; 1,4-Benzenediamine, N1,N1,N4,N4-tetramethyl-
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Gas phase ion energetics data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.1 ± 0.1 | PE | Egdell, Green, et al., 1975 | LLK |
6.20 ± 0.05 | PI | Adamchuk, Dmitriev, et al., 1972 | LLK |
≤6.20 ± 0.02 | PI | Nakato, Ozaki, et al., 1971 | LLK |
6.7 | CTS | Foster, 1959 | RDSH |
6.75 | PE | Kaim and Bock, 1978 | Vertical value; LLK |
Mass spectrum (electron ionization)
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | NIST Mass Spectrometry Data Center, 1998. |
NIST MS number | 290505 |
References
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Egdell, Green, et al., 1975
Egdell, R.; Green, J.C.; Rao, C.N.R.,
Photoelectron spectra of substituted benzenes,
Chem. Phys. Lett., 1975, 33, 600. [all data]
Adamchuk, Dmitriev, et al., 1972
Adamchuk, V.K.; Dmitriev, A.B.; Prudnikova, G.V.; Sorokin, L.S.,
Photoionization of low-volatility molecules in a Geiger counter,
Opt. Spectrosc., 1972, 33, 191, In original 358. [all data]
Nakato, Ozaki, et al., 1971
Nakato, Y.; Ozaki, M.; Egawa, A.; Tsubornura, H.,
Organic amino compounds with very low ionization potentials,
Chem. Phys. Lett., 1971, 9, 615. [all data]
Foster, 1959
Foster, R.,
Ionization potentials of electron donors,
Nature (London), 1959, 183, 1253. [all data]
Kaim and Bock, 1978
Kaim, W.; Bock, H.,
R2P- und R2N-substituierte Benzole: Die Ladungsverteilung in ihren Kationen, Anionen und Trianionen,
Chem. Ber., 1978, 111, 3843. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References
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